CN102516859A - Anti-doodling and anti-affixing paint and its preparation method - Google Patents
Anti-doodling and anti-affixing paint and its preparation method Download PDFInfo
- Publication number
- CN102516859A CN102516859A CN2011104016293A CN201110401629A CN102516859A CN 102516859 A CN102516859 A CN 102516859A CN 2011104016293 A CN2011104016293 A CN 2011104016293A CN 201110401629 A CN201110401629 A CN 201110401629A CN 102516859 A CN102516859 A CN 102516859A
- Authority
- CN
- China
- Prior art keywords
- doodling
- component
- affixing
- parts
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses an anti-doodling and anti-affixing paint and its preparation method. the paint is composed of two components A and B, wherein the component A contains, by weight, 4-20 parts of pseudo-perfluoroalkyl modified polysiloxane, 20-42 parts of hydroxy acrylic resin, 10-35 parts of pigments and fillers, 1-8 parts of an auxiliary agent, 10-36 parts of an organic solvent; and the component B contains, by weight, 12-30 parts of polyisocyanate prepolymer. The mass ratio of the component A to the component B is 2-8:1. The component A is prepared by the following steps of: adding hydroxy acrylic resin, pigments and fillers, the auxiliary agent and the organic solvent into a grinder, uniformly grinding to prepare slurry, pouring the ground slurry and pseudo-perfluoroalkyl modified polysiloxane together into a high-speed dispenser, dispersing at 800-1500 r/min for 0.5-2 hours, filtering and packaging to obtain the required component A. When in use, the anti-doodling and anti-affixing paint is obtained by uniformly mixing the components A and B at the mass ratio of 2-8:1. A paint film formed by the paint has the following advantages of low surface energy, small friction coefficient, excellent anti-doodling and anti-affixing performance and superstrong scrub resistance.
Description
Technical field
The present invention relates to coating and preparation method thereof, be specifically related to a kind of anti-doodling and anti-affixing coating and preparation method thereof.
Background technology
In the city, no matter be communal facility, on public transport stop board, waiting booth, electric pole, wall; Or public transport, on subway, train, light rail train, bus, the scribble of various coating and drawing at random and the small advertisement of arbitrarily putting up all are seen everywhere; Be commonly called as " city psoriasis "; Not only had a strong impact on city look and feel, and wanted the manpower and materials of labor, pressed for the coating that exploitation has the anti-doodling and anti-affixing performance for removing these scribbles.Existing research shows, the surface of low surface energy can prevent effectively that scribble from adhering to and pollute, and can easily remove through simply wiping.ZGK 5 has excellent hydrophobic and lyophobic property and oilness, is applied in the coating, can significantly reduce the surface energy of filming; Through modification, grafting fluoroalkyl side chain on polysiloxane backbone, when film forming, fluoro-containing group is strictness orientation film coated surface owing to its great surfactivity, and making films obtains better low surface energy effect.
The scientific research personnel has also done a few thing in the research and development of anti-doodling and anti-affixing coating, patent CN101585995B has reported with Hydroxylated acrylic resin, fluorocarbon resin, hydroxyl polydimethylsiloxaneresins resins, hexamethyl vulcabond biuret to be the oil-based anti-graffiti adhesion resistant paint of main raw material preparation; It is the anti-doodling and anti-affixing coating of compsn that patent CN 101565579B discloses with fluorocarbon resin and aliphatic polymeric isocyanate solidifying agent; Patent US 5387434 has reported with water soluble wax, water glass, rosin and tackiness agent to be the type of the damage certainly anti-doodling paint of compsn, uses high-pressure water heating to remove scribble, after the cleaning, need apply a coating again.Although above-mentioned report about anti-doodling and anti-affixing coating and preparation method thereof is arranged; But, do not see the report that the fluoroalkyl modified polyorganosiloxane is applied to preparation anti-doodling and anti-affixing coating in the dual-component polyurethane system at present both at home and abroad as yet from disclosed paper and patent.
Summary of the invention
Technical problem: the purpose of this invention is to provide the different anti-doodling and anti-affixing property of a kind of and existing composition, superpower scrub resistance, anti-liquid medium property with excellence; Coating surface can be low; Frictional coefficient is little, and is easy to clean, anti-doodling and anti-affixing coating of long service life and preparation method thereof.
Technical scheme: anti-doodling and anti-affixing coating of the present invention is made up of A, B two components, by weight,
The A component is:
4~20 parts of fluoroalkyl modified polyorganosiloxanes,
20~42 parts of Hydroxylated acrylic resins,
10~35 parts of color stuffings,
1~8 part of auxiliary agent,
10~36 parts of organic solvents,
The B component is 12~30 parts of polyisocyanate prepolymers;
The weight ratio of A component and B component is 2~8: 1.
The hydroxyl value of said Hydroxylated acrylic resin is 5~200mg KOH/g, and number-average molecular weight is 4000~50000.
Said color stuffing is one or more in aerosil, Rutile type Titanium Dioxide, anatase thpe white powder, ptfe micropowder, talcum powder, permanent white, lime carbonate, mica powder, aluminium powder or the hollow glass micropearl.
Said auxiliary agent is one or more in wetting dispersing agent, flow agent, skimmer, siccative, anti-wear agent, scratching resistant or the adhesion promoter.
Said organic solvent is the combination more than three kinds or three kinds in ritalin, vinyl acetic monomer, N-BUTYL ACETATE, toluene, p-Xylol, o-Xylol, m-xylene, 1-Methoxy-2-propyl acetate, ethylene glycol ether acetate, methylcarbonate, acetone, the pimelinketone.
Said polyisocyanate prepolymers is a kind of in HDI tripolymer, MDI tripolymer, IPDI tripolymer or the TDI tripolymer.
The preparation method of anti-doodling and anti-affixing coating is characterized in that:
The preparation of said A component:
Hydroxylated acrylic resin and color stuffing, auxiliary agent, organic solvent are joined in the shredder, process slurry after the grinding evenly; Ground slurry is put in the high speed dispersor with the fluoroalkyl modified polyorganosiloxane, after disperseing 0.5~2 hour under 800~1500 rev/mins, filtered and packaged, promptly get required A component;
During use, with A, B two components by 2~8: 1 weight proportion mixes and gets final product.
Said fluoroalkyl modified polyorganosiloxane is by fluorinated acrylate monomer and polymethyl hydrogen siloxane synthetic obtaining under catalyst action, and its compound method is: under the room temperature fluorinated acrylate monomer, solvent, catalyzer are joined in the reactor drum, stir and under protection of inert gas; Be warming up to more than 80 ℃; Drip polymethyl hydrogen siloxane, reacted 2~30 hours, be cooled to room temperature then; Except that desolvating, obtain transparent, heavy-gravity fluoroalkyl modified polyorganosiloxane through rotary evaporation.
Said fluorinated acrylate monomer is a kind of in trifluoroethyl methacrylate, vinylformic acid tetrafluoro propyl ester, tetrafluoropropyl propyl ester, vinylformic acid hexafluoro butyl ester, methylacrylic acid hexafluoro butyl ester, vinylformic acid octafluoro pentyl ester, methylacrylic acid octafluoro pentyl ester, dodecafluorhe-ptylacrylate, methylacrylic acid ten difluoro heptyl esters, vinylformic acid ten trifluoro monooctyl esters or the methylacrylic acid ten trifluoro monooctyl esters.
The structural formula of said polymethyl hydrogen siloxane is:
10≤n in the formula≤200.
Beneficial effect: the Hydroxylated acrylic resin in the A component of the present invention can with the polyisocyanate prepolymers crosslinking curing in the B component; Generation has the cancellated paint film of 3 D stereo, and this double-component polyurethane paint film cross-linking density height, compact structure, hardness height, scrub resistance and anti-liquid medium property are excellent; Added the very competent fluoroalkyl modified polyorganosiloxane of hydrophobic and oil repellent in the system; The surface energy and the frictional coefficient of paint film have been reduced significantly; Give the anti-doodling and anti-affixing property of paint film with excellence, can effectively prevent to scribble in adhering to and infiltration in paint film on the paint film, scribble can be removed through simple scouring; Various non-setting adhesives, glue also are difficult to stick to coating surface, and non-setting adhesive is pasted does not repeatedly have any glue residue for 500 times.
Embodiment
Pass through specific embodiment below; The present invention is further specified, but protection scope of the present invention is not limited thereto, any technician who is familiar with the present technique field is in scope disclosed by the invention; The variation that can expect easily or replacement all should be encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the scope of claim protection.
Embodiment 1:
The anti-doodling and anti-affixing coating that present embodiment provides is made up of A, B two components, comprises following raw material by weight:
The A component:
The B component:
18 parts of HDI tripolymers
Wherein, the compound method of fluoroalkyl modified polyorganosiloxane is: under the room temperature 60g vinylformic acid hexafluoro butyl ester, solvent, catalyzer are joined in the reactor drum, stir and under the high pure nitrogen protection; Be warming up to 90 ℃; Drip the 16.8g polymethyl hydrogen siloxane then, reacted 28 hours, be cooled to room temperature then; Except that desolvating, obtain transparent, heavy-gravity fluoroalkyl modified polyorganosiloxane through rotary evaporation; Wherein the structural formula of polymethyl hydrogen siloxane is:
The method for preparing anti-doodling and anti-affixing coating is: Hydroxylated acrylic resin and color stuffing, auxiliary agent, organic solvent are joined in the shredder, under 2500 rev/mins rotating speed, ground 3 hours, grind and evenly process slurry; Then ground slurry is put in the high speed dispersor with the fluoroalkyl modified polyorganosiloxane, after disperseing 1 hour under 1000 rev/mins the rotating speed, filtered and packaged, promptly get required A component;
During use, A, B two components are mixed, adjust to suitable viscosity and can construct.
Embodiment 2:
The anti-doodling and anti-affixing coating that present embodiment provides is made up of A, B two components, comprises following raw material by weight:
The A component:
The B component:
16 parts of MDI tripolymers
Wherein, the compound method of fluoroalkyl modified polyorganosiloxane is: under the room temperature 80g methylacrylic acid ten difluoro heptyl esters, solvent, catalyzer are joined in the reactor drum, stir and under the high pure nitrogen protection; Be warming up to 110 ℃; Drip the 13.2g polymethyl hydrogen siloxane then, reacted 16 hours, be cooled to room temperature then; Except that desolvating, obtain transparent, heavy-gravity fluoroalkyl modified polyorganosiloxane through rotary evaporation; Wherein the structural formula of polymethyl hydrogen siloxane is:
The method for preparing anti-doodling and anti-affixing coating is: Hydroxylated acrylic resin and color stuffing, auxiliary agent, organic solvent are joined in the shredder, under 2500 rev/mins rotating speed, grind 3h, grind and evenly process slurry; Then ground slurry is put in the high speed dispersor with the fluoroalkyl modified polyorganosiloxane, after disperseing 1.5 hours under 1000 rev/mins the rotating speed, filtered and packaged, promptly get required A component;
During use, A, B two components are mixed, adjust to suitable viscosity and can construct.
Embodiment 3:
The anti-doodling and anti-affixing coating that present embodiment provides is made up of A, B two components, comprises following raw material by weight:
The A component:
The B component:
18 parts of TDI tripolymers
Wherein, the compound method of fluoroalkyl modified polyorganosiloxane is: under the room temperature 100g vinylformic acid ten trifluoro monooctyl esters, solvent, catalyzer are joined in the reactor drum, stir and under the high pure nitrogen protection; Be warming up to 135 ℃; Drip the 15.6g polymethyl hydrogen siloxane then, reacted 8 hours, be cooled to room temperature then; Except that desolvating, obtain transparent, heavy-gravity fluoroalkyl modified polyorganosiloxane through rotary evaporation; Wherein the structural formula of polymethyl hydrogen siloxane is:
The method for preparing anti-doodling and anti-affixing coating is: Hydroxylated acrylic resin and color stuffing, auxiliary agent, organic solvent are joined in the shredder, under 2500 rev/mins rotating speed, grind 4h, grind and evenly process slurry; Then ground slurry is put in the high speed dispersor with the fluoroalkyl modified polyorganosiloxane, after disperseing 1.5 hours under 1000 rev/mins the rotating speed, filtered and packaged, promptly get required A component;
During use, A, B two components are mixed, adjust to suitable viscosity and can construct.
Embodiment 4:
The anti-doodling and anti-affixing coating that present embodiment provides is made up of A, B two components, comprises following raw material by weight:
The A component:
The B component:
19 parts of IPDI tripolymers
Wherein, the compound method of fluoroalkyl modified polyorganosiloxane is: under the room temperature 85g trifluoroethyl methacrylate, solvent, catalyzer are joined in the reactor drum, stir and under the high pure nitrogen protection; Be warming up to 160 ℃; Drip the 30.8g polymethyl hydrogen siloxane then, reacted 4 hours, be cooled to room temperature then; Except that desolvating, obtain transparent, heavy-gravity fluoroalkyl modified polyorganosiloxane through rotary evaporation; Wherein the structural formula of polymethyl hydrogen siloxane is:
The method for preparing anti-doodling and anti-affixing coating is: Hydroxylated acrylic resin and color stuffing, auxiliary agent, organic solvent are joined in the shredder, under 3000 rev/mins rotating speed, grind 4h, grind and evenly process slurry; Then ground slurry is put in the high speed dispersor with the fluoroalkyl modified polyorganosiloxane, after disperseing 2 hours under 1000 rev/mins the rotating speed, filtered and packaged, promptly get required A component;
During use, A, B two components are mixed, adjust to suitable viscosity and can construct.
With the paint spay-coating of the foregoing description 1~embodiment 4 on the base material of regulation; Behind the film-forming, formed paint film is carried out following technical feature test: outward appearance, hardness, sticking power, wear resistance, anti-neutral salt spray property, artificial ageing resistance, anti-liquid medium property, anti-solvent wiping property, anti-graffiti property, anti-adhibit quality.Each item The performance test results sees the following form:
Claims (10)
1. anti-doodling and anti-affixing coating, it is characterized in that being: said coating is made up of A, B two components, by weight,
The A component is:
4 ~ 20 parts of fluoroalkyl modified polyorganosiloxanes,
20 ~ 42 parts of Hydroxylated acrylic resins,
10 ~ 35 parts of color stuffings,
1 ~ 8 part of auxiliary agent,
10 ~ 36 parts of organic solvents,
The B component is 12 ~ 30 parts of polyisocyanate prepolymers;
The weight ratio of A component and B component is 2 ~ 8:1.
2. anti-doodling and anti-affixing coating according to claim 1 is characterized in that: the hydroxyl value of said Hydroxylated acrylic resin is 5 ~ 200mg KOH/g, and number-average molecular weight is 4000 ~ 50000.
3. anti-doodling and anti-affixing coating according to claim 1 is characterized in that: said color stuffing is one or more in aerosil, Rutile type Titanium Dioxide, anatase thpe white powder, ptfe micropowder, talcum powder, permanent white, lime carbonate, mica powder, aluminium powder or the hollow glass micropearl.
4. anti-doodling and anti-affixing coating according to claim 1 is characterized in that: said auxiliary agent is one or more in wetting dispersing agent, flow agent, skimmer, siccative, anti-wear agent, scratching resistant or the adhesion promoter.
5. anti-doodling and anti-affixing coating according to claim 1 is characterized in that: said organic solvent is the combination more than three kinds or three kinds in ritalin, vinyl acetic monomer, N-BUTYL ACETATE, toluene, p-Xylol, o-Xylol, m-xylene, 1-Methoxy-2-propyl acetate, ethylene glycol ether acetate, methylcarbonate, acetone, the pimelinketone.
6. anti-doodling and anti-affixing coating according to claim 1 is characterized in that: said polyisocyanate prepolymers is a kind of in HDI tripolymer, MDI tripolymer, IPDI tripolymer or the TDI tripolymer.
7. preparation method like the described anti-doodling and anti-affixing coating of claim 1-6 is characterized in that:
The preparation of said A component:
Hydroxylated acrylic resin and color stuffing, auxiliary agent, organic solvent are joined in the shredder, process slurry after the grinding evenly; Ground slurry is put in the high speed dispersor with the fluoroalkyl modified polyorganosiloxane, after disperseing 0.5 ~ 2 hour under 800 ~ 1500 rev/mins, filtered and packaged, promptly get required A component;
During use, A, B two components are mixed by 2 ~ 8:1 weight proportion and get final product.
8. the preparation method of anti-doodling and anti-affixing coating as claimed in claim 7; It is characterized in that: said fluoroalkyl modified polyorganosiloxane is by fluorinated acrylate monomer and polymethyl hydrogen siloxane synthetic obtaining under catalyst action, and its compound method is: under the room temperature fluorinated acrylate monomer, solvent, catalyzer are joined in the reactor drum, stir and under protection of inert gas; Be warming up to more than 80 ℃; Drip polymethyl hydrogen siloxane, reacted 2 ~ 30 hours, be cooled to room temperature then; Except that desolvating, obtain transparent, heavy-gravity fluoroalkyl modified polyorganosiloxane through rotary evaporation.
9. the preparation method of anti-doodling and anti-affixing coating as claimed in claim 8 is characterized in that: said fluorinated acrylate monomer is a kind of in trifluoroethyl methacrylate, vinylformic acid tetrafluoro propyl ester, tetrafluoropropyl propyl ester, vinylformic acid hexafluoro butyl ester, methylacrylic acid hexafluoro butyl ester, vinylformic acid octafluoro pentyl ester, methylacrylic acid octafluoro pentyl ester, dodecafluorhe-ptylacrylate, methylacrylic acid ten difluoro heptyl esters, vinylformic acid ten trifluoro monooctyl esters or the methylacrylic acid ten trifluoro monooctyl esters.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110401629.3A CN102516859B (en) | 2011-12-07 | 2011-12-07 | Anti-doodling and anti-affixing paint and its preparation method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110401629.3A CN102516859B (en) | 2011-12-07 | 2011-12-07 | Anti-doodling and anti-affixing paint and its preparation method |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102516859A true CN102516859A (en) | 2012-06-27 |
CN102516859B CN102516859B (en) | 2014-01-01 |
Family
ID=46287944
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201110401629.3A Expired - Fee Related CN102516859B (en) | 2011-12-07 | 2011-12-07 | Anti-doodling and anti-affixing paint and its preparation method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102516859B (en) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102731743A (en) * | 2012-06-26 | 2012-10-17 | 华烁科技股份有限公司 | Preparation of white thermosetting resin used for LED light having encapsulating film |
CN102786841A (en) * | 2012-08-24 | 2012-11-21 | 苏州金海薄膜科技发展有限公司 | Scratch-resistant and stain-repellent ink and preparation method thereof |
CN103113820A (en) * | 2013-03-13 | 2013-05-22 | 鹿尼德(上海)表面材料技术有限公司 | Double-component liquid protective paint |
CN103740220A (en) * | 2013-12-11 | 2014-04-23 | 甘肃大禹节水集团股份有限公司 | High-temperature-resistant burning-resistant under-film drip irrigation zone coating and preparation method thereof |
CN104017480A (en) * | 2014-06-24 | 2014-09-03 | 博罗县石湾美源涂料有限公司 | Acrylic polyurethane silicofluoride coating as well as preparation method and application method thereof |
CN104293018A (en) * | 2014-08-04 | 2015-01-21 | 荆门市鑫福瑞交通安全设施有限公司 | Low-surface-energy paint with hydrophobic self-cleaning function |
CN104356774A (en) * | 2014-11-21 | 2015-02-18 | 苏州大乘环保建材有限公司 | Water-based anti-doodling paint and preparation method thereof |
CN104448992A (en) * | 2014-11-19 | 2015-03-25 | 张洪吉 | Anti-scrawling water-based paint and preparation method thereof |
CN105176357A (en) * | 2015-10-21 | 2015-12-23 | 中航百慕新材料技术工程股份有限公司 | Water-based double-component anti-doodling paint |
CN105176358A (en) * | 2015-10-21 | 2015-12-23 | 中航百慕新材料技术工程股份有限公司 | Water-based anti-doodling paint |
CN105518081A (en) * | 2014-09-03 | 2016-04-20 | 新道公司 | Coating composition for preventing attachment of fliers, and coating method using same |
CN106398520A (en) * | 2016-09-30 | 2017-02-15 | 福建亿尚电气有限公司 | Light-reflecting anti-sticking nonskid paint and preparation method thereof |
CN107057427A (en) * | 2017-04-13 | 2017-08-18 | 江苏大使同丰涂料有限公司 | A kind of anti-sticking coating signposted and preparation method thereof |
CN107163728A (en) * | 2017-06-16 | 2017-09-15 | 安徽康瑞高科新材料技术工程有限公司 | A kind of ultrafast dry anti-graffiti coating |
CN108699203A (en) * | 2015-12-18 | 2018-10-23 | Hrl实验室有限责任公司 | The nonpolluting coating manufactured by the polymer of Coating Ions species |
CN109207041A (en) * | 2018-08-20 | 2019-01-15 | 安徽嘉智信诺化工股份有限公司 | A kind of aqueous anti-graffiti adhesion resistant paint |
CN109251612A (en) * | 2018-07-26 | 2019-01-22 | 广东雷邦高新材料有限公司 | A kind of organosilicon water paint and preparation method thereof |
CN109762457A (en) * | 2018-12-27 | 2019-05-17 | 耿佃勇 | Height is crosslinked anti-graffiti environmental protection coating material and preparation method thereof |
CN110922893A (en) * | 2019-11-21 | 2020-03-27 | 国网江西省电力有限公司电力科学研究院 | Hydrophobic self-cleaning anti-icing composite coating and preparation method thereof |
CN116855172A (en) * | 2023-07-13 | 2023-10-10 | 上海彩谷新材料科技有限公司 | Anti-graffiti anti-sticking protective paint and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030186066A1 (en) * | 2002-03-21 | 2003-10-02 | Degussa Ag | Air-drying silane coating compositions |
CN101781519A (en) * | 2009-12-22 | 2010-07-21 | 北京航材百慕新材料技术工程股份有限公司 | Transparent anti-graffiti dirt-resistant anti-weathering coating |
-
2011
- 2011-12-07 CN CN201110401629.3A patent/CN102516859B/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030186066A1 (en) * | 2002-03-21 | 2003-10-02 | Degussa Ag | Air-drying silane coating compositions |
CN101781519A (en) * | 2009-12-22 | 2010-07-21 | 北京航材百慕新材料技术工程股份有限公司 | Transparent anti-graffiti dirt-resistant anti-weathering coating |
Non-Patent Citations (2)
Title |
---|
《涂料工业》 20080131 宋秘钊等 "有机氟改性聚硅氧烷的研究" 1-10 第38卷, 第1期 * |
宋秘钊等: ""有机氟改性聚硅氧烷的研究"", 《涂料工业》 * |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102731743B (en) * | 2012-06-26 | 2014-05-07 | 华烁科技股份有限公司 | Preparation of white thermosetting resin used for LED light having encapsulating film |
CN102731743A (en) * | 2012-06-26 | 2012-10-17 | 华烁科技股份有限公司 | Preparation of white thermosetting resin used for LED light having encapsulating film |
CN102786841A (en) * | 2012-08-24 | 2012-11-21 | 苏州金海薄膜科技发展有限公司 | Scratch-resistant and stain-repellent ink and preparation method thereof |
CN103113820A (en) * | 2013-03-13 | 2013-05-22 | 鹿尼德(上海)表面材料技术有限公司 | Double-component liquid protective paint |
CN103740220B (en) * | 2013-12-11 | 2015-11-18 | 甘肃大禹节水集团股份有限公司 | A kind of high temperature resistant, anti-calcination under-film drip irrigation band coating and preparation method thereof |
CN103740220A (en) * | 2013-12-11 | 2014-04-23 | 甘肃大禹节水集团股份有限公司 | High-temperature-resistant burning-resistant under-film drip irrigation zone coating and preparation method thereof |
CN104017480A (en) * | 2014-06-24 | 2014-09-03 | 博罗县石湾美源涂料有限公司 | Acrylic polyurethane silicofluoride coating as well as preparation method and application method thereof |
CN104017480B (en) * | 2014-06-24 | 2016-06-15 | 博罗县石湾美源涂料有限公司 | A kind of fluorine silication acroleic acid polyurethane coating and preparation, application process |
CN104293018A (en) * | 2014-08-04 | 2015-01-21 | 荆门市鑫福瑞交通安全设施有限公司 | Low-surface-energy paint with hydrophobic self-cleaning function |
CN105518081A (en) * | 2014-09-03 | 2016-04-20 | 新道公司 | Coating composition for preventing attachment of fliers, and coating method using same |
CN105518081B (en) * | 2014-09-03 | 2017-09-01 | 新道公司 | For preventing from adhering to the coating composition of poster paper and utilizing its coating method |
CN104448992A (en) * | 2014-11-19 | 2015-03-25 | 张洪吉 | Anti-scrawling water-based paint and preparation method thereof |
CN104356774A (en) * | 2014-11-21 | 2015-02-18 | 苏州大乘环保建材有限公司 | Water-based anti-doodling paint and preparation method thereof |
CN105176357A (en) * | 2015-10-21 | 2015-12-23 | 中航百慕新材料技术工程股份有限公司 | Water-based double-component anti-doodling paint |
CN105176358A (en) * | 2015-10-21 | 2015-12-23 | 中航百慕新材料技术工程股份有限公司 | Water-based anti-doodling paint |
CN108699203A (en) * | 2015-12-18 | 2018-10-23 | Hrl实验室有限责任公司 | The nonpolluting coating manufactured by the polymer of Coating Ions species |
CN106398520A (en) * | 2016-09-30 | 2017-02-15 | 福建亿尚电气有限公司 | Light-reflecting anti-sticking nonskid paint and preparation method thereof |
CN107057427A (en) * | 2017-04-13 | 2017-08-18 | 江苏大使同丰涂料有限公司 | A kind of anti-sticking coating signposted and preparation method thereof |
CN107163728A (en) * | 2017-06-16 | 2017-09-15 | 安徽康瑞高科新材料技术工程有限公司 | A kind of ultrafast dry anti-graffiti coating |
CN109251612A (en) * | 2018-07-26 | 2019-01-22 | 广东雷邦高新材料有限公司 | A kind of organosilicon water paint and preparation method thereof |
CN109251612B (en) * | 2018-07-26 | 2021-11-19 | 广东雷邦高新材料有限公司 | Organic silicon water-based paint and preparation method thereof |
CN109207041A (en) * | 2018-08-20 | 2019-01-15 | 安徽嘉智信诺化工股份有限公司 | A kind of aqueous anti-graffiti adhesion resistant paint |
CN109762457A (en) * | 2018-12-27 | 2019-05-17 | 耿佃勇 | Height is crosslinked anti-graffiti environmental protection coating material and preparation method thereof |
CN110922893A (en) * | 2019-11-21 | 2020-03-27 | 国网江西省电力有限公司电力科学研究院 | Hydrophobic self-cleaning anti-icing composite coating and preparation method thereof |
CN116855172A (en) * | 2023-07-13 | 2023-10-10 | 上海彩谷新材料科技有限公司 | Anti-graffiti anti-sticking protective paint and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN102516859B (en) | 2014-01-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102516859B (en) | Anti-doodling and anti-affixing paint and its preparation method | |
CN105992785B (en) | Double-component paint composition and high corrosion resistance coating prepared therefrom | |
JP2013534961A (en) | Aliphatic polyurea coating, process for its production and use thereof | |
CN104530852B (en) | A kind of preparation method of photovoltaic component back plate with high hydrophobic fluorocarbon coating | |
CN101838505B (en) | Colored light-curing adhesive for adhering and sealing filled-words of metal keys and preparation method thereof | |
CN107298930A (en) | A kind of preparation of organic silicon polyurea self stratifying coating and application method | |
CN101553514A (en) | Functionalized polyurethane resin, method for the production thereof, and use thereof | |
CN103038299A (en) | Composition for use as coating material and adhesive, method for adhesive bonding, and laminated products | |
CN102558459A (en) | Optical ultraviolet curable resin composition, cured product and display device | |
CN106833164B (en) | A kind of fluororesin two-component coating and its application on photovoltaic component back plate | |
CN102031056A (en) | Coating as well as preparation method and use method thereof | |
CN102850553B (en) | Preparation method of modified polyester resin for coiled material coating material | |
CN103374246A (en) | Flexible uv-curable coating compositions | |
JP2018510233A (en) | Two-component coating composition for improving erosion resistance and coatings produced therefrom | |
CN106398523A (en) | Organosilicon coating agent and preparation method thereof | |
CN103687882A (en) | Light-curing resin composition, and plumbing member and functional panel using same | |
CN103917363A (en) | Multiple-layer edgebanding | |
CN109554107A (en) | A kind of UV light-cured type elasticity self-healing coatings | |
CN103709909A (en) | Powder paint applied to medium-density fiberboard, and preparation method and application thereof | |
CN103890027A (en) | Fluorinated water-oil repellency agents | |
CN104371086A (en) | Preparation method of ultraviolet-curing organosilane acrylic acid polyurethane | |
CN104910756A (en) | Modified nanometer titanium dioxide ultraviolet-curable coating | |
CN106318205A (en) | Organosilicon coating agent for external wall and preparation method of organosilicon coating agent | |
TWI606101B (en) | Coating composition and method of manufacturing the same | |
CN114292588B (en) | High-abrasion organic silicon coating and preparation method and application thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140101 Termination date: 20161207 |