DE2352242A1 - PIGMENTED PAINT, IN PARTICULAR FAÇADE PROTECTIVE PAINT - Google Patents

PIGMENTED PAINT, IN PARTICULAR FAÇADE PROTECTIVE PAINT

Info

Publication number
DE2352242A1
DE2352242A1 DE19732352242 DE2352242A DE2352242A1 DE 2352242 A1 DE2352242 A1 DE 2352242A1 DE 19732352242 DE19732352242 DE 19732352242 DE 2352242 A DE2352242 A DE 2352242A DE 2352242 A1 DE2352242 A1 DE 2352242A1
Authority
DE
Germany
Prior art keywords
paint
molecular weight
pigmented
low molecular
pigmented paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE19732352242
Other languages
German (de)
Other versions
DE2352242B2 (en
Inventor
Edvard B Dr Grunau
Martin Isink
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HOEVELING EMIL G VON
Original Assignee
HOEVELING EMIL G VON
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HOEVELING EMIL G VON filed Critical HOEVELING EMIL G VON
Priority to DE2352242A priority Critical patent/DE2352242B2/en
Priority to CH371275A priority patent/CH610005A5/en
Priority to AT228675A priority patent/AT335582B/en
Priority to NL7503931A priority patent/NL7503931A/en
Priority to GB13550/75A priority patent/GB1504363A/en
Priority to BE155155A priority patent/BE827638A/en
Publication of DE2352242A1 publication Critical patent/DE2352242A1/en
Publication of DE2352242B2 publication Critical patent/DE2352242B2/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C04B41/495—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
    • C04B41/4961—Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes

Description

Pigmentiertes Anstrichmittel, insbesondere PassadenschutzfarbePigmented paint, in particular Passade protection paint

Die Erfindung betrifft ein pigmentiertes Anstrichmittel, insbesondere Passadenschutzfarbe, zum Wasserabweisendmachen von Baustoffen unter Verwendung von Siloxanharzen und Mischpolymerisaten der Methacrylsäureester.The invention relates to a pigmented paint, in particular passport protection paint, for making water repellent Building materials using siloxane resins and copolymers of methacrylic acid esters.

Ein solches Anstrichmittel ist in der Offenlegungssohrift 2 150 736 vorgeschlagen worden. Dieses Anstrichmittel ist vorteilhaft und soll weitergehend verbessert werden.One such paint is in the disclosure regulation 2 150 736 have been proposed. This paint is advantageous and should be further improved.

Insbesondere besieht sich die Erfindung auf ein Anstrichmittel zum Wasserabstoiendmaohen von mineralischen Baustoffen.In particular, the invention relates to a paint for making mineral building materials water-repellent.

Es ist zwar bekannt« daB Mischungen aus Siloxanharzen und Polymethacrylsäure-Methylester (AS 1 67I 28O) als farblose Imprägnierungen mit wasserabweisendem Bffekt eingesetzt werden, doch unterscheiden sich diese Kombinationen wesentlich von pigmentierten Anstrichmitteln. Derartige Imprägnierungen dringen tief in den Baustoff ein und hinterlassen keinen sichtbaren Film an der Oberfläche. Ihre wasserabweisende Wirkung beruht auf der Erhöhung der Orenzfläohenspannung des Wassers. Der Pestkörpergehalt derartiger Imprägnierungsmittel in organischen Lösungsmitteln ist relativ gering und beträgt nurIt is known that mixtures of siloxane resins and Polymethacrylic acid methyl ester (AS 1 67I 28O) as colorless Impregnations with a water-repellent effect are used, however, these combinations differ significantly from pigmented paints. Such impregnations penetrate deep into the building material and do not leave any visible Film on the surface. Their water-repellent effect is based on the increase in the orenz surface tension of the water. Of the Pest body content of such impregnating agents in organic solvents is relatively low and only amounts to

- 1 -509817/0999- 1 -509817/0999

ca. 3 - 8 Jf, je nach Saugfähigkeit des Baustoffes. Außerdem ist zur Erzielung einer ausreichenden Verträglichkeit von Siloxanharzen mit Mischpolymerisaten ein hoher Anteil an aromatischen Lösungsmitteln erforderlich.approx. 3 - 8 Jf, depending on the absorbency of the building material. aside from that is a high proportion of to achieve sufficient compatibility of siloxane resins with copolymers aromatic solvents required.

Im Qegensatz zu farblosen Imprägnierungen legt man bei pigmentierten Anstrichmitteln einen besonderen Wert auf den optischen Effekt. Farbtonbeständigice it und Glanzerhaltung- sind in dieser Beziehung besonders zu erwähnen.In contrast to colorless impregnations, special emphasis is placed on the visual effect of pigmented paints. Color retention and gloss retention are in special mention should be made of this relationship.

Vor allem ist zur Erzielung deckender und witterungsbeständiger Eigenschaften eine bestimmte Mindestpigmentvolumen-Konzentratlon erforderlich.Above all, a certain minimum pigment volume concentration is required to achieve covering and weather-resistant properties.

Der Erfindung liegt die Aufgabe zugrunde« ein Anstrichmittel der eingangs angegebenen Art dahingehend zu verbessern» daß bei guten deckenden und witterungsbeständigen Eigenschaften eine gute Lagerfähigkeit gewährleistet ist» ohne daß dadurch die Verarbeitbarkeit beeinträchtigt wird.The invention is based on the problem of a paint of the type indicated at the outset to the extent that »that with good covering and weather-resistant properties a good shelf life is guaranteed »without affecting the processability.

Diese Aufgabe wird, erfindungsgemäß dadurch gelöst, daß niedermolekulare Methyl-« Phenyl- oder Metbyl-Phenyl-Slloxanharze eingebracht werden und ihr Anteil« bezogen auf das Mischpolymerisat, 10-30 Gewichtsprozent beträgt. Hierdurch ergibt sich ein verhlltniemÄßig hoher Bindeeittelgehalt, was für die Wlttei-ungebeetändigkeit und Deckungseigenachait vorteilhaft ist. Dabei 1st weiter die hohe Konzentration in Verbindung mit einem aliphatischen Lösungsmittel vorteilhaft· well dadurch für den praktischen Einsatz die Verarbeitung im Rolloder Streichverfahren auch beim überstreichen erleichtert wird. Mit besonderes Vorteil werden in der Mischung des pigmentierten Anstrichmittels Mischpolymerisate, die in aliphatischen Löeungeeitteln löslich sind, verwendet.This object is achieved according to the invention in that low molecular weight methyl, phenyl or methyl phenyl slloxane resins are introduced and their proportion «based on the copolymer, is 10-30 percent by weight. This results in a relatively high binder content, what for the resistance to resistance and the inherent coverage is advantageous. The high concentration in connection with an aliphatic solvent is also advantageous This makes processing in the roller or brush method easier for practical use, even when painting over. Copolymers which are in aliphatic Löeungeeitteln are soluble, used.

509817/0999509817/0999

ORIGINAL INSPECTEDORIGINAL INSPECTED

23522^223522 ^ 2

Überraschend hat sich gezeigt* daß durch die Erfindung ein Anstrichmittel geschaffen wird, weiches auf der Basis niedermolekularer Slloxanharze beruht, wobei zweckmäßig ein Katalysator für die niedermolekularen Siloxanharze enthalten 1st. Mit besonderem Vorteil werden als Katalysator organische Zinnverbindungen eingesetzt. Die niedermolekularen Siloxanharze können sich durch Zusatz solcher Katalysatoren, z.B. organische Zinnverbindungen wie Dlbutylzlnndilaurat, in Oegenwart von Wasser (Luftfeuchtigkeit) zu höhermolekularen Verbindungen beschleunigt umsetzen. Der angegebene Katalysator ist mit beiden Bindemitteln, die erfindungsgemäß verwendet werden, verträglich. Die sich ergebenden höhenaolekularen Verbindungen zeigen dann die ausgesprochen hohe wasserabweis-ende Wirkung der bekannten Siloxanharze. Durch die gute Verträglichkeit der niedermolekularen Siloxanharze mit den erwähnten Mischpolymerisaten wird eine gleichmäßige Verteilung der Siloxanmoleküle im Anstrichfilm erreicht, so daß bereits bei geringer. Insbesondere zehnprozentiger Konzentration, bezogen auf Slloxanharz, ein wasserabweisender Effekt erzielt wird.Surprisingly it has been shown * that a Paint is created, which is based on low molecular weight siloxane resins, wherein a catalyst for the low molecular weight siloxane resins is expediently contained. Organic tin compounds are used with particular advantage as the catalyst. The low molecular weight siloxane resins by adding such catalysts, e.g. organic tin compounds such as di-butyltin dilaurate, in Oegenwart accelerated conversion of water (humidity) to higher molecular weight compounds. The specified catalyst is with both binders which are used according to the invention, compatible. The resulting higher molecular weight compounds then show the extremely high water-repellent effect of the known siloxane resins. Due to the good compatibility of the low molecular weight siloxane resins with those mentioned Copolymers a uniform distribution of the siloxane molecules in the paint film is achieved, so that already at less. In particular, ten percent concentration, based on Slloxanharz, a water-repellent effect is achieved.

Dabei wird einbezogen, daß ein verhältnismäßig hoher Bindemittelgehalt bei einer geringen Lösungsmitteliienge erreicht wird, Die im folgenden angegebene Tabelle beinhaltet eine Rezeptur der Mischung für das Anstreichmittel unter Angabe verschiedener Mengen zugleich zum Machweis der durch die Erfindung erzielten Wirkung. Die Zahlen in der Tabelle drücken Gewichtsprozente der Mischung aus.It is taken into account that a relatively high binder content is achieved with a low amount of solvent, The table given below contains a formulation of the mixture for the paint, stating various amounts at the same time for making the effect achieved by the invention. The numbers in the table express the weight percent of the mixture.

5 0 9 8 17/0999 ORIGINAL INSPECTED5 0 9 8 17/0999 ORIGINAL INSPECTED

cn O «βcn O «β

1. Mi*d«rnol*kul&ree Phenylelloxan1. Mi * d «rnol * kul & ree phenylelloxane

2· Katalysator! organische Zlnnver2 · catalyst! organic ingredients

blndunginflation

3* PoljamtfeAcryleäureester3 * Polyamtfe acrylic acid ester

ha Chlorparaffln (63 J6 Chlor) h a chlorinated paraffin (63 J6 chlorine)

5. Titandioxyd5. Titanium dioxide

6β lfikrcmislerttr6β lfikrcmislerttr

0,50.5 11 22 33 44th 33 0,050.05 0,050.05 Ο,ΟρΟ, Ορ 0,10.1 0,10.1 0,10.1 14,514.5 14,014.0 13,013.0 12,012.0 11,011.0 10,010.0 3,03.0 3.03.0 3,03.0 3.03.0 3,03.0 3.03.0 25,025.0 25,025.0 25,025.0 25,025.0 25*025 * 0 25,025.0 IQ9GIQ 9 G 1O9O1O 9 O 10,010.0 10,010.0 10,010.0 lrt.O „lrt.O " 1,01.0 1,01.0 1,01.0 1,01.0 1,01.0 1,0
1 1.0
1 45,9545.95 45*9545 * 95 45,9545.95 45,945.9 $5-9
; „ft* ff s/$ 5-9
; "Ft * ff s / ! ^ ! ^ 100*»«-
ί100 * »« -
ί 100,—100.00 I
iOO^- I.
iOO ^ - 100,»100, »

w&ss€r*towei*»nä« Wirkung naeh 2 T&g&n: geringe | gutew & ss € r * towei * »Nä« effect after 2 T & g & n: low | quality

sehr gut®j sehr gute! sehrvery good®j very good! very

Es zeigt sich, da® durah di© Erfindung eine überraschend
gute wasserabweisende Wirkung bei Verwendung der angegebenen Stoffe erzielt wird. Dabei liegt ein besonderes Merkmal auch darin, daß der Anteil der niedermolekularen Siloxanharsse, bezogen auf die Gesamtmischung des Anstrichmittels, eti-aa 2-5 Gewichtsprozent beträgt»It turns out that the invention is a surprising one
good water-repellent effect is achieved when using the specified substances. A special feature is that the proportion of the low molecular weight siloxane harsse, based on the total mixture of the paint, is eti-aa 2-5 percent by weight »

Gegenüber herkömmlichen Anstrichstoffen für Fassaden hat das erfindungsgemäße pigmentierte Anstrichmittel die Vorteile
hohen Dampfdiffusionsvermögens, großer Haftfestigkeit insbesondere auf mineralisehen Untergründen, geringen Masseraufnahme Vermögens 9 starker Wasserabweisung im Sinne einer ErhS» hung der Grenzflächenspannung des Wassers bei hohem Eindringvermögen in den Baustoff und damit einer Regulierung des Wasserhaushaltes* SoBc derCompared to conventional paints for facades, the pigmented paint according to the invention has the advantages
high vapor diffusion capacity, high adhesive strength, especially on mineral substrates, low mass absorption capacity 9 strong water repellency in the sense of an increase in the interfacial tension of the water with a high penetration capacity in the building material and thus a regulation of the water balance

ORlGIMAL INSPECTEDORlGIMAL INSPECTED

Claims (6)

PatentansprücheClaims 1. Pigmentiertes Anstrichmittel* insbesondere Fassadenschutzfarbe, zum Wasserabweisendmaehen von Baustoffen unter Verwendung von Siloxanharzen und Mischpolymerisaten der Methaorylsäureester, dadurch gekennzeichnet, daß niedermolekulare Methyl-, Phenyl- oder Methyl-Phenyl-Siloxanharze eingebracht werden und ihr Anteil, bezogen auf das Mischpolymerisat, 10 - 50 Gewichtsprozent beträgt.1. Pigmented paint * in particular facade protection paint, for making building materials water-repellent using siloxane resins and copolymers from Methaoryl acid esters, characterized in that low molecular weight methyl, phenyl or methyl-phenyl-siloxane resins are introduced and their proportion, based on the copolymer, is 10-50 percent by weight. 2. Pigmentiertes Anstrichmittel nach Anspruch 1, dadurch gekennzeichnet, daß Mischpolymerisate, die in aliphatischen Lösungsmitteln löslich sind, verwendet werden.2. Pigmented paint according to claim 1, characterized in that that copolymers which are soluble in aliphatic solvents are used. 3. Pigmentiertes Anstrichmittel nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß ein Katalysator für die niedermolekularen Siloxanharza enthalten ist.3. Pigmented paint according to claim 1 or 2, characterized in that a catalyst for the low molecular weight Siloxanharza is included. 4. Pigmentiertes Anstrichmittel nach Anspruch 3, dadurch ge-Kennzaichnet, daß als Katalysator organische Zinnverbindungen eingesetzt werdena 4. Pigmented paint according to claim 3, characterized in that organic tin compounds are used as the catalyst a 50981 7/099950981 7/0999 5224252242 cj. Pigmentiertes Anstrichmittel naeh einem der Ansprüche 1 bis k, dadurch gekennzeichnet* <iaS aer Anteil der niedermolekularen Silo^Mihars©, tofcsogen awsf di@ Oesamfe mischung d@s Anstrichmittels» otf.ia 2- c j. Pigmented paint Naeh any one of claims 1 to k, wherein * <ias aer proportion of low molecular weight silo Mihars ^ ©, tofcsogen awsf di @ d @ s Oesamfe mix paint "ot f .ia 2- 5 Qewichtsproge beträgt·5 weight pro amounts to· 6. Pigmentiertes Anstrichmittel nach eioera der Änspiilchs 1 bis 3» dadurch gekennzeichnet, daß niedermolekulares Phenyl-Si loxan verwendet6. Pigmented paint according to the age of the Anspiilchs 1 to 3 »characterized in that low molecular weight Phenyl-Si loxane used 509817/0999 ORIGINAL iNSPECTED509817/0999 ORIGINAL iNSPECTED
DE2352242A 1973-10-16 1973-10-16 Pigmented paints Ceased DE2352242B2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
DE2352242A DE2352242B2 (en) 1973-10-16 1973-10-16 Pigmented paints
CH371275A CH610005A5 (en) 1973-10-16 1975-03-24 Pigmented paint
AT228675A AT335582B (en) 1973-10-16 1975-03-25 PIGMENTED PAINT
NL7503931A NL7503931A (en) 1973-10-16 1975-04-02 PAINT.
GB13550/75A GB1504363A (en) 1973-10-16 1975-04-02 Pigmented paint
BE155155A BE827638A (en) 1973-10-16 1975-04-07 PIGMENTED COATING PRODUCT

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2352242A DE2352242B2 (en) 1973-10-16 1973-10-16 Pigmented paints

Publications (2)

Publication Number Publication Date
DE2352242A1 true DE2352242A1 (en) 1975-04-24
DE2352242B2 DE2352242B2 (en) 1975-08-14

Family

ID=5895748

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2352242A Ceased DE2352242B2 (en) 1973-10-16 1973-10-16 Pigmented paints

Country Status (6)

Country Link
AT (1) AT335582B (en)
BE (1) BE827638A (en)
CH (1) CH610005A5 (en)
DE (1) DE2352242B2 (en)
GB (1) GB1504363A (en)
NL (1) NL7503931A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0212790A2 (en) * 1985-06-11 1987-03-04 MALNING h/f Paint not permeable to water and permeable to aqueous vapour
FR2623200A1 (en) * 1987-11-16 1989-05-19 Siceront Kf Varnish intended especially for the protection of equipped electronic cards
EP0761625A1 (en) * 1995-08-08 1997-03-12 Bayer Ag Siloxane filler compositions, their preparation and use for coatings
WO2014097309A1 (en) 2012-12-17 2014-06-26 Asian Paints Ltd. Stimuli responsive self cleaning coating

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2948708C2 (en) * 1979-02-02 1984-06-28 Th. Goldschmidt Ag, 4300 Essen Process for the preparation of organopolysiloxanes modified with pentaerythritol triacrylic or pentaerythritol trimethacrylic acid esters
FR2483448B1 (en) * 1980-05-29 1985-12-20 Nippon Sheet Glass Co Ltd ANTI-FOG COATING COMPOSITION, SHAPED ARTICLE COATED WITH SUCH COMPOSITION AND PROCESS FOR PREPARING THE SAME
GB2150581B (en) * 1983-12-05 1987-09-30 Nagy Jozsef Silicone base artist's paints and their preparation
RU2338767C2 (en) 2003-01-30 2008-11-20 Акцо Нобель Коатингс Интернэшнл Б.В. Coating composition solidified at room temperature and its use

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0212790A2 (en) * 1985-06-11 1987-03-04 MALNING h/f Paint not permeable to water and permeable to aqueous vapour
EP0212790A3 (en) * 1985-06-11 1988-01-07 Malning H/F Paint not permeable to water and permeable to aqueous vapour
FR2623200A1 (en) * 1987-11-16 1989-05-19 Siceront Kf Varnish intended especially for the protection of equipped electronic cards
EP0761625A1 (en) * 1995-08-08 1997-03-12 Bayer Ag Siloxane filler compositions, their preparation and use for coatings
US5847037A (en) * 1995-08-08 1998-12-08 Bayer Aktiengesellschaft Mixtures, process for the production thereof and use thereof for coatings
WO2014097309A1 (en) 2012-12-17 2014-06-26 Asian Paints Ltd. Stimuli responsive self cleaning coating

Also Published As

Publication number Publication date
GB1504363A (en) 1978-03-22
AT335582B (en) 1977-03-25
CH610005A5 (en) 1979-03-30
BE827638A (en) 1975-07-31
DE2352242B2 (en) 1975-08-14
ATA228675A (en) 1976-07-15
NL7503931A (en) 1976-10-05

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