CN103694896A - Air-drying colorful color-change raw lacquer coating and modulation method thereof - Google Patents
Air-drying colorful color-change raw lacquer coating and modulation method thereof Download PDFInfo
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- CN103694896A CN103694896A CN201410000391.7A CN201410000391A CN103694896A CN 103694896 A CN103694896 A CN 103694896A CN 201410000391 A CN201410000391 A CN 201410000391A CN 103694896 A CN103694896 A CN 103694896A
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Abstract
The invention belongs to the field of chemical treatment of coatings, and particularly relates to an air-drying colorful color-change raw lacquer coating and a modulation method thereof. The air-drying colorful color-change raw lacquer coating is characterized by being the raw lacquer coating prepared from a pearlescent pigment, quick dry refined lacquer and refined wood lacquer according to the weight ratio of 2:3:(4-6) in a mixing and stirring manner. The coating has excellent acid and alkali resistance, ultraviolet resistance, water tolerance, non-conducting property, non-magnetic property and the like, and can be applied to the fields such as lacquer craftwork, pseudo-classic architecture, cultural relic restoration, bedroom decoration, toys for children, food containers and the like.
Description
Technical field
The invention belongs to the chemical treatment field of coating, particularly a kind of self-drying type illusion-colour variable color raw lacquer coating and modulator approach.
Background technology
Raw lacquer is a kind of local product resource of China, have the laudatory title of " king of coating ".Raw lacquer paint film is hard, heat-resisting, corrosion-resistant, and lacquerware unearthed in the ancient tomb from 7000 is still excellent.But also there are some shortcomings in it, as alkali resistance, weathering resistance is poor, bad to metal adhesion, the paint aldehydes matter of raw lacquer easily causes human body skin irritated, and in actual applications raw lacquer also must be under specific temperature and humidity condition (relative humidity 70%-90%, temperature 25-35 ℃) could be dried, the bottleneck that this has more become raw lacquer to apply, therefore, the quick-drying problem that solves raw lacquer on the basis that does not affect raw lacquer characteristic property is the important content of raw lacquer Applied research fields always.
Three former good fortunes wait people (Japanese Laid-Open Patent Publication, clear 59-76580) to adopt short period of time UV Light and place a middle or short term at the air containing low concentration ozone, and drying varniss speed is accelerated.Test is 20 ℃ of temperature, and under relative humidity 80% condition, the drying varniss time shortens nearly 1/2 than traditional method, and paint film property keeps excellent.These have all seriously limited its range of application.At present, not yet find research and the patent documentation about illusion-colour variable color raw lacquer coating aspect.
Little wooden lacquer tree, claims again a family lacquer tree, and trunk is short and small, and growth is fast and the life-span is short, and output is high and the amount of setting seeds is few, and paint liquid is rare pure, moisture few, and oil content weight is low containing laccol amount, and dry property is little, and weather resistance is poor.Paint film is shiny black hard, has very strong sticking power, opacifying power and weather resistance, and water-fast, heat-resisting, wear-resisting and anti-corrosion.
It is the traditional culture of China that raw lacquer is coated with lacquer decorations skill, has the historic evolution of 7000.Raw lacquer is a kind of lacquer tree plant secretion thing, and pure natural is nontoxic, extensive industrial antisepsis coating and decorative paint as chemical industry, oil, military project, medicine, shipbuilding, papermaking, building, life staying idle at home articles for use, artwork etc.To masses, providing green, a nontoxic rich Color Life space, is that any chemical coating institute is irreplaceable.Raw lacquer, as a kind of natural paint, because its natural group in one's duty chief component material laccol is subacidity, adds that raw lacquer itself is with dark violet pigment, and other selection brings very large locality and selectivity to pigment class to give the allotment of colored paint in raw lacquer technique.Acid in raw lacquer easily reacts with most of various chemical pigments, causes title complex not shift from dry or form and aspect.Since history, in raw lacquer technique, selected natural mineral pigment as the color of the allotment raw lacquer such as cinnabar, orpiment, malachite green, azurite always; In recent years, fast development along with chemical industry, various chemical pigments fall over each other to emerge, and a lot of organic pigment (as green in phthalocyanine blue, the phthalein mountain valley with clumps of trees and bamboo etc.) and mineral-type pigment (as titanium dioxide, iron oxide red, iron oxide yellow etc.) are selected by raw lacquer technique, to the colour system of raw lacquer technique, have started the new situation.Historical raw lacquer technique, take red, black is dominant hue, color is single, organic chemistry pigment and inorganic chemistry pigment have been applied in recent years, it is abundant that form and aspect become, but also do not have a kind ofly can reappear soft raw lacquer pigment formula and modulator approach as that nature shellfish light class illusion-colour color and luster can be had a visual angle mobility or tool shusu.The present invention is according to the physics and chemistry feature of pearly pigment and be color characteristic, physico-chemical property and film-forming quality in conjunction with refining raw lacquer, be introduced in raw lacquer modulation toning, obtained self-drying type illusion-colour variable color raw lacquer coating, started a raw lacquer colorant new system, greatly enrich the coloured typies of raw lacquer coating, expanded the space of raw lacquer processed and applied.
Summary of the invention
The object of the invention is to improve for the modulator approach deficiency of existing raw lacquer, a kind of high-quality self-drying type illusion-colour variable color raw lacquer coating and modulator approach are provided, in time of drying and mechanical properties, improve a lot.
A kind of self-drying type illusion-colour of the present invention variable color raw lacquer coating, is characterized in that by by weight pearly pigment: quick-drying boiled urushi: refining little wood paint stirs well the raw lacquer coating of making for 2:3:4-6 mixing.
A kind of self-drying type illusion-colour variable color raw lacquer coating of the present invention, it is characterized in that described refining little wood paint is produced 7.5 minutes above high purity raw lacquer after naturally standing 30 days by little wooden lacquer tree, extract separated upper strata paint liquid, stir dehydration 72 hours, add absorbent cotton and mix rear with canequim press filtration formation boiled urushi.
A kind of self-drying type illusion-colour variable color raw lacquer coating of the present invention, it is characterized in that described quick-drying boiled urushi is 7.0 minutes above high-quality raw lacquer paints that produce with large wooden lacquer tree, canequim filters, under 20-30 ℃ of indoor dust-free environment, 12-18r/min stirs 5-7 days, to paint the liquid garnet, the abundant oxypolymerization viscosity of paint liquid of presenting unanimous between the higher and lower levels, strengthens and is as the criterion, and decocts dish and detects moisture moisture 12-15%, add the press filtration that stirs of 3% short staple cotton, sealing and standing 15 days.
A kind of self-drying type illusion-colour variable color raw lacquer coating of the present invention, is characterized in that described pearly pigment is the pigment of different-grain diameter mica chip coated metal oxide.
A kind of self-drying type illusion-colour variable color raw lacquer coating of the present invention, it is characterized in that modulator approach for adding pearly pigment on demand in quick-drying boiled urushi and refining little wood paint mixture, its ratio is pearly pigment by weight: quick-drying boiled urushi: refining little wooden paint=2:3:4-6, under the rotating speed of 25 revs/min, stir 30 minutes, mix and obtain self-drying type illusion-colour variable color raw lacquer coating.
A kind of self-drying type illusion-colour variable color raw lacquer coating of the present invention, is characterized in that by by weight pearly pigment: quick-drying boiled urushi: refining little wood paint stirs well the raw lacquer coating of making for 2:3:5 mixing.
A kind of self-drying type illusion-colour variable color raw lacquer coating of the present invention, is characterized in that described pearly pigment is the pigment of different-grain diameter mica chip cladding titanium dioxide or ferric oxide.
The present invention chooses the separated upper strata paint liquid of the standing extraction of little wooden lacquer tree institute's production of high purity raw lacquer process nature, stir again the filter of dehydration essence and form boiled urushi, then add on demand quick-drying boiled urushi and different pearly pigments, a kind of self-drying type illusion-colour variable color raw lacquer coating and modulator approach thereof are provided.
Self-drying type illusion-colour variable color raw lacquer coating and its technology of modulator approach thereof that the present invention is alleged are embodied as: it is by the separated upper strata paint liquid of the standing extraction of little wooden lacquer tree institute's production of high purity raw lacquer process nature, stir again the filter of dehydration essence and form boiled urushi, then add on demand different quick-drying boiled urushis and pearly pigment to disperse to stir to form.
The little wooden lacquer tree institute production of high purity raw lacquer of the self-drying type illusion-colour variable color raw lacquer coating that the present invention is alleged and modulator approach indication thereof refers to that 7.5 minutes above high purity raw lacquer that little wooden lacquer tree produces are after naturally standing 30 days, extract separated upper strata paint liquid, stir again the filter of dehydration essence and form boiled urushi, then add on demand quick-drying boiled urushi and different pearly pigments to disperse to stir to form.
The alleged lacquer tree of the present invention produce 7.0 and 7.5 refer to raw lacquer decoct dish mark, i.e. residuum except moisture.Be called for short 7.0 minutes or 7.5 minutes.
The self-drying type illusion-colour variable color raw lacquer coating of the self-drying type illusion-colour variable color raw lacquer coating that the present invention is alleged and modulator approach indication thereof refers at relative humidity 50-95%, under 5 ℃ of-40 ℃ of conditions of temperature, can certainly do the illusion-colour variable color raw lacquer coating of film forming.The little wooden lacquer tree institute production of high purity raw lacquer of indication refers to that 7.5 minutes above high purity raw lacquer that little wooden lacquer tree produces are after naturally standing 30 days, extract separated upper strata paint liquid, and its raw lacquer is stirred to dehydration 72 hours, add absorbent cotton and mix the rear canequim essence filter formation boiled urushi of using, then add on demand the pearly pigment of quick-drying boiled urushi and different meshes different model to disperse to stir to form.Self-drying type illusion-colour variable color raw lacquer coating and modulator approach thereof are the pearly pigments adding on the basis of refining little wood paint.The pearly pigment of indication is that pearly pigment mainly be take the coated mica chip of thin oxide layer that titanium dioxide and ferric oxide be representative and formed.The pearly pigment that pearly pigment has comprised different meshes and different model.Described pearly pigment mainly be take the coated mica chip of thin oxide layer that titanium dioxide and ferric oxide be representative and is formed.The mica chip that it has comprised different-grain diameter and be coated on the titanium dioxide of various thickness above mica chip and the various metal oxides that ferric oxide is representative.The addition manner of the pearly pigment adding stirs 30 minutes under 15-25 rev/min of rotating speed.
The invention has the beneficial effects as follows that this coating has fabulous acid and alkali-resistance, UV resistant, water-fast, non-conductive, the premium properties such as magnetic conduction not, can be used for the fields such as lacquer craftwork, building in the style of the ancients, historical relic reparation, interior decoration, toy for children, food product containers.
The coating that the present invention produces has the advantages such as short, sticking power time of drying, snappiness and impact strength are good, acidproof, high temperature resistant, as a kind of coating, at aspects such as industrial container pipeline, artwork production, historical relic's protection and furniture applications, has better application prospect.
Embodiment
Below by embodiment, the present invention is further described in detail, but this can not be interpreted as to the scope of above-mentioned theme of the present invention only limits to following example.All technology realizing based on foregoing of the present invention all belong to technical scope of the present invention.
Embodiment 1: the manly little wooden lacquer tree of collecting is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and chameleon series pearlescence, model is T10-01, and particle diameter is 15-50um, under 15 revs/min of rotating speeds, stirs 30 minutes.Be prepared into and film, form purple-silvery white-green-blue unreal self-drying type illusion-colour variable color raw lacquer coating.
Embodiment 2: the manly little wooden lacquer tree of collecting is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and chameleon series pearlescence, model is T10-06, and particle diameter 20-100um stirs 30 minutes under 15 revs/min of rotating speeds.Be prepared into and film, form red-Jin-copper-green self-drying type illusion-colour variable color raw lacquer coating.
Embodiment 3: the manly little wooden lacquer tree of collecting is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and silvery white serial pearlescence, model is 108, particle diameter 10um, and order number 1200 stirs 30 minutes under 15 revs/min of rotating speeds.Be prepared into and film, form pearliness self-drying type illusion-colour raw lacquer coating.
Embodiment 4: the manly little wooden lacquer tree of collecting is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and silvery white serial pearlescence, model is 123, particle diameter 25um, and order number 800 stirs 30 minutes under 15 revs/min of rotating speeds.Be prepared into and film, form soft pearly-lustre pool self-drying type illusion-colour raw lacquer coating.
Embodiment 5: the manly little wooden lacquer tree of collecting is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and silvery white serial pearlescence, model is 425B, particle diameter 60um, and order number, 400, under 15 revs/min of rotating speeds, stir 30 minutes.Be prepared into and film, form the sapphire blue self-drying type illusion-colour of illusion-colour raw lacquer coating.
Embodiment 6: the little wooden lacquer tree in Jianshi of collection is produced to 7.8 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and silvery white serial pearlescence, model is 425B, particle diameter 60um, and order number, 400, under 15 revs/min of rotating speeds, stir 30 minutes.Be prepared into and film, form the sapphire blue self-drying type illusion-colour of illusion-colour raw lacquer coating.
Embodiment 7: the little wooden lacquer tree in Jianshi of collection is produced to 7.8 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and chameleon series pearlescence, model is T10-01, and particle diameter is 15-50um, under 15 revs/min of rotating speeds, stirs 30 minutes.Be prepared into and film, form purple-silvery white-green-blue unreal self-drying type illusion-colour variable color raw lacquer coating.
Embodiment 8: the little wooden lacquer tree in Jianshi of collection is produced to 7.8 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and chameleon series pearlescence, model is T10-06, and particle diameter 20-100um stirs 30 minutes under 15 revs/min of rotating speeds.Be prepared into and film, form red-Jin-copper-green self-drying type illusion-colour variable color raw lacquer coating.
Embodiment 9: the little wooden lacquer tree in Jianshi of collection is produced to 7.8 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and silvery white serial pearlescence, model is 108, particle diameter 10um, and order number 1200 stirs 30 minutes under 15 revs/min of rotating speeds.Be prepared into and film, form pearliness self-drying type illusion-colour raw lacquer coating.
Embodiment 10: the little wooden lacquer tree of lamp stand of collection is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and chameleon series pearlescence, model is T10-01, and particle diameter is 15-50um, under 15 revs/min of rotating speeds, stirs 30 minutes.Be prepared into and film, form purple-silvery white-green-blue unreal self-drying type illusion-colour variable color raw lacquer coating.
Embodiment 11: the little wooden lacquer tree of lamp stand of collection is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and chameleon series pearlescence, model is T10-06, and particle diameter 20-100um stirs 30 minutes under 15 revs/min of rotating speeds.Be prepared into and film, form red-Jin-copper-green self-drying type illusion-colour variable color raw lacquer coating.
Embodiment 12: the little wooden lacquer tree of lamp stand of collection is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and silvery white serial pearlescence, model is 108, particle diameter 10um, and order number 1200 stirs 30 minutes under 15 revs/min of rotating speeds.Be prepared into and film, form pearliness self-drying type illusion-colour raw lacquer coating.
Embodiment 13: the little wooden lacquer tree of lamp stand of collection is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and silvery white serial pearlescence, model is 425B, particle diameter 60um, and order number, 400, under 15 revs/min of rotating speeds, stir 30 minutes.Be prepared into and film, form the sapphire blue self-drying type illusion-colour of illusion-colour raw lacquer coating.
Embodiment 14: the soaring little wooden lacquer tree of collecting is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and chameleon series pearlescence, model is T10-01, and particle diameter is 15-50um, under 15 revs/min of rotating speeds, stirs 30 minutes.Be prepared into and film, form purple-silvery white-green-blue unreal self-drying type illusion-colour variable color raw lacquer coating.
Embodiment 15: the soaring little wooden lacquer tree of collecting is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and chameleon series pearlescence, model is T10-06, and particle diameter 20-100um stirs 30 minutes under 15 revs/min of rotating speeds.Be prepared into and film, form red-Jin-copper-green self-drying type illusion-colour raw lacquer coating.
Embodiment 16: the soaring little wooden lacquer tree of collecting is produced to 7.5 minutes above high purity raw lacquer after naturally standing 30 days, extract separated upper strata paint liquid.And by its raw lacquer stirring dehydration 72 hours, add absorbent cotton and mix rear with canequim essence filter formation boiled urushi.Add quick-drying boiled urushi and silvery white serial pearlescence, model is 425B, particle diameter 60um, and order number, 400, under 15 revs/min of rotating speeds, stir 30 minutes.Be prepared into and film, form the sapphire blue self-drying type illusion-colour of illusion-colour raw lacquer coating.
Self-drying type illusion-colour variable color raw lacquer coating is applied to glass on-chip testing time of drying with 75um, is applied to test mechanical performance on tinplate, the results are shown in Table 1, table 2:
Table 1 self-drying type illusion-colour variable color raw lacquer coating time of drying
Table 2 self-drying type illusion-colour variable color raw lacquer coating measuring mechanical property
17 1 kinds of self-drying type illusion-colour variable color raw lacquer coatings of embodiment, by weight pearly pigment: quick-drying boiled urushi: refining little wood paint stirs well for 2:3:5 mixes the raw lacquer coating of making.Refining little wood paints and is produced 7.5 minutes above high purity raw lacquer after naturally standing 30 days by little wooden lacquer tree, extracts separated upper strata paint liquid, stirs dehydration 72 hours, adds absorbent cotton and mixes rear with canequim press filtration formation boiled urushi.Quick-drying boiled urushi is 7.0 minutes above high-quality raw lacquer paints that produce with large wooden lacquer tree, canequim filters, under 20-30 ℃ of indoor dust-free environment, 12-18r/min stirs 5-7 days, with the paint liquid garnet, the abundant oxypolymerization viscosity of paint liquid of presenting unanimous between the higher and lower levels, strengthen and be as the criterion, decoct dish and detect moisture moisture 12-15%, add the press filtration that stirs of 3% short staple cotton, sealing and standing 15 days.Pearly pigment is the pigment of different-grain diameter mica chip cladding titanium dioxide or ferric oxide.Modulator approach for adding pearly pigment on demand in quick-drying boiled urushi and refining little wood paint mixture, and its ratio, by weight stirring under the rotating speed of 25 revs/min 30 minutes, mixes and obtain self-drying type illusion-colour variable color raw lacquer coating.This coating has fabulous acid and alkali-resistance, UV resistant, water-fast, non-conductive, the premium properties such as magnetic conduction not, can be used for the fields such as lacquer craftwork, building in the style of the ancients, historical relic reparation, interior decoration, toy for children, food product containers.
Claims (6)
1. a self-drying type illusion-colour variable color raw lacquer coating, is characterized in that by by weight pearly pigment: quick-drying boiled urushi: refining little wood paint stirs well the raw lacquer coating of making for 2:3:4-6 mixing.
2. a kind of self-drying type illusion-colour variable color raw lacquer coating according to claim 1, it is characterized in that described refining little wood paint is produced 7.5 minutes above high purity raw lacquer after naturally standing 30 days by little wooden lacquer tree, extract separated upper strata paint liquid, stir dehydration 72 hours, add absorbent cotton and mix rear with canequim press filtration formation boiled urushi.
3. a kind of self-drying type illusion-colour variable color raw lacquer coating according to claim 1, it is characterized in that described quick-drying boiled urushi is 7.0 minutes above high-quality raw lacquer paints that produce with large wooden lacquer tree, canequim filters, under 20-30 ℃ of indoor dust-free environment, 12-18r/min stirs 5-7 days, to paint the liquid garnet, the abundant oxypolymerization viscosity of paint liquid of presenting unanimous between the higher and lower levels, strengthens and is as the criterion, and decocts dish and detects moisture moisture 12-15%, add the press filtration that stirs of 3% short staple cotton, sealing and standing 15 days.
4. a kind of self-drying type illusion-colour variable color raw lacquer coating according to claim 1, is characterized in that described pearly pigment is the pigment of different-grain diameter mica chip coated metal oxide.
5. a kind of self-drying type illusion-colour variable color raw lacquer coating according to claim 1, it is characterized in that modulator approach for adding pearly pigment on demand in quick-drying boiled urushi and refining little wood paint mixture, its ratio is pearly pigment by weight: quick-drying boiled urushi: refining little wooden paint=2:3:4-6, under the rotating speed of 25 revs/min, stir 30 minutes, mix and obtain self-drying type illusion-colour variable color raw lacquer coating.
6. a kind of self-drying type illusion-colour variable color raw lacquer coating according to claim 1, is characterized in that by by weight pearly pigment: quick-drying boiled urushi: refining little wood paint stirs well the raw lacquer coating of making for 2:3:5 mixing.7, a kind of self-drying type illusion-colour variable color raw lacquer coating according to claim 4, is characterized in that described pearly pigment is the pigment of different-grain diameter mica chip cladding titanium dioxide or ferric oxide.
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| CN105602307A (en) * | 2016-03-02 | 2016-05-25 | 沈阳化工大学 | Waterproof transparent coating for protecting cultural relic |
| CN106675217A (en) * | 2016-12-20 | 2017-05-17 | 东来涂料技术（上海）有限公司 | Automotive special paint containing chameleon pearlescent pigments and preparation method of automotive special paint |
| CN107163847A (en) * | 2017-06-14 | 2017-09-15 | 湖北宝石花工艺品有限公司 | A kind of modulator approach of colored raw lacquer coating |
| CN113799529A (en) * | 2021-10-11 | 2021-12-17 | 福建省艺术馆(福建省非物质文化遗产保护中心) | Temp-sensing color-changing making process for Thangka lacquer painting and Temp-sensing color-changing Thangka lacquer painting |
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| CN107163847A (en) * | 2017-06-14 | 2017-09-15 | 湖北宝石花工艺品有限公司 | A kind of modulator approach of colored raw lacquer coating |
| CN113799529A (en) * | 2021-10-11 | 2021-12-17 | 福建省艺术馆(福建省非物质文化遗产保护中心) | Temp-sensing color-changing making process for Thangka lacquer painting and Temp-sensing color-changing Thangka lacquer painting |
| CN113799529B (en) * | 2021-10-11 | 2022-07-05 | 福建省艺术馆(福建省非物质文化遗产保护中心) | Temp-sensing color-changing making process for Thangka lacquer painting and Temp-sensing color-changing Thangka lacquer painting |
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