CN102329555A - Micro-bubble elastic polyurethane waterproof coating - Google Patents
Micro-bubble elastic polyurethane waterproof coating Download PDFInfo
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- CN102329555A CN102329555A CN201110211453A CN201110211453A CN102329555A CN 102329555 A CN102329555 A CN 102329555A CN 201110211453 A CN201110211453 A CN 201110211453A CN 201110211453 A CN201110211453 A CN 201110211453A CN 102329555 A CN102329555 A CN 102329555A
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- elastic polyurethane
- polyurethane waterproof
- talcum powder
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Abstract
The invention relates to a micro-bubble elastic polyurethane waterproof coating. The micro-bubble elastic polyurethane waterproof coating is characterized by comprising the following ingredients in parts by weight: 60-100 parts of polyurethane, 10-20 parts of isocyanate, 10-20 parts of water, 10-20 parts of zinc oxide, 0.1-1.0 part of talcum powder, 0.1-1.0 part of surfactant, 0.1-1.0 part of catalyst, 1-10 parts of hydroxypropyl methylcellulose, 80-100 parts of packing and 10-20 parts of plasticizer; the packing is any one of calcium carbonate, talcum powder and silicon dioxide; the plasticizer is any one of paraffin wax, castor oil, bisphthalate and stearic acid; the catalyst is methyldiethanolamine; and the surfactant is an anionic surfactant. The micro-bubble elastic polyurethane waterproof coating provided by the invention is safe and environment friendly because the organic solvent is adopted; and the coating has the advantages of easiness for coating and drying, good film forming property and smoothness.
Description
Technical field
The present invention relates to polyacrylate coating agent, belong to the textile chemistry field.
Background technology
The esters of acrylic acid coating-forming agent because good combination property is cheap, is one of the most general coating-forming agent; The organic solvent type coating-forming agent is the toluene solution of polyacrylic ester, good film-forming property, epithelium smooth pliable; Be easy to oven dry, but owing to contain 80% toluene solvant, inflammable, explosive, contaminate environment.
Summary of the invention
Technical problem to be solved by this invention provides a kind of microvesicle elastic polyurethane waterproof paint.
For solving the problems of the technologies described above, the present invention realizes like this
The microvesicle elastic polyurethane waterproof paint comprises the following component in weight part:
Urethane 60-100
Isocyanic ester 10-20
Water 10-20
Zinc oxide 10-20
Talcum powder 0.1-1.0
Tensio-active agent 0.1-1.0
Catalyzer 0.1-1.0
Hypromellose 1-10
Filler 80-100
Softening agent 10-20
Described filler is any of lime carbonate, talcum powder, silicon-dioxide.
Described softening agent is any of paraffin, Viscotrol C, Bisphthalate, Triple Pressed Stearic Acid.
The methyldiethanolamine of described catalyzer.
Described tensio-active agent is an AS.
The present invention has following positive effect:
Filler can increase the thickness of coating; Regulate rheological property, improve physical strength, put forward the weather resistance of coating and reduce cost; The filler that the present invention adopts mainly contains: 1, lime carbonate, talcum powder can improve the soft and moist type of coated membrane, reduce water-permeable, the internal stress when eliminating paint solidification; 2, silicon-dioxide can improve the mechanical property of coated membrane, plays effects such as thickening, thixotroping, sag prevention.
Softening agent can reduce the second-order transition temperature of resin, improves toughness, elongation, perviousness and the sticking power of coating.
The microvesicle elastic polyurethane waterproof paint of the present invention's preparation is amber viscous fluid, and solid content is 20%, and viscosity is 5000mPa.s (room temperature).Not not with an organic solvent, safety, environmental protection, its coating is easy to coating, good film-forming property, smooth, is easy to oven dry.
Embodiment
Below in conjunction with embodiment the present invention is done further detailed description.
Embodiment 1-4 prepares components contents that the microvesicle elastic polyurethane waterproof paint adopts (units) as follows
Table 1
? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
Urethane | 60.4 | 70.6 | 84.2 | 97.3 |
Isocyanic ester | 10.3 | 15.4 | 19.4 | 13.2 |
Water | 10.5 | 17.6 | 19.9 | 11.6 |
Zinc oxide | 10.9 | 15.6 | 17.2 | 18.9 |
Talcum powder | 0.1 | 0.5 | 0.7 | 0.9 |
Tensio-active agent | Sodium alkyl benzene sulfonate 0.1 | X 2073 0.5 | Lamepon A 0.8 | Succinate sodium sulfonate 0.9 |
Hypromellose | 1.5 | 5.4 | 7.2 | 6.1 |
Methyldiethanolamine | 0.1 | 1.0 | 0.9 | 0.5 |
Filler | Lime carbonate 80 | Talcum powder 100 | Silicon-dioxide 90 | Talcum powder 85 |
Softening agent | Paraffin 10.2 | Viscotrol C 19.7 | Bisphthalate 15.3 | Triple Pressed Stearic Acid 12.1 |
The preparation process is following: urethane, isocyanic ester are put into reaction vessel; 90-100 ℃ adds 10-30min, adds entry, zinc oxide, talcum powder, tensio-active agent, catalyzer, filler, softening agent, stirs 1-5h; Add hypromellose then, continue reaction 0.5-1h.Then raw material is transferred in the ball mill, grinds discharging 2 times.
Above-mentioned embodiment does not limit technical scheme of the present invention in any form, and the technical scheme that mode obtained that every employing is equal to replacement or equivalent transformation all drops on protection scope of the present invention.
Claims (2)
1. the microvesicle elastic polyurethane waterproof paint is characterized in that comprising the following component in weight part: urethane 60-100, isocyanic ester 10-20, water 10-20, zinc oxide 10-20, talcum powder 0.1-1.0, tensio-active agent 0.1-1.0, catalyzer 0.1-1.0, hypromellose 1-10, filler 80-100, softening agent 10-20; Described filler is any of lime carbonate, talcum powder, silicon-dioxide; Described softening agent is any of paraffin, Viscotrol C, Bisphthalate, Triple Pressed Stearic Acid; The methyldiethanolamine of described catalyzer; Described tensio-active agent is an AS.
2. the preparation method of microvesicle elastic polyurethane waterproof paint; It is characterized in that urethane, isocyanic ester are put into reaction vessel; 90-100 ℃ adds 10-30min, adds entry, zinc oxide, talcum powder, tensio-active agent, catalyzer, filler, softening agent, stirs 1-5h; Add hypromellose then, continue reaction 0.5-1h; Then raw material is transferred in the ball mill, grinds discharging 2 times.
Priority Applications (1)
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CN201110211453A CN102329555A (en) | 2011-07-27 | 2011-07-27 | Micro-bubble elastic polyurethane waterproof coating |
Applications Claiming Priority (1)
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CN201110211453A CN102329555A (en) | 2011-07-27 | 2011-07-27 | Micro-bubble elastic polyurethane waterproof coating |
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CN102329555A true CN102329555A (en) | 2012-01-25 |
Family
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CN201110211453A Pending CN102329555A (en) | 2011-07-27 | 2011-07-27 | Micro-bubble elastic polyurethane waterproof coating |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102876216A (en) * | 2012-09-26 | 2013-01-16 | 苏州汾湖电梯有限公司 | Coating for aluminum alloy decoration panel of elevator |
CN103540251A (en) * | 2013-09-26 | 2014-01-29 | 芜湖杰诺科技有限公司 | Waterborne polyurethane waterproofing paint |
CN104343050A (en) * | 2013-08-05 | 2015-02-11 | 金东纸业(江苏)股份有限公司 | Water-resistant paint, water-resistant paint production process, and paper |
CN111231425A (en) * | 2020-02-20 | 2020-06-05 | 上海乐盈纸业有限公司 | Waterproof corrugated paper and preparation method thereof |
Citations (4)
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CN101402826A (en) * | 2008-11-14 | 2009-04-08 | 上海维凯化学品有限公司 | Watersoluble polyurethane concrete paint base and method of producing the same |
CN101469246A (en) * | 2007-12-27 | 2009-07-01 | 上海涂料有限公司技术中心 | Preparation of polyaspartate polyurea waterproof coating material |
US20090240004A1 (en) * | 2006-09-29 | 2009-09-24 | Alois Maier | Functionalized polyurethane resin, method for the production thereof, and use thereof |
CN101717486A (en) * | 2009-12-03 | 2010-06-02 | 上海维凯化学品有限公司 | Degradable aqueous polyurethane dispersion and preparation method thereof |
-
2011
- 2011-07-27 CN CN201110211453A patent/CN102329555A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090240004A1 (en) * | 2006-09-29 | 2009-09-24 | Alois Maier | Functionalized polyurethane resin, method for the production thereof, and use thereof |
CN101469246A (en) * | 2007-12-27 | 2009-07-01 | 上海涂料有限公司技术中心 | Preparation of polyaspartate polyurea waterproof coating material |
CN101402826A (en) * | 2008-11-14 | 2009-04-08 | 上海维凯化学品有限公司 | Watersoluble polyurethane concrete paint base and method of producing the same |
CN101717486A (en) * | 2009-12-03 | 2010-06-02 | 上海维凯化学品有限公司 | Degradable aqueous polyurethane dispersion and preparation method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102876216A (en) * | 2012-09-26 | 2013-01-16 | 苏州汾湖电梯有限公司 | Coating for aluminum alloy decoration panel of elevator |
CN104343050A (en) * | 2013-08-05 | 2015-02-11 | 金东纸业(江苏)股份有限公司 | Water-resistant paint, water-resistant paint production process, and paper |
CN103540251A (en) * | 2013-09-26 | 2014-01-29 | 芜湖杰诺科技有限公司 | Waterborne polyurethane waterproofing paint |
CN103540251B (en) * | 2013-09-26 | 2016-03-30 | 芜湖杰诺科技有限公司 | A kind of aqueous polyurethane waterproof paint |
CN111231425A (en) * | 2020-02-20 | 2020-06-05 | 上海乐盈纸业有限公司 | Waterproof corrugated paper and preparation method thereof |
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Application publication date: 20120125 |