CA2387803A1 - Abrasion resistant coatings - Google Patents
Abrasion resistant coatings Download PDFInfo
- Publication number
- CA2387803A1 CA2387803A1 CA 2387803 CA2387803A CA2387803A1 CA 2387803 A1 CA2387803 A1 CA 2387803A1 CA 2387803 CA2387803 CA 2387803 CA 2387803 A CA2387803 A CA 2387803A CA 2387803 A1 CA2387803 A1 CA 2387803A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- resin
- coating composition
- film
- improved method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
- D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
- D21H27/28—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/918—Material abnormally transparent
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24364—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.] with transparent or protective coating
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- Y10T428/24372—Particulate matter
- Y10T428/24405—Polymer or resin [e.g., natural or synthetic rubber, etc.]
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- Y10T428/24413—Metal or metal compound
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- Y10T428/24438—Artificial wood or leather grain surface
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- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
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- Y10T428/24926—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including ceramic, glass, porcelain or quartz layer
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- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/254—Polymeric or resinous material
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- Y10T428/257—Iron oxide or aluminum oxide
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31859—Next to an aldehyde or ketone condensation product
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- Y10T428/31866—Impregnated or coated cellulosic material
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Abstract
A coating composition for forming abrasion-resistant, high clarity coatings is described. It has been found that a macrocrystalline or single crystal miner al abrasive can be added at high levels, about 5 to about 80 percent by weight, to art-recognized film-forming resin compositions for producing coatings exhibiting exceptional abrasion resistance and clarity. Such a coating composition is useful for application to surfaces including wood, vinyl, til e, rubber modified cement, marble, metal, plastic, and laminated surfaces.</SDO AB>
Claims (31)
1. A coating composition for forming abrasion-resistant coatings of high clarity, said coating composition comprising a film-forming resin composition and a mineral abrasive in macrocrystalline or single crystalline form in an amount effective to impart abrasion resistance to the coating.
2. The composition of claim 1 wherein the mineral abrasive is an aluminum oxide.
3. The composition of claim 2 wherein the aluminum oxide is an electrofused aluminum oxide.
4. The composition of claim 2 wherein the aluminum oxide forms about 5 to about 80 weight percent of the coating.
5. The coating composition of claim 1 wherein the mineral abrasive is a silicon dioxide.
6. The composition of claim 5 wherein the silicon dioxide forms about 5 to about 80 weight percent of the coating.
7. The composition of claim 1 wherein the single crystal mineral abrasive forms a crystal of about 1 micron to about 500 microns in size.
8. The composition of claim 1 wherein the film-forming resin composition comprises a thermosetting resin.
9. The coating composition of claim 8 wherein the thermosetting resin comprises epoxy resins, acrylic resins, polyester resins, polycarbonate resins, melamine-formaldehyde resins, or polyurethane resins.
10. The coating composition of claim 9 wherein the thermosetting resins comprise a polymer crosslinked through the use of an aminoplast.
11. The composition of claim 1 wherein the film-forming resin composition comprises a UV-curable resin.
12. The composition of claim 11 wherein the UV-curable resin comprises olefin functional monomers and olefin functional oligomers or polymers.
13. The composition of claim 12 wherein the olefin functional oligomers or polymers comprise polyurethanes, cellulosic acrylic butyrates, nitrocellulosic polymers, polyesters, acrylic polymers, or blended or grafted combinations thereof.
14. The composition of claim 1 wherein the film-forming resin composition comprises a thermalplastic resin.
15. The composition of claim 14 wherein the thermalplastic resin comprises a nitrocellulose resin, an alkyd resin, a polyester resin, an acrylic resin, a vinyl acrylic resin, a styrene acrylic resin, a urethane, or a natural product.
16. In a method of surface finishing comprising the steps of applying at least one sealer coating composition to form a sealer coat and one top coating composition to form a surface top coat, the improvement which comprises using an improved sealer coating composition comprising a film-forming resin composition and a macrocrystalline or single crystalline mineral abrasive in an amount effective to impart abrasion resistance to the surface finish.
17. The improved method of claim 16 wherein at least two sealer coats are applied to the surface before the top coat is applied.
18. The improved method of claim 16 or 17 wherein the coating composition for the top coat comprises a film-forming resin composition and macrocrystalline or single crystalline mineral abrasive.
19. The improved method of claim 16 wherein the sealer coat or top coat is formed using the coating composition wherein the film-forming resin composition comprises a thermosetting resin.
20. The improved method of claim 19 wherein the thermosetting resin comprises epoxy resin, a polyurethane resin, a polyester resin, a polycarbonate resin, a melamine-formaldehyde resin, or an acrylic resin.
21. The improved method of claim 16 wherein the sealer coat or top coat is formed using a coating composition wherein the film-forming resin composition comprises a UV-curable resin composition.
22. The improved method of claim 21 wherein the UV-curable resin composition comprises olefin functional monomers and olefin functional oligomers or polymers.
23. The improved method of claim 22 wherein the olefin functional oligomers or polymers comprise polyurethanes.
24. The improved method of claim 16 wherein the mineral abrasive is an electrofused aluminum oxide.
25. The improved method of claim 24 wherein the aluminum oxide forms about 5 to about 80 percent by weight of the sealer coat.
26. The improved method of claim 24 wherein the aluminum oxide forms about 5 to about 20 percent by weight of the top coat.
27. The improved method of claim 16 wherein the surface is selected from the group consisting of a wood surface, a vinyl surface, a tile surface, a rubber modified cement surface, a marble surface, a metal surface, and a plastic surface.
28. An abrasion-resistant laminate comprising a base layer and at least one additional layer wherein the surface of said additional layer is finished with a coating composition comprising a film-forming resin composition and a macrocrystalline or single crystalline mineral abrasive in an amount effective to impart abrasion resistance to the surface finish.
29. A method of finishing the surface of a laminate comprising the step of applying to at least one layer of the laminate a coating composition comprising a film-forming resin composition and a macrocrystalline or single crystalline mineral abrasive in an amount effective to impart abrasion resistance to the surface finish.
30. A paper composition for forming an abrasion resistant surface of high clarity on a laminated composite said composition comprising paper impregnated or coated with a coating composition comprising a film-forming resin and about 5 to about 60 percent by weight of a mineral abrasive in macrocrystalline or single crystalline form.
31. A coating composition for forming abrasion-resistant coatings of high clarity, said coating composition comprising a film-forming resin composition and a mineral abrasive in macrocrystalline or single crystalline form wherein said mineral abrasive forms about 5 up to about 60 weight percent of the coating and wherein the coating composition exhibits about 70 percent clarity measured according to the ASTM® E430 Standard.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16988299P | 1999-12-09 | 1999-12-09 | |
US60/169,882 | 1999-12-09 | ||
US19954300P | 2000-04-25 | 2000-04-25 | |
US60/199,543 | 2000-04-25 | ||
PCT/US2000/042697 WO2001042373A2 (en) | 1999-12-09 | 2000-12-08 | Abrasion resistant coatings |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2387803A1 true CA2387803A1 (en) | 2001-06-14 |
CA2387803C CA2387803C (en) | 2010-02-09 |
Family
ID=26865475
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2387803 Expired - Fee Related CA2387803C (en) | 1999-12-09 | 2000-12-08 | Abrasion resistant coatings |
Country Status (5)
Country | Link |
---|---|
US (2) | US6436159B1 (en) |
EP (1) | EP1250395A4 (en) |
CA (1) | CA2387803C (en) |
MX (1) | MXPA02005597A (en) |
WO (1) | WO2001042373A2 (en) |
Families Citing this family (89)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001042373A2 (en) * | 1999-12-09 | 2001-06-14 | Valspar Sourcing, Inc. | Abrasion resistant coatings |
US7763345B2 (en) | 1999-12-14 | 2010-07-27 | Mannington Mills, Inc. | Thermoplastic planks and methods for making the same |
SE516696C2 (en) | 1999-12-23 | 2002-02-12 | Perstorp Flooring Ab | Process for producing surface elements comprising an upper decorative layer as well as surface elements produced according to the method |
EP1303398B1 (en) * | 2000-07-11 | 2008-11-19 | Pergo (Europe) AB | A process for the manufacturing of an improved core for decorative laminates and a decorative laminate obtained by the process |
US8028486B2 (en) | 2001-07-27 | 2011-10-04 | Valinge Innovation Ab | Floor panel with sealing means |
US20040058089A1 (en) * | 2001-10-10 | 2004-03-25 | Sport Court, Inc. | Floor tile coating method and system |
US6562414B2 (en) * | 2001-10-10 | 2003-05-13 | Sport Court, Inc. | Method of coating polyolefin floor tile |
DE10161093B4 (en) * | 2001-12-12 | 2008-04-17 | Ackner, Friedrich | Scratch and abrasion resistant decorative film and process for its preparation |
DE10163344B4 (en) * | 2001-12-21 | 2006-01-19 | Papierfabrik Schoeller & Hoesch Gmbh & Co. Kg | Light resistant overlay paper, process for its manufacture and use |
DE10209014A1 (en) * | 2002-02-25 | 2003-09-11 | Behr Automotive Gmbh | Method for manufacturing an interior fitting for vehicles and interior fitting manufactured thereafter |
US20040180181A1 (en) * | 2002-03-29 | 2004-09-16 | Eric Franzoi | Wear resistant laminates |
DE10262235B4 (en) | 2002-11-12 | 2010-05-12 | Kronotec Ag | Particle board, in particular floor panel or furniture panel, and method for its production |
US7617651B2 (en) | 2002-11-12 | 2009-11-17 | Kronotec Ag | Floor panel |
ES2307840T3 (en) | 2002-11-15 | 2008-12-01 | Flooring Technologies Ltd. | EQUIPMENT COMPOSED BY TWO CONSTRUCTION PLATES THAT CAN JOIN BETWEEN YES AND AN INSERTED PIECE TO INTERLOCK THESE CONSTRUCTION PLATES. |
DE10306118A1 (en) | 2003-02-14 | 2004-09-09 | Kronotec Ag | building board |
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- 2000-12-08 WO PCT/US2000/042697 patent/WO2001042373A2/en active Application Filing
- 2000-12-08 MX MXPA02005597A patent/MXPA02005597A/en active IP Right Grant
- 2000-12-08 US US09/733,782 patent/US6436159B1/en not_active Expired - Lifetime
- 2000-12-08 CA CA 2387803 patent/CA2387803C/en not_active Expired - Fee Related
- 2000-12-08 EP EP00992887A patent/EP1250395A4/en not_active Withdrawn
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2002
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US20030055145A1 (en) | 2003-03-20 |
CA2387803C (en) | 2010-02-09 |
MXPA02005597A (en) | 2004-09-10 |
US6436159B1 (en) | 2002-08-20 |
WO2001042373A3 (en) | 2002-03-14 |
US6641629B2 (en) | 2003-11-04 |
EP1250395A2 (en) | 2002-10-23 |
EP1250395A4 (en) | 2005-06-08 |
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