DE1037668B - Process for the refinement of glass-like surfaces and an electric light bulb manufactured afterwards - Google Patents
Process for the refinement of glass-like surfaces and an electric light bulb manufactured afterwardsInfo
- Publication number
- DE1037668B DE1037668B DEB38790A DEB0038790A DE1037668B DE 1037668 B DE1037668 B DE 1037668B DE B38790 A DEB38790 A DE B38790A DE B0038790 A DEB0038790 A DE B0038790A DE 1037668 B DE1037668 B DE 1037668B
- Authority
- DE
- Germany
- Prior art keywords
- glass
- refinement
- light bulb
- electric light
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5035—Silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/87—Ceramics
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/213—SiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/111—Deposition methods from solutions or suspensions by dipping, immersion
Description
DEUTSCHESGERMAN
Es ist bereits bekannt, einen reflexionsvermindernden Überzug auf optisch wirksamen Flächen, insbesondere auf Glas, und auch Schichten zum Schutz empfindlicher Gläser dadurch zu erzeugen, daß man den Gegenstand nach erfolgter Reinigung in ein Hochvakuum einführt, seine Oberfläche mit dem Dampf eines Überzugsmetalls, z. B. reinsten Siliciums oder siliciumähnlicher Elemente, beschichtet und anschließend daran die so hergestellten Schichten oxydiert. It is already known to use an anti-reflective Coating on optically effective surfaces, in particular on glass, and also layers for protection To produce more sensitive glasses by the fact that the object after cleaning in a Introduces high vacuum, its surface with the vapor of a coating metal, e.g. B. purest silicon or silicon-like elements, coated and then oxidized the layers produced in this way.
Es ist weiterhin bekannt, daß wasserabstoßende Überzüge auf Glas, Porzellan u. dgl., durch Überziehen der Oberfläche des Gegenstandes mit einer Lösung eines hydrolysierbaren Silans oder eines polymerisierten oder hydrolysierten Produkts desselben erzeugt werden können, worauf der Gegenstand auf eine Temperatur erhitzt wird, die unterhalb des Zersetzungspunktes des Silans liegt.It is also known that water-repellent coatings can be applied to glass, porcelain and the like by coating the surface of the article with a solution of a hydrolyzable silane or a polymerized one or hydrolyzed product thereof can be generated, whereupon the article is based a temperature is heated which is below the decomposition point of the silane.
Gemäß der vorliegenden Erfindung werden der glasartigen Oberfläche eines isolierenden Materials wasserabstoßende Eigenschaften erteilt, indem man den Gegenstand mit der Lösung eines organischen Silikats überzieht, worauf der Gegenstand unter Entfernung des Lösungsmittels auf eine die Zersetzung des Silikats herbeiführende Temperatur erhitzt wird, .so daß ein an der behandelten Fläche anhaftender, aus Kieselsäure bestehender Überzug von etwa molekularer Dicke verbleibt.According to the present invention, the vitreous surface of an insulating material Water-repellent properties are given by treating the object with a solution of an organic Silicate coats, whereupon the object undergoes decomposition with removal of the solvent of the silicate causing temperature is heated, .so that an adhering to the treated area, from Silica existing coating of approximately molecular thickness remains.
In diesem Sinne kann auf die wasserabstoßend auszubildende Fläche ein Überzug eines Tetraäthylorthosilikats gebracht werden, auf den man alsdann Hitze, κ. ß. mittels einer Flamme, derart einwirken läßt, daß das Tetraätbylorthosilikat zersetzt wird. Hierdurch ergibt sich ein weißer Kieselsäureniederschlag, von dem eine dünne Schicht an der Oberfläche haftet. Der Überschuß an Kieselsäure kann alsdann abgewischt werden. Der Überzug aus Tetraäthylorthosilikat kann z. B. in der Weise erzeugt werden, daß man den Gegenstand in das Äthylsilikat eintaucht oder die betreffende Fläche mit demselben besprüht, worauf man den Überschuß der Flüssigkeit von dem Gegenstand ablaufen läßt und ihn alsdann mit einer Flamme von genügender kinetischer Energie bzw. mit kurzer Flamme trockenbrennt.In this sense, a coating of a tetraethylorthosilicate can be applied to the surface to be made water-repellent to which one then heats, κ. ß. by means of a flame, can act in such a way that the tetraethyl orthosilicate is decomposed. This results in a white silica precipitate, of to which a thin layer adheres to the surface. The excess silica can then be wiped off will. The coating of tetraethyl orthosilicate can, for. B. be generated in such a way that the The object is immersed in the ethyl silicate or the surface in question is sprayed with the same, whereupon one let the excess of the liquid run off the object and then with a flame of sufficient kinetic energy or burns dry with a short flame.
Eine besondere Anwendungsform der Erfindung richtet sich auf die x\usbildung der Glashüllen von elektrischen Lampen, die Witterungseinflüssen unmittelbar ohne Schutzfassung ausgesetzt werden sollen, z. B. farbige dekorative Ausstellungslampen. In ähnlicher Weise kann man auch Glühlampen behandein, die in Innenräumen zur Verwendung kommen, in denen möglicherweise ein Bespritzen der Lampe mit Wassertropfen vorkommen kann.A particular form of application of the invention is directed to the formation of the glass envelopes of electrical lamps that are to be exposed to the weather without a protective socket, z. B. colored decorative exhibition lamps. Incandescent lamps can also be treated in a similar way, which are used indoors, where the lamp is likely to be splashed can occur with water droplets.
Ohne einen Überzug aus wasserabweisendem Mate-Verfahren zur VeredlungWithout a coating made of water-repellent mate process for refinement
von glasartigen Flächen und danachof glass-like surfaces and afterwards
hergestellte elektrische Glühlampemanufactured electric light bulb
Anmelder:Applicant:
The British Thomson-Houston Company
Limited, LondonThe British Thomson-Houston Company
Limited, London
Vertreter: Dipl.-Ing. Dr. M. Herzfeld, Patentanwalt,
Düsseldorf, Kreuzstr. 32Representative: Dipl.-Ing. Dr. M. Herzfeld, patent attorney,
Düsseldorf, Kreuzstr. 32
Beanspruchte Priorität:
Großbritannien vom 21. Januar 1955Claimed priority:
Great Britain January 21, 1955
Kenneth Charles Forman,Kenneth Charles Forman,
Rugby, Warwickshire (Großbritannien),Rugby, Warwickshire (Great Britain),
ist als Erfinder genannt wordenhas been named as the inventor
rial können nur elektrische Lampen, deren Wandung während der Brennzeit niedrige Temperaturen annimmt, der Einwirkung von Wassertropfen ausgesetzt werden, ohne daß die Gefahr des Springens des Lampenkolbens als Ergebnis der plötzlichen thermischen Beanspruchung infolge des Auftreffens von Wassertropfen besteht Durch Verwendung der Überzüge gemäß vorliegender Erfindung werden die thermischen Beanspruchungen verringert, da einer Benetzung der Glasfläche durch Anwesenheit des dünnen Kieselsäureüberzugs vorgebeugt wird.Only electrical lamps whose walls take on low temperatures during the burning time can be rial, exposed to the action of water droplets without the risk of the Lamp envelope as a result of the sudden thermal stress as a result of the impact of By using the coatings of the present invention, the thermal Stresses are reduced because the glass surface is wetted by the presence of the thin silica coating is prevented.
Claims (3)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1140294X | 1955-01-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1037668B true DE1037668B (en) | 1958-08-28 |
Family
ID=10877136
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEB38790A Pending DE1037668B (en) | 1955-01-21 | 1956-01-19 | Process for the refinement of glass-like surfaces and an electric light bulb manufactured afterwards |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1037668B (en) |
FR (1) | FR1140294A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE834002C (en) * | 1950-09-19 | 1952-03-13 | Dow Corning | Process for surface treatment of glass and the like like |
DE855767C (en) * | 1939-11-18 | 1952-11-17 | Leitz Ernst Gmbh | Method for producing reflection-reducing layers on optically effective surfaces, e.g. B. glass surfaces |
-
1956
- 1956-01-19 DE DEB38790A patent/DE1037668B/en active Pending
- 1956-01-20 FR FR1140294D patent/FR1140294A/en not_active Expired
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE855767C (en) * | 1939-11-18 | 1952-11-17 | Leitz Ernst Gmbh | Method for producing reflection-reducing layers on optically effective surfaces, e.g. B. glass surfaces |
DE834002C (en) * | 1950-09-19 | 1952-03-13 | Dow Corning | Process for surface treatment of glass and the like like |
Also Published As
Publication number | Publication date |
---|---|
FR1140294A (en) | 1957-07-18 |
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