CN1614129A - Bactericidal and anti-virus fabrics and its production and garment for patients therefrom - Google Patents

Bactericidal and anti-virus fabrics and its production and garment for patients therefrom Download PDF

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Publication number
CN1614129A
CN1614129A CN 200310103149 CN200310103149A CN1614129A CN 1614129 A CN1614129 A CN 1614129A CN 200310103149 CN200310103149 CN 200310103149 CN 200310103149 A CN200310103149 A CN 200310103149A CN 1614129 A CN1614129 A CN 1614129A
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CN
China
Prior art keywords
fabric
titanium oxide
coating
compound
sterilizing
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CN 200310103149
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Chinese (zh)
Inventor
刘必前
李兰
杜京儒
董伟
刘依娜
钟明成
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ZHONGKE ANKANG MEDICAL PRODUCTS CO Ltd BEIJING
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ZHONGKE ANKANG MEDICAL PRODUCTS CO Ltd BEIJING
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Application filed by ZHONGKE ANKANG MEDICAL PRODUCTS CO Ltd BEIJING filed Critical ZHONGKE ANKANG MEDICAL PRODUCTS CO Ltd BEIJING
Priority to CN 200310103149 priority Critical patent/CN1614129A/en
Publication of CN1614129A publication Critical patent/CN1614129A/en
Pending legal-status Critical Current

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Abstract

A sterilizing antivirus fabric with super amphophobic nature features that the super amphophobic layer and the sterilizing layer are coated on one or two surface of said fabric. Its preparing process and the medical clothes made of it are also disclosed.

Description

Ultra-amphosphobic sterilizing disease-preventing poison fabric and method for making thereof and be used for medical patient's gown
Technical field
The invention belongs to the medical protective material field, particularly ultra-amphosphobic sterilizing disease-preventing poison fabric and method for making thereof, and this ultra-amphosphobic sterilizing disease-preventing poison fabric is used to prepare medical patient's gown.
Background technology
Hospital is the place of curing the sickness to save the patient, and all kinds of sufferer personnel are also carrying various bacteriums and germ, therefore very easily causes cross infection, brings huge threat for people's health.The use of medical protective material provides to the personnel that work in this environment avoids germ invasion and attack, convenient safe safeguard measure.People use protective materials setting " filtration barrier " together, and the harmful substance that environment brought is played the filtration buffer action, make bacterium, virus and various harmful materials etc. can not enter human body.Because some germ is very indomitable, and mainly by body fluid, transmitted by droplets and direct contact, thus require protective materials will possess the killing pathogenic bacteria function, and kill the bacterium ability and be eager to excel and just can reach good protection effect.
Super two thin fabric, its surface has the function of super-hydrophobic and super oleophobic.This function can stop each pseudo body fluid (as blood, sputum, excreta etc.) to infiltrate the opposite side of fabric, thereby has effectively stoped the diffusion of bacterium and virus; Simultaneously germ can be prevented, and condition and the chance that bacterium grows up and breeds can be avoided offering attached to fabric face.
Nano-TiO 2Photochemical catalyst has the function of kill bacteria, because its specific area is bigger, when running into bacterium, at first with the germ adsorption filtration on its surface, the cell of directtissima bacterium subsequently causes the organic matter degradation in the bacterial cell, with this kill bacteria, and make it to decompose.Nano-TiO 2It is high and lasting that the photo-catalyst agent has antimicrobial efficiency, and good advantages such as security.Utilize natural daylight, normal temperature and pressure to get final product catalytic decomposition germ and pollutant, wide accommodation.
Studies show that TiO 2The photo-catalyst agent is to staphylococcus aureus, Escherichia coli, and bacillus subtilis and streptococcus mutans all have higher sterilizing rate, even cancer cell can be killed.Nano-TiO 2Also different mould (as aspergillus flavus, aspergillus niger, Sai Shi aspergillus, Aspergillus terreus, aspergillus ustus, Chaetomium globosum, multi-trunk natalensis, Penicillium citrinum, Paecilomyces varioti, Trichoderma viride) also there is the good sterilization effect.
Inorganic antiseptic has contact-type, broad-spectrum antiseptic, and lasting, water-fast, acid and alkali-resistance are harmless to the health, characteristics such as non-secondary pollution, are widely used at present.As its antibiotic mechanism of silver ion is that silver ion carries out haptoreaction, causes the total composition of microorganism to destroy or produce dysfunction.When the silver ion of trace arrives the microbial cell film, because of the latter electronegative, rely on Coulomb attraction, make both firm adsorption filtrations, silver is from entering in the born of the same parents in the penetration cell wall, and with the sulfydryl reaction, make protein coagulating, destroy the activity of cell synzyme, cell is lost the division growth ability and death.Silver ion can also destroy microorganisms electric transmission system, respiratory system and substance delivery system.
Summary of the invention
One of purpose of the present invention provides a kind of ultra-amphosphobic sterilizing disease-preventing poison fabric, with the cross infection problem between the present patient of hospital of better solution, provides a kind of dress materials of highly effective and safe for vast patient.
Two of purpose of the present invention provides ultra-amphosphobic sterilizing disease-preventing poison process for making such fabric.
Three of purpose of the present invention provides the patient's gown with the malicious textile of ultra-amphosphobic sterilizing disease-preventing comfortable and easy to wear, well behaved hospital.
Four of purpose of the present invention provides ultra-amphosphobic sterilizing disease-preventing poison fabric and is used to prepare medical personnel's safety device.
Ultra-amphosphobic sterilizing disease-preventing of the present invention poison fabric is with organically the be combined with each other textile material of formation of super two thin fabric coatings and sterilizing fabric coating, is that super two thin fabric coatings and sterilizing coating organically are combined in fabric face and/or the fabric.The one side of its fabric is super two thin fabric coatings, and another side is the sterilizing fabric coating;
Or the two sides of fabric is the sterilizing fabric coating, is outward super two thin fabric coatings at the sterilizing fabric coating of fabric one side.
Ultra-amphosphobic sterilizing disease-preventing poison process for making such fabric of the present invention comprises the following steps:
(1) the super two thin fabric coatings of preparation;
(3) preparation sterilizing fabric coating;
Adopt the method for coating or spraying to prepare the two thin fabric coatings of excess of export, prepare the sterilizing fabric coating at another side in the one side of fabric;
Or adopt the method for coating or spraying all to prepare the sterilizing fabric coating on the two sides of fabric, outside the sterilizing fabric coating of fabric one side, adopt the method for coating or spraying to prepare the two thin fabric coatings of excess of export.
When the method that adopts coating or spraying when fabric face prepares coating, its feed liquid also will be penetrated in the fabric, obtain super two thin fabric coating and sterilizing coating in fabric.
Super two thin fabric coatings of the present invention: it has and does not get wet and the surface of oily dirt free, can be according to the Organic fluoride finishing agents that uses in the Chinese patent application number 01141502.9, and adopt the method for coating or spraying to handle and obtain.Resulting fabric has a ultra-amphosphobic.
Described Organic fluoride finishing agent is the aqueous systems of the isopropyl alcohol of the magnesium chloride of crosslinking agent, 0~0.1g/L of the organic fluorine that contains 10~70g/L, 0~7g/L and 0~30g/L.
Described top finish condition is:
Working solution: Organic fluoride finishing agent 50~70wt%
Thickener 2~5wt%
Defoamer 1~2wt%
It is 8~9 that ammoniacal liquor is transferred pH
Surplus is a water
Coating process: to fabric or article coatings, carry out preliminary drying under the room temperature, 70~90 ℃ of preliminary drying temperature, preliminary drying time 5~30min cures then, and 100~130 ℃ of stoving temperatures cure time 1~4min.
Described spraying finishing condition is:
Working solution: Organic fluoride finishing agent
Spray art: to fabric spraying, carry out preliminary drying under the room temperature, 70~90 ℃ of preliminary drying temperature, preliminary drying time 5~30min cures then, and 100~130 ℃ of stoving temperatures cure time 1~4min.
Sterilizing fabric coating of the present invention is that fabric face is coated with the nano-titanium oxide antiseptic, or the compound antiseptic of nano-titanium oxide, and the content of the compound of nano-titanium oxide or nano-titanium oxide is 4~30g/m in the fabric 2
The making of sterilizing fabric coating of the present invention is to finish by following method.Can be with the nano-titanium oxide antiseptic, or the compound antiseptic of nano-titanium oxide is made into certain density colloidal sol, handle to obtain through the method for coating or spraying.
The antiseptic aqueous solution that described antiseptic colloidal sol solid content is 5~90g/L or the system of suspension.
Described top finish condition is:
Working solution: antiseptic 5~20wt%
Thickener 2~5wt%
Defoamer 1~2wt%
It is 8~9 that ammoniacal liquor is transferred pH
Surplus is a water
Coating process: to fabric coating, carry out preliminary drying under the room temperature, 70~90 ℃ of preliminary drying temperature, preliminary drying time 5~30min cures then, and 100~130 ℃ of stoving temperatures cure time 1~4min.
Described spraying finishing condition is:
Working solution: antiseptic colloidal sol
Spray art: to fabric spraying, carry out preliminary drying under the room temperature, 70~90 ℃ of preliminary drying temperature, preliminary drying time 5~30min cures then, and 100~130 ℃ of stoving temperatures cure time 1~4min.
Organic fluorine of the present invention is an acrylic acid fluorohydrocarbon esters resin, as the Unidyne TG of the Scotchgard FC of Minnesota Mining and Manufacturing Company, the Zepel of E.I.Du Pont Company, Japanese dog metal working industry Co., Ltd., the Asahigard AG of Asahi Glass company or the Oleophobol C of vapour crust etc.No matter organofluorine compound in water or in organic solvent, can reduce the surface tension of solution significantly, show excellent hydrophobicity and oleophobic property.The surface tension of Organic fluoride finishing agent is very low, and its wettability and penetrability are good, can be easy to wetting and sprawl on the surface of various different materials.And the stable performance of Organic fluoride finishing agent, the fabric after the arrangement can keep good hand feeling and excellent gas permeability.
Described crosslinking agent is crosslinking agent EH (producing as Shanghai the May 4th auxiliary reagent factory), crosslinking agent MH (producing as Dalian city light industry research institute), melmac or hydroxymethyl-2 dihydroxy-ethylene urea (2D resin) etc.
Described defoamer is silicone based defoamer, as organic silicon defoaming agent RJ-03 (production of Beijing chemical industry two factories), silicone defoaming agent DYXBG-03 (production of Shijiazhuang, Hebei Toyo Chemicals Co. Ltd.) or defoaming lubricant SAF (production of auxiliary reagent factory, Shanghai) etc.; The alkyl ether phosphate class is as defoamer GP (production of auxiliary reagent factory, Shanghai); The mixture of alkyl phosphate and silicone oil is as defoamer DP (the big magnificent chemical industry in Xi'an, Shaanxi Co., Ltd produces) etc.
Described thickener is an acrylic thickener, as thickener HD (production of auxiliary reagent factory, Shanghai), thickener P-91 (production of auxiliary reagent factory, Shenyang, Liaoning), synthetic thickening agent PF (production of east wind adhensive factory, changzhou city), synthetic thickening agent CB-21 (production of Yantai, Shandong printing and dyeing assistant factory) or thickener 8201 (production of Nantong chemical institute trial (demonstration) plant) etc.
The compound antiseptic of nano-titanium oxide of the present invention comprise titanium oxide and silica compound, titanium oxide and zinc oxide compound, titanium oxide and iron oxide compound, be doped with iron ion titanium oxide, be doped with the titanium oxide of nitrogen element etc.Titanium oxide wherein: the compound of silica, titanium oxide: zinc oxide composites or titanium oxide: the mol ratio of the compound of iron oxide is 1~2.5: 1; Be doped with iron ion titanium oxide, be doped with the titanium oxide of nitrogen element, wherein the mol ratio of iron ion and titanium oxide is 1: 1~90, the mol ratio of nitrogen element and titanium oxide is 1: 1~95.
The consumption of described super two thin fabric coatings and sterilizing fabric coating colloidal sol or solution is as the criterion for they are sticked on the fabric securely.
Will super two thin fabric coatings and the sterilizing coating organically be combined in fabric face or the fabric, with the patient's clothes or the safety device of this textile hospital, make patient's clothes and safety device have the function of sterilized antiviral and blocking-up proliferation of germs approach.
The specific embodiment
The invention will be further described below in conjunction with embodiment, and cited embodiment is not to be limited embodiment.
Embodiment 1
Get pure-cotton fabric 20cm 2Sample, at room temperature, above-mentioned fabrics is sprayed with the aqueous systems that contains Japan AGC AG-710 organic fluorine 70g/L, put baking oven then into, 70 ℃ of preliminary dryings 30 minutes, continue to cure 4 minutes at 100 ℃, obtain having the fabric of single face ultra-amphosphobic.
This fabric is being sprayed to the non-super two processing one sides of dredging of above-mentioned fabrics with the aqueous systems of 1: 2 mixed of weight ratio with 10wt% nano-titanium oxide colloidal sol and 5wt% zinc oxide antiseptic colloidal sol, put baking oven then into, oven dry obtains ultra-amphosphobic sterilizing disease-preventing poison fabric.
The pure cotton fabric good hand touch of made, Quine's method is adopted in the patient's gown antibacterial fabric test of made.Get one deck above-mentioned fabrics, bacterium liquid is directly dripped on two-layer cotton yarn, cover, judge its bacteriostasis according to the bacteriostasis rate size with culture medium.The result was 〉=99% to colibacillary killing rate after 10 minutes, and resistance to hydrostatic pressure is 20cmH 2O.
Embodiment 2
Get polyester-cotton blend lining 20cm 2Sample, at room temperature, above-mentioned fabrics is sprayed with the aqueous systems that contains Japan AGC AG-710 organic fluorine 70g/L, put baking oven then into, 70 ℃ of preliminary dryings 30 minutes, continue to cure 4 minutes at 100 ℃, obtain having the fabric of single face ultra-amphosphobic.
Again to this textile sterilizing coating, be with nano-titanium oxide: the mol ratio of zinc oxide composites is the colloidal sol that 1: 1 nano-titanium oxide compound is made into 6wt%, spray to stating the non-super two processing one sides of dredging of fabric, put baking oven then into, oven dry obtains ultra-amphosphobic sterilizing disease-preventing poison fabric, and wherein the compound content of titanium oxide and zinc oxide is 4~30g/m in the sterilizing coating 2
The material antibacterial tests of made adopts Quine's method.Get one deck fabric, cover, judge its bacteriostasis according to the bacteriostasis rate size with culture medium.The result was 〉=99% to colibacillary killing rate after 5 minutes, and resistance to hydrostatic pressure is 20cmH 2O.
Embodiment 3
The pure cotton knitting product are cut into the square sample of 25cm, carry out top finish with the working solution of following composition.
Working solution is formed: Organic fluoride finishing agent 60wt%
Thickener P-91 5wt%
Silicone defoaming agent RJ-03 2wt%
It is 8 that ammoniacal liquor is transferred pH
Surplus is a water
Wherein the Organic fluoride finishing agent is to contain Japan AGC AG-480 organic fluorine 40g/L, the aqueous systems of magnesium chloride 0.1g/L and isopropyl alcohol 30g/L.
Under the room temperature pure cotton knitting product are carried out coating, put baking oven then into,, continue to cure 1 minute, obtain having the fabric of single face ultra-amphosphobic at 130 ℃ 90 ℃ of preliminary dryings 5 minutes.
Described sterilizing coating is that nano-titanium oxide and silica compound antiseptic are made into the colloidal sol that concentration is 5wt%, antiseptic colloidal sol is sprayed on non-super two the dredging of fabric handles one side, obtains ultra-amphosphobic sterilizing disease-preventing poison fabric after the drying.Wherein nano-titanium oxide and silica compound content are 4~30g/m in the sterilizing tissue layer 2, nano-titanium oxide: the mol ratio of silica compound is 2: 1.
Antibacterial tests adopts Quine's method.Get one deck fabric, bacterium liquid is directly dripped on fabric, cover, judge its bacteriostasis according to the bacteriostasis rate size with culture medium.The result is 〉=99% to colibacillary killing rate behind 10min, and resistance to hydrostatic pressure is 20cmH 2O.
Embodiment 4
Get polyester-cotton blend lining 20cm 2Sample, this textile sterilizing coating is handled, the iron oxide compound antiseptic of nano-titanium oxide is made into the colloidal sol that concentration is 6wt%, spray to above-mentioned fabrics is two-sided, put baking oven then into, oven dry obtains the sterilizing coating.Wherein the compound content of nano-titanium oxide and iron oxide is 4~30g/m 2, nano-titanium oxide: the mol ratio of iron oxide compound is 1: 1.
Again at room temperature, with the aqueous systems that contains Japan AGC AG-7000 organic fluorine 70g/L the one side of above-mentioned fabrics is sprayed, put baking oven then into, 70 ℃ of preliminary dryings 30 minutes, continuation was cured 4 minutes at 100 ℃, obtained having the fabric of single face ultra-amphosphobic.
The material antibacterial tests of made adopts Quine's method.Get one deck fabric, cover, judge its bacteriostasis according to the bacteriostasis rate size with culture medium.The result was 〉=99% to colibacillary killing rate after 5 minutes, and resistance to hydrostatic pressure is 20cmH 2O.
Embodiment 5
Get pure-cotton fabric 20cm 2Sample, this fabric is simultaneously sprayed to above-mentioned fabrics with the aqueous systems that 10wt% is doped with the titanium oxide sol of iron ion, wherein the mol ratio of iron ion and titanium oxide is 1: 2, puts baking oven then into, oven dry obtains the sterilizing coating.
At room temperature, with the aqueous systems that contains Japan AGC AG-480 organic fluorine 70g/L the unprocessed one side of above-mentioned fabrics is sprayed, put baking oven then into, 70 ℃ of preliminary dryings 30 minutes, continuation was cured 4 minutes at 100 ℃, obtained having the fabric of single face ultra-amphosphobic.
Antibacterial tests adopts Quine's method.Get one deck fabric, bacterium liquid is directly dripped on fabric, cover, judge its bacteriostasis according to the bacteriostasis rate size with culture medium.The result was 〉=99% to colibacillary killing rate after 10 minutes, and resistance to hydrostatic pressure is 20cmH 2O.

Claims (9)

1. ultra-amphosphobic sterilizing disease-preventing poison fabric, be will super two thin fabric coatings and the sterilizing fabric coating textile material that organically is combined with each other and forms, it is characterized in that: described textile material be that super two thin fabric coatings and sterilizing coating organically are combined in fabric face and/or the fabric.
2. fabric as claimed in claim 1 is characterized in that: described fabric simultaneously is super two thin fabric coatings, and another side is the sterilizing fabric coating;
Or the two sides of fabric is the sterilizing fabric coating, is outward super two thin fabric coatings at the sterilizing fabric coating of fabric one side.
3. fabric as claimed in claim 1 or 2, it is characterized in that: described sterilizing coating is that fabric face is coated with the nano-titanium oxide antiseptic, or the compound antiseptic of nano-titanium oxide, the content of the compound of nano-titanium oxide or nano-titanium oxide is 4~30g/m in the fabric 2
4. fabric as claimed in claim 3 is characterized in that: the compound of described nano-titanium oxide comprise titanium oxide and silica compound, titanium oxide and zinc oxide compound, titanium oxide and iron oxide compound, be doped with iron ion titanium oxide, be doped with the titanium oxide of nitrogen element; Titanium oxide wherein: the compound of silica, titanium oxide: zinc oxide composites or titanium oxide: the mol ratio of the compound of iron oxide is 1~2.5: 1; Be doped with iron ion titanium oxide, be doped with the titanium oxide of nitrogen element, wherein the mol ratio of iron ion and titanium oxide is 1: 1~90, the mol ratio of nitrogen element and titanium oxide is 1: 1~95.
5. one kind as each described process for making such fabric of claim 1~5, and it is characterized in that: described process for making such fabric comprises the following steps:
(1) the super two thin fabric coatings of preparation;
(3) preparation sterilizing fabric coating;
Adopt the method for coating or spraying to prepare the two thin fabric coatings of excess of export, prepare the sterilizing fabric coating at another side in the one side of fabric;
Or adopt the method for coating or spraying all to prepare the sterilizing fabric coating on the two sides of fabric, outside the sterilizing fabric coating of fabric one side, adopt the method for coating or spraying to prepare the two thin fabric coatings of excess of export.
6. method as claimed in claim 5 is characterized in that: the making of described sterilizing tissue layer is with the nano-titanium oxide antiseptic, or nano-titanium oxide compound antiseptic is made into colloidal sol, handles obtaining through the method for coating or spraying;
The antiseptic aqueous solution that described antiseptic colloidal sol solid content is 5~90g/L or the system of suspension;
Described top finish condition is:
Working solution: antiseptic 5~20wt%
Thickener 2~5wt%
Defoamer 1~2wt%
It is 8~9 that ammoniacal liquor is transferred pH
Surplus is a water
Coating process: to fabric coating, carry out preliminary drying under the room temperature, 70~90 ℃ of preliminary drying temperature are cured then, 100~130 ℃ of stoving temperatures
Described spraying finishing condition is:
Working solution: antiseptic colloidal sol
Spray art: to fabric spraying, carry out preliminary drying under the room temperature, 70~90 ℃ of preliminary drying temperature are cured then, 100~130 ℃ of stoving temperatures.
7. as claim 5 or 6 described methods, it is characterized in that: described sterilizing coating is to contain the nano-titanium oxide antiseptic in the fabric, or containing the compound antiseptic of nano-titanium oxide, the content of the compound of nano-titanium oxide or nano-titanium oxide is 4~30g/m in the fabric 2
8. fabric as claimed in claim 7 is characterized in that: the compound of described nano-titanium oxide comprise titanium oxide and silica compound, titanium oxide and zinc oxide compound, titanium oxide and iron oxide compound, be doped with iron ion titanium oxide, be doped with the titanium oxide of nitrogen element; Titanium oxide wherein: the compound of silica, titanium oxide: zinc oxide composites or titanium oxide: the mol ratio of the compound of iron oxide is 1~2.5: 1; Be doped with iron ion titanium oxide, be doped with the titanium oxide of nitrogen element, wherein the mol ratio of iron ion and titanium oxide is 1: 1~90, the mol ratio of nitrogen element and titanium oxide is 1: 1~95.
9. purposes as each described ultra-amphosphobic sterilizing disease-preventing poison fabric of claim 1~5, it is characterized in that: described fabric is used to prepare medical patient's gown or safety device.
CN 200310103149 2003-11-05 2003-11-05 Bactericidal and anti-virus fabrics and its production and garment for patients therefrom Pending CN1614129A (en)

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Application Number Priority Date Filing Date Title
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101748575B (en) * 2008-12-18 2012-02-29 中国纺织科学研究院 Method for single-sided fabric finishing
US8153834B2 (en) 2007-12-05 2012-04-10 E.I. Dupont De Nemours And Company Surface modified inorganic particles
CN103409959A (en) * 2013-08-29 2013-11-27 华纺股份有限公司 Three-proofing finishing method for elastic tencel blended fabrics
CN103726295A (en) * 2013-12-25 2014-04-16 西安工程大学 Finishing method of cotton-polyester blended fabric with antibacterial, hydrophobic and antifouling functions
US8716198B2 (en) 2008-05-09 2014-05-06 E I Du Pont De Nemours And Company Prevention and remediation of water and condensate blocks in wells
CN103981726A (en) * 2014-05-28 2014-08-13 浙江辰鸿纺织品科技有限公司 Antibacterial and mouldproof leaching slurry intumescent coating
CN112012011A (en) * 2020-08-25 2020-12-01 浙江理工大学 Cotton fabric with different functions on two sides and preparation method thereof
CN113152101A (en) * 2021-03-15 2021-07-23 合肥工业大学 Preparation method of antiviral polylactic acid non-woven fabric

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8153834B2 (en) 2007-12-05 2012-04-10 E.I. Dupont De Nemours And Company Surface modified inorganic particles
US8716198B2 (en) 2008-05-09 2014-05-06 E I Du Pont De Nemours And Company Prevention and remediation of water and condensate blocks in wells
CN101748575B (en) * 2008-12-18 2012-02-29 中国纺织科学研究院 Method for single-sided fabric finishing
CN103409959A (en) * 2013-08-29 2013-11-27 华纺股份有限公司 Three-proofing finishing method for elastic tencel blended fabrics
CN103409959B (en) * 2013-08-29 2015-08-12 华纺股份有限公司 A kind of method of Tencel elastic force BLENDED FABRIC three-prevention finishing
CN103726295A (en) * 2013-12-25 2014-04-16 西安工程大学 Finishing method of cotton-polyester blended fabric with antibacterial, hydrophobic and antifouling functions
CN103726295B (en) * 2013-12-25 2016-03-02 西安工程大学 There is polyester cotton method for sorting that is antibacterial, hydrophobic and anti-pollution function
CN103981726A (en) * 2014-05-28 2014-08-13 浙江辰鸿纺织品科技有限公司 Antibacterial and mouldproof leaching slurry intumescent coating
CN112012011A (en) * 2020-08-25 2020-12-01 浙江理工大学 Cotton fabric with different functions on two sides and preparation method thereof
CN112012011B (en) * 2020-08-25 2022-12-09 浙江理工大学 Cotton fabric with different functions on two sides and preparation method thereof
CN113152101A (en) * 2021-03-15 2021-07-23 合肥工业大学 Preparation method of antiviral polylactic acid non-woven fabric
CN113152101B (en) * 2021-03-15 2022-07-12 合肥工业大学 Preparation method of antiviral polylactic acid non-woven fabric

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