CN1344297A - 制备可去除的自净表面的方法 - Google Patents

制备可去除的自净表面的方法 Download PDF

Info

Publication number
CN1344297A
CN1344297A CN00805310A CN00805310A CN1344297A CN 1344297 A CN1344297 A CN 1344297A CN 00805310 A CN00805310 A CN 00805310A CN 00805310 A CN00805310 A CN 00805310A CN 1344297 A CN1344297 A CN 1344297A
Authority
CN
China
Prior art keywords
salient
self
hydrophobic material
hydrophobic
cleaning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN00805310A
Other languages
English (en)
Inventor
威廉·巴思洛特
克里斯托弗·奈恩休斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7902402&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1344297(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of CN1344297A publication Critical patent/CN1344297A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • C09D191/06—Waxes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B17/00—Methods preventing fouling
    • B08B17/02—Preventing deposition of fouling or of dust
    • B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B17/00—Methods preventing fouling
    • B08B17/02—Preventing deposition of fouling or of dust
    • B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
    • B08B17/065—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement the surface having a microscopic surface pattern to achieve the same effect as a lotus flower
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/056—Forming hydrophilic coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/06—Coating with compositions not containing macromolecular substances
    • C08J7/065—Low-molecular-weight organic substances, e.g. absorption of additives in the surface of the article
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/008—Temporary coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/32—Processes for applying liquids or other fluent materials using means for protecting parts of a surface not to be coated, e.g. using stencils, resists
    • B05D1/322—Removable films used as masks
    • B05D1/327—Masking layer made of washable film
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]

Abstract

本发明涉及用于制备自净表面的方法,该表面具有凸出部和凹部,凸出部之间的间距为0.1－200μm,凸出部的高度为0.1－100μm,该方法中涂敷含疏水材料的溶液、分散液或乳化液,并接着进行干燥,在溶剂蒸发时,经自结构形成自净表面,并且所涂敷的材料是用洗涤剂可去除的。

Description

制备可去除的自净表面的方法
本发明涉及一种制备自净表面的方法。
物体表面的净化有很大的技术和经济意义，并且部分由于光学和美学的原因和部分由于技术原因，特别是在涉及透光表面时，为保持其功能必须时常进行净化。
已进行过大量努力以制造可排斥尘粒和/或自净化的表面。聚合物薄膜或聚合物板的生产商力求去解决此问题，其方法是制备尽可能光的表面和使表面或者特别疏水或者特别亲水。例如由特别疏水的聚四氟乙烯形成的表面或特别亲水的“无滴涂层”，在该涂层上水和尘粒以不成滴流走。
CH-PS-268258描述了疏水表面，它与水的接触角为120°。可通过在基底上涂敷粉末如陶土、滑石、粘土或硅胶而达到，并且该粉末预先经有机硅化合物的疏水处理。该涂敷与可固化树脂一起进行或由含有机溶剂的溶液进行。但该方法不能制备持久性的疏水表面。同时也未指出粉末的粒度或粒度分布。如此得到的表面的性质与旱金莲的叶面进行比较。比较中要指出的是，旱金莲的叶面的特性的根据是不知的，而且在技术上也不可分析。最近完成的研究表明，旱金莲具有特别细的超结构，其结构单元小于2μm。
US-P-3354022描述了一种疏水表面，该表面有凸凹，并且空气含量至少为60％，这样达到表面接触角大于90°。
DE-PS-1023217描述了一种制备有粗糙表面的成型体的模具。该模具可用于由橡胶或塑料制造有粗糙表面的成型部件。模具的壁涂敷有粗刚玉粉末和烘漆。该模具制备的产品带有随机出现的凹痕，并因此有改进的粘附性能，甚至避免了通常硫化表层。如此所得的表面例如有很好的可书写性。因为肯定不能用流动水进行自净化。
JP-A-62-191447描述了一种提高表面疏水性的方法。因此，涂敷一层等离子体聚合物薄膜，该薄膜通过蚀刻粗糙化，并且再涂敷第二层等离子体聚合物薄膜。
JP-A-3-174279(摘要)描述了一种在纸或薄膜上制备无光泽装饰表面的方法。该表面是通过漆制造的，该漆以电离辐射固化，并以非特定性的方式施加上非特定的图案。然后经进一步辐照完全固化。
申请人的深入研究导致了意外的结果，即在技术上有可能人工地使物体表面可自净化，就是以人工的方法提供由凸凹构成的表面结构，要注意的是表面结构的凸出部之间的距离为0.1-200μm，优选0.1-100μm，并且凸出部的高度为0.1-100μm，优选0.1-50μm，还要注意的是凸出部是由疏水聚合物或半疏水材料构成，并且要注意该凸出部不可通过水或通过带洗涤剂的水去除(参看WO 96/04123)。
本发明的目的是研制一种制备自净表面的方法，该表面可被洗涤溶液去除。该目的通过权利要求1的特征部分实现的。
用于制备具有凸凹的、且凸出部之间的距离为0.1-200μm和凸出部高度为0.1-100μm的自净表面的本发明方法是基于在表面上涂敷疏水材料并接着进行干燥，该材料在溶剂蒸发时经自结构而形成自净表面，所涂敷的材料可用洗涤剂水溶液去除。这种疏水材料可以是溶液、分散液或乳化液。
“用洗涤剂可去除”意指所涂敷的材料通过洗涤剂水溶液的作用，至少是长期作用下，会由于溶解作用使至少部分所涂敷的材料去除。本发明所涂敷的材料也可通过机械力去除，如通过刷、刮或用水高压清洁。
在一个实施方案中，该疏水材料是蜡，它经自结构形成自净的微结构表面。
在另一个实施方案中，该溶液、分散液或乳化液含有固体微粒。当其与疏水材料如蜡同时使用时，其本身可以是疏水的或亲水的。
疏水材料的涂敷可通过喷雾如借助喷雾嘴或喷雾枪来进行。根据所计划应用的类型，还具有疏油性的疏水材料是有利的。
还有一种可能的方法是借助于用水的共输送将疏水材料输送过可渗透蒸汽的表面。
适合本发明的疏水材料包括特别是长链仲醇和链烷二醇、β-二酮、仲酮和长链烷。特别合适的是二十九烷-10-醇、二十九烷-7，10-二醇、二十九烷-5，10-二醇、三十一烷-12，14-二酮、三十一烷-8，10-二酮、棕榈酮和其它疏水物质，它们可溶于挥发性溶剂中，并在溶剂蒸发时通过自结构形成疏水性的防水表面。
一种在物体上的透明的且出自光学、美学或技术的原因其透明性可保持长时间的自净表面特别具有技术的重要性。特别包括建筑物、车辆、太阳能集流器等的玻璃制品。如果自净特性仅暂时需要如在储存或运输期间，但另外情况下又是不需要的如出自美观的原因，则该自净表面的可去除性是特别重要的。
屋面、屋顶、纪念碑和货亭以及贮仓、罐或管道的内涂层的自净表面的制备也是具有经济及技术意义的，这些表面层或含有水溶液或可用流动的水容易地不留残余物地净化。车辆如轿车、火车或飞机的外涂层也是很有利的。
如果表面结构的凸出部互相离得很近，以避免在凸出部之间的凹部与水滴接触，这样可达到最佳结果。如果表面的结构的凸出部相距太近，或其凹部不够深，则表面就成为封闭的表面，并且能较好地被润湿。因此要力求达到底面上的凸出物的高度随凸出部之间距离的增加而增加。至今的测量表明，凸出部的间距及高度在权利要求的范围内可达到好的结果。其凸出部的高度为0.1-50μm，并且凸出部的间距为0.1-100μm的表面有最佳结果。
本发明将通过下列实施例阐明。
实施例1：
将三十一烷-14，16-二酮在己烷或乙酸乙酯中的0.1％的溶液借助于喷雾嘴或喷雾枪喷雾到任意表面上。在溶剂的蒸发过程中，三十一烷-14，16-二酮通过自结构形成细管状的晶体，其大部分的直径为0.2μm，长度为0.5-5μm。通过涂敷，可润湿的表面变成疏水的，并且接触角增加到160°。从这类表面可用流动水洗去沾污的颗粒，并且从长期看，该涂层本身也是可去除的。为增加涂层的粗糙度，可在溶液中混入亲水粉末(如石英粉)或疏水粉末(如聚四氟乙烯)。
实施例2：
将市售石膏以1∶10∶2(重量％)的比例与水和硅酮盐(Wacker BS15)混合，接着用刷子或辊子涂敷。在干燥时形成微粗糙的表面，其结构由石膏的针形晶体确定。在水蒸发后，用一层疏水剂覆盖。这类表面上的接触角超过150°。
实施例3：
将市售石膏以1∶10∶0.5(重量％)的比例与水和硅酮盐(WackerSilikon WI)混合，接着用喷雾枪涂敷。在干燥时形成微粗糙的表面，其结构由石膏的针形晶体确定。在水蒸发后，用一层疏水剂覆盖。这类表面上的接触角超过150°。
实施例4：
在透水蒸汽的聚合物(如聚氨酯)的一面上涂以蜡类物质(如三十一烷-14，16-二酮)，该类物质的特征是可形成结构(参看实施例1)。如果使水通过该聚合物，则蜡会被共输送，并在表面上形成所需要的微结构。
通过足够大量的蜡，在该体系中也可达到一定的耐用性，因其受损的或受侵蚀的结构在一段时间内可再生。

Claims (10)

1.一种用于制备自净表面的方法，该表面具有凸出部和凹部，凸出部之间的间距为0.1-200μm，凸出部的高度为0.1-100μm，该方法中，涂敷含疏水材料的溶液、分散液或乳化液并接着进行干燥，在溶剂蒸发时通过自结构形成自净表面，该所涂敷的材料是用洗涤剂可去除的。
2.权利要求1的方法，其特征在于，该疏水材料是蜡。
3.权利要求1的方法，其特征在于，该疏水材料是蜡类物质，如伯醇或仲醇和链烷二醇、β-二酮、仲酮和长链烷。
4.权利要求1的方法，其特征在于，该溶液、分散液或乳化液含有固体微粒。
5.权利要求1-4至少之一的方法，其特征在于，通过喷雾涂敷溶液、分散液或乳化液。
6.权利要求5的方法，其特征在于，通过喷雾嘴或喷雾枪进行涂敷。
7.权利要求1-6至少之一的方法，其特征在于，该疏水材料还是疏油的。
8.一种具有带凸凹的表面的物体，其凸出部之间的间距为0.1-200μm，凸出部的高度为0.1-100μm，而且至少该凸出部是疏水的，并且该凸出部由固体微粒组成，该表面上覆盖有疏水的材料。
9.仲醇和链烷醇、β-二酮、仲酮和长链烷在制备自净表中的应用。
10.权利要求9的应用，其特征在于，采用二十九烷-10-醇、二十九烷-7，10-二醇、二十九烷-5，10-二醇、三十一烷-12，14-二酮、三十一烷-8，10-二酮或棕榈酮作为疏水材料。
CN00805310A 1999-03-25 2000-03-18 制备可去除的自净表面的方法 Pending CN1344297A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19913602 1999-03-25
DE19913602.5 1999-03-25

Publications (1)

Publication Number Publication Date
CN1344297A true CN1344297A (zh) 2002-04-10

Family

ID=7902402

Family Applications (1)

Application Number Title Priority Date Filing Date
CN00805310A Pending CN1344297A (zh) 1999-03-25 2000-03-18 制备可去除的自净表面的方法

Country Status (24)

Country Link
US (2) US20050136217A1 (zh)
EP (1) EP1171529B1 (zh)
JP (1) JP2002540283A (zh)
KR (1) KR20020000792A (zh)
CN (1) CN1344297A (zh)
AT (1) ATE245681T1 (zh)
AU (1) AU765310B2 (zh)
BG (1) BG105920A (zh)
CA (1) CA2368204C (zh)
CZ (1) CZ20013361A3 (zh)
DE (1) DE50003003D1 (zh)
DK (1) DK1171529T3 (zh)
EE (1) EE200100494A (zh)
ES (1) ES2203450T3 (zh)
HR (1) HRP20010699A2 (zh)
HU (1) HUP0200452A2 (zh)
NO (1) NO20014618L (zh)
PL (1) PL191143B1 (zh)
PT (1) PT1171529E (zh)
RU (1) RU2246514C2 (zh)
SK (1) SK285771B6 (zh)
WO (1) WO2000058410A1 (zh)
YU (1) YU67701A (zh)
ZA (1) ZA200107800B (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101626840B (zh) * 2006-12-18 2012-05-09 罗地亚管理公司 有利于清除建筑材料上的覆盖层和/或污垢的处理
CN104349850A (zh) * 2012-02-29 2015-02-11 麻省理工学院 用于修改在表面上冷凝的物件和方法
CN108554988A (zh) * 2011-08-05 2018-09-21 麻省理工学院 采用液体浸渍表面的装置
CN110142189A (zh) * 2019-04-08 2019-08-20 深圳市劢全新材料科技有限责任公司 一种涂覆方法及其在耐高温涂层涂覆中的应用

Families Citing this family (75)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10106242A1 (de) * 2001-02-10 2002-08-14 Aloys Wobben Vorrichtung zum Entsalzen von Wasser mit der Umkehrosmose
DE10117945A1 (de) * 2001-04-10 2002-10-24 Stiftung A Wegener Inst Polar Biozidfreie Antifouling-Beschichtung
DE10118345A1 (de) 2001-04-12 2002-10-17 Creavis Tech & Innovation Gmbh Eigenschaften von Strukturbildnern für selbstreinigende Oberflächen und die Herstellung selbiger
DE10118346A1 (de) * 2001-04-12 2002-10-17 Creavis Tech & Innovation Gmbh Textile Flächengebilde mit selbstreinigender und wasserabweisender Oberfläche
DE10118349A1 (de) * 2001-04-12 2002-10-17 Creavis Tech & Innovation Gmbh Selbstreinigende Oberflächen durch hydrophobe Strukturen und Verfahren zu deren Herstellung
DE10118348A1 (de) * 2001-04-12 2002-10-17 Creavis Tech & Innovation Gmbh Polymerfaser mit selbstreinigender und wasserabweisender Oberfläche
DE10118352A1 (de) 2001-04-12 2002-10-17 Creavis Tech & Innovation Gmbh Selbstreinigende Oberflächen durch hydrophobe Strukturen und Verfahren zu deren Herstellung
DE10124076C1 (de) * 2001-05-14 2002-10-10 Fraunhofer Ges Forschung Verfahren zur Herstellung von hydrophoben bis hydrophilen Oberflächen
DE10134477A1 (de) 2001-07-16 2003-02-06 Creavis Tech & Innovation Gmbh Selbstreinigende Oberflächen durch hydrophobe Strukturen und Verfahren zu deren Herstellung
DE10159767A1 (de) * 2001-12-05 2003-06-18 Degussa Verfahren zur Herstellung von Gegenständen mit antiallergischen Oberflächen
DE10160055A1 (de) * 2001-12-06 2003-06-18 Degussa Diffus reflektierende Oberflächen zu deren Herstellung
DE10160054A1 (de) * 2001-12-06 2003-06-18 Degussa Lichtstreuende Werkstoffe die selbstreinigende Oberflächen aufweisen
DE10162457A1 (de) * 2001-12-19 2003-07-03 Degussa Oberflächenstrukturierte Einbauten für Mehrphasentrennapparate
DE10205007A1 (de) * 2002-02-07 2003-08-21 Creavis Tech & Innovation Gmbh Verfahren zur Herstellung von Schutzschichten mit schmutz- und wasserabweisenden Eigenschaften
EP1475426B1 (de) 2003-04-24 2006-10-11 Goldschmidt GmbH Verfahren zur Herstellung von ablösbaren schmutz- und wasserabweisenden flächigen Beschichtungen
DE10356752A1 (de) 2003-12-04 2005-06-30 Roche Diagnostics Gmbh Beschichtete Testelemente
US8034173B2 (en) 2003-12-18 2011-10-11 Evonik Degussa Gmbh Processing compositions and method of forming the same
US8974590B2 (en) 2003-12-18 2015-03-10 The Armor All/Stp Products Company Treatments and kits for creating renewable surface protective coatings
US7828889B2 (en) 2003-12-18 2010-11-09 The Clorox Company Treatments and kits for creating transparent renewable surface protective coatings
US7650848B2 (en) * 2004-02-17 2010-01-26 University Of Florida Research Foundation, Inc. Surface topographies for non-toxic bioadhesion control
US9016221B2 (en) 2004-02-17 2015-04-28 University Of Florida Research Foundation, Inc. Surface topographies for non-toxic bioadhesion control
WO2005090490A2 (en) * 2004-03-17 2005-09-29 The Lubrizol Corporation Method to use an emulsified material as a coating
DE102004025368A1 (de) 2004-05-19 2005-12-08 Basf Ag Verfahren zur Herstellung von strukturierten Oberflächen
US7722951B2 (en) * 2004-10-15 2010-05-25 Georgia Tech Research Corporation Insulator coating and method for forming same
DE102004062739A1 (de) * 2004-12-27 2006-07-06 Degussa Ag Selbstreinigende Oberflächen mit durch hydrophobe Partikel gebildeten Erhebungen, mit verbesserter mechanischer Festigkeit
KR100710444B1 (ko) * 2005-02-24 2007-04-24 주식회사 엘지화학 도어용 합성수지 판넬 및 그 제조방법
US20080221009A1 (en) * 2006-01-30 2008-09-11 Subbareddy Kanagasabapathy Hydrophobic self-cleaning coating compositions
US20090018249A1 (en) * 2006-01-30 2009-01-15 Subbareddy Kanagasabapathy Hydrophobic self-cleaning coating compositions
US20080221263A1 (en) * 2006-08-31 2008-09-11 Subbareddy Kanagasabapathy Coating compositions for producing transparent super-hydrophobic surfaces
US8258206B2 (en) 2006-01-30 2012-09-04 Ashland Licensing And Intellectual Property, Llc Hydrophobic coating compositions for drag reduction
DE102006007800B3 (de) * 2006-02-20 2007-10-04 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Strukturierungsverfahren und Bauteil mit einer strukturierten Oberfläche
US20090011222A1 (en) * 2006-03-27 2009-01-08 Georgia Tech Research Corporation Superhydrophobic surface and method for forming same
US20070231542A1 (en) * 2006-04-03 2007-10-04 General Electric Company Articles having low wettability and high light transmission
DE102006050365A1 (de) * 2006-10-25 2008-04-30 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Strukturierte Oberfläche mit schaltbarer Haftfähigkeit
AU2006351753B2 (en) * 2006-12-11 2012-12-20 Essity Hygiene And Health Aktiebolag Absorbent article with a strongly hydrophobic layer
AT504995B1 (de) * 2007-03-02 2011-12-15 Fabian Ferdinand Dipl Ing Dr Vorrichtung zur aufbereitung von wasser
FR2913231B1 (fr) * 2007-03-02 2009-07-10 Essilor Int Article ayant une surface nanotexturee a proprietes superhydrophobes.
EP1978063A1 (en) * 2007-04-05 2008-10-08 YKI, Ytkemiska Institutet AB An aqueous hydrophobic coating composition comprising a fatty acid or a salt thereof
US20080245273A1 (en) * 2007-04-05 2008-10-09 Jouko Vyorkka Hydrophobic coatings
US20080250978A1 (en) * 2007-04-13 2008-10-16 Baumgart Richard J Hydrophobic self-cleaning coating composition
ES2444703T3 (es) * 2007-06-29 2014-02-26 Cellutech Ab Métodos para preparar superficies superhidrofóbicas sobre cuerpos sólidos mediante soluciones de expansión rápida
EP2011630A1 (de) 2007-07-03 2009-01-07 F. Hoffmann-La Roche AG Verfahren zur Herstellung eines Analyseelementes
EP2011629A1 (de) 2007-07-03 2009-01-07 F. Hoffman-la Roche AG Verfahren zur Herstellung eines mikrofluiden Systems auf einer Polymeroberfläche
US20090064894A1 (en) * 2007-09-05 2009-03-12 Ashland Licensing And Intellectual Property Llc Water based hydrophobic self-cleaning coating compositions
EP2143337A1 (de) 2008-07-09 2010-01-13 Bayer MaterialScience AG Wachshaltige Lacke
CN102245314B (zh) 2008-11-11 2014-11-19 佛罗里达大学研究基金会有限公司 图案化表面的方法以及包含该表面的制品
DE102009013315A1 (de) 2009-03-18 2010-09-23 Sasol Germany Gmbh Beschichtungen unter Einsatz von Dialkyl-/Dialkenylethern als Hydrophobierungsmittel, deren Verwendung und Metalle versehen mit der Beschichtung
US8147607B2 (en) 2009-10-26 2012-04-03 Ashland Licensing And Intellectual Property Llc Hydrophobic self-cleaning coating compositions
DE102009051598B4 (de) 2009-11-02 2022-10-06 Vereinigung zur Förderung des Instituts für Kunststoffverarbeitung in Industrie und Handwerk an der Rhein.-Westf. Technischen Hochschule Aachen e.V. Verfahren zur Herstellung von Vorrichtungen mit Mikrostrukturen aus Kunststoff mittels Verstreckung zum Zwecke der Selbstreinigung, derartige Vorrichtungen und deren Verwendung
DE102010024559A1 (de) 2010-06-22 2011-12-22 Süd-Chemie AG Verfahren zur Herstellung hydrophober Oberflächen
US9675994B2 (en) 2011-06-01 2017-06-13 The University Of North Carolina At Chapel Hill Superhydrophobic coatings and methods for their preparation
US9937655B2 (en) 2011-06-15 2018-04-10 University Of Florida Research Foundation, Inc. Method of manufacturing catheter for antimicrobial control
EP2739564A1 (en) * 2011-08-03 2014-06-11 Massachusetts Institute Of Technology Articles for manipulating impinging liquids and methods of manufacturing same
US9309162B2 (en) 2012-03-23 2016-04-12 Massachusetts Institute Of Technology Liquid-encapsulated rare-earth based ceramic surfaces
IN2014DN08699A (zh) 2012-03-23 2015-05-22 Massachusetts Inst Technology
US20130337027A1 (en) 2012-05-24 2013-12-19 Massachusetts Institute Of Technology Medical Devices and Implements with Liquid-Impregnated Surfaces
US9625075B2 (en) 2012-05-24 2017-04-18 Massachusetts Institute Of Technology Apparatus with a liquid-impregnated surface to facilitate material conveyance
JP2015525132A (ja) 2012-06-13 2015-09-03 マサチューセッツ インスティテュート オブ テクノロジー 表面上の液体を浮上させるための物品および方法ならびにそれを組み入れたデバイス
US20140178611A1 (en) 2012-11-19 2014-06-26 Massachusetts Institute Of Technology Apparatus and methods employing liquid-impregnated surfaces
CN109719109B (zh) 2012-11-19 2023-01-06 麻省理工学院 采用液体浸渍表面的装置和方法
DE102012022782A1 (de) * 2012-11-22 2013-12-24 Heidelberger Druckmaschinen Ag Reinigungsmittel zum gleichzeitigen Reinigen und Beschichten von Oberflächen
WO2014097309A1 (en) 2012-12-17 2014-06-26 Asian Paints Ltd. Stimuli responsive self cleaning coating
CA2901023A1 (en) 2013-02-15 2014-08-21 Massachusetts Institute Of Technology Grafted polymer surfaces for dropwise condensation, and associated methods of use and manufacture
KR20150143734A (ko) 2013-04-16 2015-12-23 메사추세츠 인스티튜트 오브 테크놀로지 에멀젼 및 기타 혼합물의 단극 분리를 위한 시스템 및 방법
US9585757B2 (en) 2013-09-03 2017-03-07 Massachusetts Institute Of Technology Orthopaedic joints providing enhanced lubricity
US20150179321A1 (en) 2013-12-20 2015-06-25 Massachusetts Institute Of Technology Controlled liquid/solid mobility using external fields on lubricant-impregnated surfaces
US9947481B2 (en) 2014-06-19 2018-04-17 Massachusetts Institute Of Technology Lubricant-impregnated surfaces for electrochemical applications, and devices and systems using same
US9546284B1 (en) 2014-07-10 2017-01-17 Hkc-Us, Llc Dust prevention compositions, coatings and processes of making
EP3287388A4 (en) * 2015-04-24 2018-12-19 Toyo Seikan Co., Ltd. Structure having externally added region on surface
CN109070155A (zh) * 2016-03-23 2018-12-21 Bsh家用电器有限公司 具有自洁表面的家用器具及用于制造该家用器具的方法
IT201700047751A1 (it) * 2017-05-03 2018-11-03 Bridgestone Corp Mescola in gomma per porzioni di battistrada
DE102017008415A1 (de) 2017-08-19 2019-02-21 Hescoat GmbH Antihaftbeschichtung
EP3797671A1 (en) * 2019-09-26 2021-03-31 Ambu A/S A tip part for an endoscope and the manufacture thereof
IT202000016276A1 (it) * 2020-07-06 2022-01-06 Bridgestone Europe Nv Sa Battistrada ad elevato drenaggio
RU202433U1 (ru) * 2020-10-19 2021-02-17 Федеральное государственное бюджетное образовательное учреждение высшего образования "Вятский государственный университет" Нетокопроводящая шлифовальная щетка для токосъемных колец и коллекторов электрических машин

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH268258A (fr) * 1946-07-30 1950-08-16 Rhone Poulenc Chemicals Revêtement hydrofuge.
US3354022A (en) * 1964-03-31 1967-11-21 Du Pont Water-repellant surface
US4183757A (en) * 1974-03-13 1980-01-15 The British Petroleum Company Limited Treatment of underwater surfaces
US4808323A (en) * 1986-10-01 1989-02-28 Federal-Mogul Corporation Non-deleterious dry film lubricant coating composition, rubber sealing element coated therewith; and method of
DK53391D0 (da) * 1991-03-25 1991-03-25 Isoline As Fremgangsmaade til semiautomatisk rengoering og konservering af overflader og middel til brug ved fremgangsmaaden
US5492881A (en) * 1994-03-25 1996-02-20 Diamond; Charles M. Sorbent system
US6660363B1 (en) * 1994-07-29 2003-12-09 Wilhelm Barthlott Self-cleaning surfaces of objects and process for producing same
JPH08131941A (ja) * 1994-09-13 1996-05-28 Kao Corp 基材表面への撥水性付与方法
JPH10156282A (ja) * 1996-11-28 1998-06-16 Seimi Chem Co Ltd 撥水撥油性金属材料
EP0887179B1 (en) * 1996-12-09 2005-12-21 Nippon Sheet Glass Co., Ltd. Non-fogging article and process for the production thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101626840B (zh) * 2006-12-18 2012-05-09 罗地亚管理公司 有利于清除建筑材料上的覆盖层和/或污垢的处理
CN108554988A (zh) * 2011-08-05 2018-09-21 麻省理工学院 采用液体浸渍表面的装置
CN104349850A (zh) * 2012-02-29 2015-02-11 麻省理工学院 用于修改在表面上冷凝的物件和方法
CN110142189A (zh) * 2019-04-08 2019-08-20 深圳市劢全新材料科技有限责任公司 一种涂覆方法及其在耐高温涂层涂覆中的应用

Also Published As

Publication number Publication date
JP2002540283A (ja) 2002-11-26
PT1171529E (pt) 2003-12-31
SK13402001A3 (sk) 2002-05-09
US20070098957A1 (en) 2007-05-03
HUP0200452A2 (en) 2002-11-28
EP1171529B1 (de) 2003-07-23
KR20020000792A (ko) 2002-01-05
HRP20010699A2 (en) 2002-12-31
NO20014618L (no) 2001-09-25
EE200100494A (et) 2002-12-16
RU2246514C2 (ru) 2005-02-20
YU67701A (sh) 2003-08-29
DK1171529T3 (da) 2003-11-03
SK285771B6 (sk) 2007-08-02
ES2203450T3 (es) 2004-04-16
DE50003003D1 (de) 2003-08-28
US20050136217A1 (en) 2005-06-23
ATE245681T1 (de) 2003-08-15
AU765310B2 (en) 2003-09-18
BG105920A (en) 2002-05-31
CA2368204A1 (en) 2000-10-05
CZ20013361A3 (cs) 2002-02-13
WO2000058410A1 (de) 2000-10-05
PL191143B1 (pl) 2006-03-31
EP1171529A1 (de) 2002-01-16
ZA200107800B (en) 2002-05-29
PL350945A1 (en) 2003-02-24
AU4106300A (en) 2000-10-16
CA2368204C (en) 2008-09-09
NO20014618D0 (no) 2001-09-24

Similar Documents

Publication Publication Date Title
CN1344297A (zh) 制备可去除的自净表面的方法
CN1307007C (zh) 产生具有防污和拒水性能的保护层的方法
ES2271144T3 (es) Superficies autolimpiables por estructuras hidrofobas y procedimiento para su preparacion.
US6858284B2 (en) Surfaces rendered self-cleaning by hydrophobic structures, and process for their production
Wen et al. Biomimetic polymeric superhydrophobic surfaces and nanostructures: from fabrication to applications
JPH10507695A (ja) 物体の自己浄化性表面とその形成方法
Jia et al. Efficiently texturing hierarchical epoxy layer for smart superhydrophobic surfaces with excellent durability and exceptional stability exposed to fire
JP4988196B2 (ja) 自浄性表面及びその製造法
Huang et al. Solvent-free fabrication of robust superhydrophobic powder coatings
JP2002038102A (ja) 難湿性表面を形成するための組成物
Ma et al. A facile spraying method for fabricating superhydrophobic leather coating
CN101984751B (zh) 用于复合元件的再生性表面性能
Yilgoer Superhydrophobic polymer surfaces: preparation, properties and applications
KR100208908B1 (ko) 다중피복의특수효과를갖는피복물을제조하고복구시키는방법
Raju et al. A Review of Recent Advances in the Development of Superhydrophobicity over Various Substrate Surfaces Using Polymers
Roach et al. Superhydrophobicity and Self‐Cleaning
CN113913564A (zh) 一种激光刻蚀模板法制备自清洁皮革面料的方法
US20050049328A1 (en) Surface film with depositing function, the production and use thereof
CN205239327U (zh) 一种车用后视镜
CN1068583A (zh) “图文、彩塑”保护剂及其生产工艺

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication