EP1215276A1 - Detergent composition comprising microdispersed particles containing silicate - Google Patents
Detergent composition comprising microdispersed particles containing silicate Download PDFInfo
- Publication number
- EP1215276A1 EP1215276A1 EP01128892A EP01128892A EP1215276A1 EP 1215276 A1 EP1215276 A1 EP 1215276A1 EP 01128892 A EP01128892 A EP 01128892A EP 01128892 A EP01128892 A EP 01128892A EP 1215276 A1 EP1215276 A1 EP 1215276A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cleaning agent
- detergent
- agents
- silicate
- detergents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002245 particle Substances 0.000 title claims abstract description 44
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 239000003599 detergent Substances 0.000 title claims description 52
- 239000000203 mixture Substances 0.000 title claims description 31
- 239000012459 cleaning agent Substances 0.000 claims abstract description 37
- 238000005406 washing Methods 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 37
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- 108090000790 Enzymes Proteins 0.000 claims description 8
- 102000004190 Enzymes Human genes 0.000 claims description 8
- 239000002518 antifoaming agent Substances 0.000 claims description 8
- 239000007844 bleaching agent Substances 0.000 claims description 8
- 239000008119 colloidal silica Substances 0.000 claims description 7
- 238000004851 dishwashing Methods 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 229920002545 silicone oil Polymers 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 239000004569 hydrophobicizing agent Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000012190 activator Substances 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000003093 cationic surfactant Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 3
- 239000013543 active substance Substances 0.000 claims description 2
- 239000008139 complexing agent Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 150000002222 fluorine compounds Chemical class 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- 239000000499 gel Substances 0.000 claims 2
- 150000004812 organic fluorine compounds Chemical class 0.000 claims 1
- 230000009467 reduction Effects 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 28
- 238000004140 cleaning Methods 0.000 description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- -1 polydimethylsiloxane Polymers 0.000 description 18
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- 238000003756 stirring Methods 0.000 description 9
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- ZLIBICFPKPWGIZ-UHFFFAOYSA-N pyrimethanil Chemical compound CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 ZLIBICFPKPWGIZ-UHFFFAOYSA-N 0.000 description 8
- 150000001298 alcohols Chemical class 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 229940088598 enzyme Drugs 0.000 description 7
- 239000000344 soap Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229960004106 citric acid Drugs 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 5
- 239000004667 Diesterquat Substances 0.000 description 5
- 108090001146 Nuclear Receptor Coactivator 1 Proteins 0.000 description 5
- 102100037223 Nuclear receptor coactivator 1 Human genes 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- 229920004482 WACKER® Polymers 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 239000000908 ammonium hydroxide Substances 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 229960002303 citric acid monohydrate Drugs 0.000 description 4
- 229940071118 cumenesulfonate Drugs 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 4
- 229910000271 hectorite Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 108010075550 termamyl Proteins 0.000 description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 239000002979 fabric softener Substances 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 229940094522 laponite Drugs 0.000 description 3
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 3
- XMMDVXFQGOEOKH-UHFFFAOYSA-N n'-dodecylpropane-1,3-diamine Chemical compound CCCCCCCCCCCCNCCCN XMMDVXFQGOEOKH-UHFFFAOYSA-N 0.000 description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 3
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 230000002940 repellent Effects 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 235000014347 soups Nutrition 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 244000218514 Opuntia robusta Species 0.000 description 2
- 235000003166 Opuntia robusta Nutrition 0.000 description 2
- 244000300264 Spinacia oleracea Species 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 235000021185 dessert Nutrition 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 108010020132 microbial serine proteinases Proteins 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Natural products CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical class O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
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- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
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- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
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- 235000021355 Stearic acid Nutrition 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- XRRYGMTXOYFERK-UHFFFAOYSA-N [I].[K].[I] Chemical compound [I].[K].[I] XRRYGMTXOYFERK-UHFFFAOYSA-N 0.000 description 1
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- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- ZDGGJQMSELMHLK-UHFFFAOYSA-N m-Trifluoromethylhippuric acid Chemical compound OC(=O)CNC(=O)C1=CC=CC(C(F)(F)F)=C1 ZDGGJQMSELMHLK-UHFFFAOYSA-N 0.000 description 1
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
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- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003470 sulfuric acid monoesters Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical group OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
Definitions
- the invention relates to detergents and cleaning agents containing silicate-containing microdisperse hydrophilic particles, with high dirt removal ability and less Re-soiling tendency of the surfaces to be cleaned.
- WO 99/00457 describes a facade coating that Facades' tendency to become dirty is reduced.
- EP 368 559 describes the use of finely divided silica as Abrasion agents.
- DE 2 809 371 describes the use of polydimethylsiloxane and colloid Silicic acid, which acts as an abrasive.
- the aforementioned writings refer to the abrasive effects of colloidal Silica and its thickening effect in one formulation.
- silicate-containing particles act as surface coating agents which are used in the Attachment to the surfaces to displace the dirt and at the same time by Coating of the surfaces complicates their re-soiling. In the Repeated use of detergents and cleaning agents increases the effect on.
- silicate-containing particles are their ability in aqueous dispersion and / or to form sufficiently small particles when applied to surfaces.
- Microdispers refers to the particle size of the silicate-containing particles. Particle, which are not sufficiently small in solution or when applied to surfaces Forming no particles at all are not suitable for the invention.
- the invention relates to detergents and cleaning agents containing microdisperse, hydrophilic silicate-containing particles.
- the invention also relates to the use of microdisperse, hydrophilic silicate-containing particles as surface coating agents for Reinforcement of dirt detachment and reduction of the tendency to re-soiling in detergents and cleaning agents.
- the silicate-containing particles preferably have a particle size of 1 to 500 nm, particularly preferably 9 to 50 nm.
- the silicate-containing particles are on the Ionically charged surface.
- the dirt is removed by the electric charge better detached and difficult to recontaminate.
- Those are preferred particles containing silicate negatively charged.
- silicate-containing particles are colloidal silica sols which are derived from the Clariant GmbH as ® Klebosol and from Bayer as ® Baykisol to be expelled.
- the synthetic ones are also particularly suitable Clay minerals hectorite and saponite from Laporte (® Laponite types), Südchemie (® Optigel) and Clariant GmbH (® SKS-20 and ® SKS-21).
- the silicate-containing particles become simultaneous used with hydrophobizing agents, which increases dirt removal and reduces the tendency to re-soiling.
- Preferred hydrophobicizing agents are silicones, silicone oils and / or Fluorosilicone oils, e.g. the antifoam emulsions ® SE36 and ® SE39, the Antifoam ® S850 and the antifoam powder ® ASP 8, ® ASP 15, ® ASP16, ® ASP 20 and ® ASP30 from Wacker.
- Polyorganosiloxanes such as e.g. Polydimethylsiloxanes, polysiloxanes, alkyl modified siloxanes and amino functional ones Siloxanes, particularly preferred ® Finish CT 34 E (silicone softener emissions from Wacker).
- So-called soil release polymers are also suitable as hydrophobizing agents, e.g. Polymers of phthalic acid and / or terephthalic acid or their Derivatives, especially oligomeric terephthalate esters, polymers Ethylene terephthalates and polyethylene glycol terephthalates or also anionic and / or nonionic derivatives thereof.
- hydrophobizing agents are cationic surfactants consisting of quaternary mono- (C 8 -C 16 ) -N-alkyl or alkenyl ammonium salts, the N positions of which are occupied by methyl, hydroxymethyl or hydroxypropyl groups.
- cationic surfactants consisting of quaternary mono- (C 8 -C 16 ) -N-alkyl or alkenyl ammonium salts, the N positions of which are occupied by methyl, hydroxymethyl or hydroxypropyl groups.
- Distearyldimethylammonium chloride, ditallow dimethylammonium chloride, diethanolamine diester quat, triethanolamine diester quat and alkylhydroxyethyldimethylammonium chloride are particularly preferred.
- hydrophobizing agents are fluorine compounds, e.g. that of the 3M company.
- the detergents and cleaning agents preferably contain 0.01 to 10% by weight, particularly preferably 0.1 to 5% by weight of silicate-containing particles.
- Concentrates containing up to 80% by weight of particles containing silicate are also preferred contain.
- the weight ratio of water in the washing and cleaning agents is to silicate-containing particles between 10,000 to 1 and 1: 4.
- the weight ratio of silicate-containing particles to water repellents is preferably between 100 to 1 and 1 to 100. Washing and cleaning agents are preferred 0.01 to 10% by weight of silicate-containing particles, 0.01 to 10 wt .-% water repellents and contain up to 99.5% other detergent ingredients.
- Washing and cleaning agents are also preferred 0.01 to 10% by weight of silicate-containing particles, 0.5 to 60% by weight of surfactants and up to 99.5% by weight of other detergent ingredients.
- Washing and cleaning agents are also preferred 0.01 to 10% by weight of silicate-containing particles, 0.01 to 10% by weight of water repellent, 0.5 to 60% by weight of surfactants and contain up to 99.5% by weight of other detergents / cleaning agent ingredients,
- the surface-active substances can be anionic, cationic, act non-ionic and / or zwitterionic surfactants.
- Alkyl alkoxylates, gluconamides and alkyl polyglycosides are nonionic surfactants particularly preferred.
- alkyl alkoxylates preference is given to using ethoxylated alcohols, preferably primary alcohols, preferably having 8 to 22 carbon atoms and preferably 1 to 80 EO units per mole of alcohol, the alcohol radical being linearly or preferably 2-methyl-branched or linear and methyl-branched Contains residues in the mixture, as is usually the case in oxo alcohol residues.
- ethoxylated alcohols preferably primary alcohols, preferably having 8 to 22 carbon atoms and preferably 1 to 80 EO units per mole of alcohol, the alcohol radical being linearly or preferably 2-methyl-branched or linear and methyl-branched Contains residues in the mixture, as is usually the case in oxo alcohol residues.
- the preferred ethoxylated alcohols include, for example, C 11 alcohols with 3, 5, 7, 8 and 11 EO units, (C 12 -C 15 ) alcohols with 3, 6, 7, 8, 10 and 13 EO units , (C 14 -C 15 ) alcohols with 4, 7 or 8 EO units, (C 16 -C 18 ) alcohols with 8, 11, 15, 20, 25, 50 or 80 EO units and mixtures the same.
- the degrees of ethoxylation given represent statistical averages, which can be an integer or a fraction for a specific product.
- fatty alcohol EO / PO adducts can also be used, such as the ®Genapol types 3970, 2909 and 2822 from Clariant GmbH.
- Suitable surfactants are polyhydroxy fatty acid amides of the formula R 2 -CO-N (R 3 ) -Z, in which R 2 CO for an aliphatic acyl radical having 6 to 22 carbon atoms, R 3 for hydrogen, an alkyl or hydroxyalkyl radical with 1 to 4 carbon atoms and Z represents a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
- Alkyl glycosides of the general formula RO (G) x can preferably be used, in which R denotes a primary straight-chain or methyl-branched, in particular methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms, and G represents a glycose unit with 5 or 6 carbon atoms, preferably for glucose.
- the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; x is preferably 1.2 to 1.4.
- Preferred anionic surfactants of the sulfonate type are the known (C 9 -C 13 ) alkylbenzenesulfonates, alpha-olefin sulfonates and alkanesulfonates. Esters of sulfo fatty acids or the disalts of alpha sulfo fatty acids are also suitable.
- Suitable anionic surfactants are sulfonated fatty acid glycerol esters, which are mono-, di- and triesters and their mixtures, such as those produced by esterification by 1 mol of monoglycerol with 1 to 3 mol of fatty acid or in the transesterification of triglycerides with 0.3 to 2 Moles of glycerol can be obtained.
- alkyl sulfates are the sulfuric acid monoesters of the (C 12 -C 18 ) fatty alcohols, such as lauryl, myristyl, cetyl or stearyl alcohol, and the fatty alcohol mixtures obtained from coconut oil, palm and palm kernel oil, which additionally contain proportions of unsaturated alcohols, for example, oleyl alcohol.
- the sulfuric acid monoesters of the (C 12 -C 18 ) fatty alcohols such as lauryl, myristyl, cetyl or stearyl alcohol
- the fatty alcohol mixtures obtained from coconut oil, palm and palm kernel oil which additionally contain proportions of unsaturated alcohols, for example, oleyl alcohol.
- Soaps are particularly suitable as further anionic surfactants.
- Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, Palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, as well especially from natural fatty acids, e.g. Coconut, palm kernel or Tallow fatty acids, derived soap mixtures.
- the anionic surfactants can be used in Form of their sodium, potassium or ammonium salts, as well as soluble salts organic bases, such as mono-, di- or triethanolamine, are present.
- the anionic surfactants in the form of their sodium or potassium salts, especially in the form of the sodium salts.
- detergent / cleaning agent ingredients are builders, cobuilders, Alkali suppliers, anti-foaming agents, dispersants, pH regulators, complexing agents, Bleaching agents, bleach activators and catalysts and / or enzymes.
- the builders are preferably crystalline aluminosilicates, Alkali carbonates, alkali ortho-, alkali pyro- and alkali polyphosphates, crystalline Layered silicates, crystalline alkali silicates without a layered structure and / or X-ray amorphous alkali silicates.
- the cobuilders are preferably monomeric, oligomeric, polymeric or copolymeric carboxylic acids.
- the bleaching systems are preferably active chlorine carriers and / or organic or inorganic active oxygen carriers, bleach activators (e.g. TAED), Bleaching catalysts, enzymes for removing discoloration, perborates and / or Percarbonates.
- bleach activators e.g. TAED
- Bleaching catalysts enzymes for removing discoloration, perborates and / or Percarbonates.
- the pH regulators are preferably soda, citric acid, Sodium citrate and / or bicarbonate.
- detergents and cleaning agents can optionally also contain enzymes, such as. Proteases, amylases, lipases and cellulases.
- the detergents and cleaning agents can be used to treat fiber and Textile surfaces, but also for the treatment of hard surfaces from the various materials, e.g. Metals, glass, ceramics, plastics etc., be used.
- the detergents are preferably heavy duty detergents, compact heavy duty detergents, Compact color detergent, full detergent with low bulk density, Special detergents, e.g. Laundry after-treatment agent, fabric softener, Stain salts, bleach boosters, curtain detergents, wool detergents, modular detergents and commercial detergents.
- Special detergents e.g. Laundry after-treatment agent, fabric softener, Stain salts, bleach boosters, curtain detergents, wool detergents, modular detergents and commercial detergents.
- the cleaning agents are generally cleaning agents for hard ones Surfaces such as Facade, glass, ceramic, metal, window, floor and Carpet cleaner.
- the cleaning agents are preferably hand dishwashing detergents, Machine dishwashing detergent, dishwasher detergent and rinse aid.
- Further preferred cleaning agents are automotive and paint cleaners for the manual application and for automatic application in car washes.
- compositions of the agents according to the invention will stated in percent by weight.
- the Gardnertest is a cleaning test for hard surfaces, mainly floors, etc. Test strips (maximum 45 cm long and 5-6 cm wide) are treated with the test solution, dried and then soiled. To examine the cleaning process, 10 g of the cleaning solution are placed on the strips and a piece of wipe is attached to a holder. The cloth is driven by means of tensioning ropes, driven by an eccentric, back and forth on the prepared sample strip. The number of wiping movements is read on a counter. The number of wiping movements up to absolute cleanliness is evaluated, or after a maximum of 50 wiping movements the cleaning result is rated on a scale from 1 (clean) to 5. The rating 50/3 means that after the maximum number of 50 wiping cycles, the sampling gave the mark 3 on the scale from 1 to 5. The rating 5/1 means that after 5 wiping steps, the sampling gave the mark 1 (clean) on the scale from 1 to 5.
- the measured values were arithmetically averaged and an average Scale spread from 0 to 100%.
- Example 1 As in Example 1, a general purpose cleaner was made. In addition, with the Added water glue sol 30 V 25. This can be compared to in the Gardner test Example 1 an improvement in the cleaning effect can be achieved.
- the Composition and results are shown in Table 1.
- Example 1 As in Example 1, a general purpose cleaner was made. In addition, with the Water hectorite SKS-21 added. This can be compared to in the Gardner test Example 1 an improvement in the cleaning effect can be achieved. The Composition and results are shown in Table 1.
- Example 1 As in Example 1, a general purpose cleaner was made. In addition, with the Water Klebosol 30 V 25 and with the cumene sulfonate TexCare SRC-1 dispersion added. As a result, in the Gardner test in comparison to Examples 1 to 3 an improvement in the cleaning effect can be achieved. The composition and the results are shown in Table 1.
- a tile / bathroom cleaner was made using isopropanol and water were mixed together. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 with vigorous stirring and finally citric acid monohydrate admixed. The cleaning effect was examined using the Gardner test. The composition and the results are shown in Table 1.
- Example 5 As in Example 5, a tile / bathroom cleaner was made. In addition, with added Klebosol 20 H 12 to the water. In the Gardner test in Compared to example 5, an improvement in the cleaning effect can be achieved. The composition and the results are shown in Table 1.
- Example 5 a tile / bathroom cleaner was made.
- Klebosol 20 H 12 and with the citric acid finish CT 34 E As a result, in the Gardner test in comparison to Examples 5 and 6 Improvement of the cleaning effect can be achieved.
- the composition and the results are shown in Table 1.
- a hand dishwashing liquid was made by using Hostapur SAS 60 Water and Klebosol 30 R 12 was mixed. Then Genagen CAB 818, Genapol UD 080 and Genapol ZRO liquid mixed in with slow stirring.
- the Composition is shown in Table 2.
- a window cleaner was made using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide and Isopropanol mixed in with stirring. The composition is in Table 2 listed.
- a window cleaner was made using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide, isopropanol and finish CT 34 E mixed in with stirring. The composition is in the table 2 listed.
- a tile / bath cleaner was made by mixing isopropanol with water was mixed. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 and finally Klebosol 30H25 mixed in with stirring. The Composition is shown in Table 2.
- a car wash cleaner was manufactured by Genapol UD 110 and Genapol UD 50 were successively dissolved in water. Then Klebosol 30 R 12 mixed. The composition is shown in Table 2.
- a drying agent for car washes was manufactured by consecutively butyl diglycol, acetic acid, conc., Genamin LAP 100 D and Praepagen 4317 were mixed. Then water and Klebosol 30 H 25 were added.
- the Composition is shown in Table 2.
- a hot wax for car washes was made one by one Balsamic turpentine, spindle oil, butyl diglycol, Genapol X 080 and Hoechst wax KST were mixed. Then Praepagen WKT, water and Klebosol 30 H 25 added. The composition is shown in Table 2.
- a dishwasher washer was made by one after the other Citric acid, cumene sulfonate, Genapol 2908 and Klebosol 30 H 25 in water were solved. According to the general rule implementation of Machine dishwashing detergent tests were tableware with a commercially available Rinsed tablet dishwasher detergent. The above wording was used as rinse aid used. This procedure of cleaning and rinsing was repeated repeated and the dishes then patterned. The composition and the Results are shown in Table 3.
- Example 16 a dishwasher cleaner is made. additionally is glue in 30 H 25 mixed.
- Implementation according to the general regulation of the machine dishwasher detergent tests dishes were washed twice with one commercially available tablet dishwasher detergent and rinsed with the rinse aid treated.
- the use of silica sol gives clear advantages to the Cleaning effect.
- the composition and the results are in Table 3 listed.
- a liquid detergent is made by stirring vigorously Alkylbenzenesulfonate, citric acid, Genapol 3070, soap, water, silicone oil, Phosphonate, polyglycol ether and Klebosol 30 V 50 mixes.
- the composition is listed in Table 4.
- a powder detergent is made by washing in one Ploughshare mixer from Lödige Antifoam, layered silicate, soda, Sokalan CP5 and zeolite A mixes and sprayed Genapol 3070. The remaining components are mixed in briefly. The composition is shown in Table 4.
- a fabric softener is made by stirring at 50 to 60 ° C first dissolve Lapnite RD and then Praepagen WK in water.
- the Composition is shown in Table 4.
- a fabric softener is made by dissolving diesterquat (85%) triethanolamine melted at 50 ° C in preheated water, then stirring in Genapol UD 088 and cooling the solution. Finally, TexCare SRC-1 dispersion and Klebosol 30 V 50 are stirred in.
Abstract
Die Erfindung betrifft Wasch- und Reinigungsmittel enthaltend mikrodisperse, hydrophile silikathaltige Partikel. Der Teilchendurchmesser der Partikel beträgt bevorzugt 1 bis 500 nm. Der Zusatz der silikathaltigen Partikel führt zu einer verbesserten Schmutzablösung bei gleichzeitiger Verringerung der Wiederanschmutzneigung.The invention relates to washing and cleaning agents containing microdisperse, hydrophilic silicate-containing particles. The particle diameter of the particles is preferably 1 to 500 nm. The addition of the silicate-containing particles leads to improved dirt detachment with a simultaneous reduction in the tendency to re-soiling.
Description
Die Erfindung betrifft Wasch- und Reinigungsmittel, enthaltend silikathaltige, mikrodisperse hydrophile Partikel, mit hohem Schmutzablösevermögen und geringer Wiederanschmutzneigung der zu reinigenden Oberflächen.The invention relates to detergents and cleaning agents containing silicate-containing microdisperse hydrophilic particles, with high dirt removal ability and less Re-soiling tendency of the surfaces to be cleaned.
In WO 99/00457 ist eine Fassadenbeschichtung beschrieben, die die Verschmutzungsneigung von Fassaden verringert.WO 99/00457 describes a facade coating that Facades' tendency to become dirty is reduced.
In EP 252 708 wird gefunden, dass der Zusatz von kolloider Kieselsäure zu Klarspülmitteln die Abtrocknungszeit verringert.In EP 252 708 it is found that the addition of colloidal silica Rinse aid reduces the drying time.
EP 368 559 beschreibt den Einsatz von fein verteilter Kieselsäure als Abrasionsmittel.EP 368 559 describes the use of finely divided silica as Abrasion agents.
DE 2 809 371 beschreibt den Einsatz von Polydimethylsiloxan und kolloider Kieselsäure, die als Abrasiv wirkt.DE 2 809 371 describes the use of polydimethylsiloxane and colloid Silicic acid, which acts as an abrasive.
Die vorgenannten Schriften beziehen sich auf die abrasive Wirkung von kolloidaler Kieselsäure und ihre verdickende Wirkung in einer Formulierung.The aforementioned writings refer to the abrasive effects of colloidal Silica and its thickening effect in one formulation.
Überraschenderweise wurde nun gefunden, dass der Zusatz von mikrodispersen, hydrophilen silikathaltigen Partikeln zu Wasch- und Reinigungsmitteln die Schmutzablösung erleichtert, die Reinigungswirkung erhöht und die Wiederanschmutzung der so behandelten Oberflächen verringert.Surprisingly, it has now been found that the addition of microdisperse, hydrophilic silicate-containing particles for washing and cleaning agents Dirt detachment facilitates, the cleaning effect increases and the Re-soiling of the surfaces treated in this way is reduced.
Die silikathaltigen Partikeln wirken als Oberflächenbeschichtungsmittel, die bei der Anlagerung an die Oberflächen den Schmutz verdrängen und gleichzeitig durch die Beschichtung der Oberflächen deren Wiederanschmutzung erschweren. Bei der wiederholten Anwendung der Wasch- und Reinigungsmittel tritt der Effekt verstärkt auf.The silicate-containing particles act as surface coating agents which are used in the Attachment to the surfaces to displace the dirt and at the same time by Coating of the surfaces complicates their re-soiling. In the Repeated use of detergents and cleaning agents increases the effect on.
Wesentlich für die silikathaltigen Partikel ist ihre Fähigkeit in wässriger Dispersion und/oder beim Aufbringen auf Oberflächen hinreichend kleine Teilchen zu bilden. Mikrodispers bezieht sich auf die Teilchengröße der silikathaltigen Partikel. Partikel, die in Lösung bzw. beim Aufbringen auf Oberflächen keine hinreichend kleinen oder gar keine Partikel bilden, eignen sich nicht für die Erfindung.What is important for the silicate-containing particles is their ability in aqueous dispersion and / or to form sufficiently small particles when applied to surfaces. Microdispers refers to the particle size of the silicate-containing particles. Particle, which are not sufficiently small in solution or when applied to surfaces Forming no particles at all are not suitable for the invention.
Gegenstand der Erfindung sind Wasch- und Reinigungsmittel, enthaltend mikrodisperse, hydrophile silikathaltige Partikel.The invention relates to detergents and cleaning agents containing microdisperse, hydrophilic silicate-containing particles.
Ebenfalls Gegenstand der Erfindung ist die Verwendung von mikrodispersen, hydrophilen silikathaltigen Partikeln als Oberflächenbeschichtungsmittel zur Verstärkung der Schmutzablösung und Verringerung der Wiederanschmutzneigung in Wasch- und Reinigungsmitteln.The invention also relates to the use of microdisperse, hydrophilic silicate-containing particles as surface coating agents for Reinforcement of dirt detachment and reduction of the tendency to re-soiling in detergents and cleaning agents.
Bevorzugt haben die silikathaltigen Partikel eine Teilchengröße von 1 bis 500 nm, besonders bevorzugt 9 bis 50 nm.The silicate-containing particles preferably have a particle size of 1 to 500 nm, particularly preferably 9 to 50 nm.
In einer bevorzugten Ausführungsform sind die silikathaltigen Partikel an der Oberfläche ionisch geladen. Durch die elektrische Aufladung wird der Schmutz besser abgelöst und die Wiederanschmutzung erschwert. Bevorzugt sind die silikathaltigen Partikel negativ geladen.In a preferred embodiment, the silicate-containing particles are on the Ionically charged surface. The dirt is removed by the electric charge better detached and difficult to recontaminate. Those are preferred particles containing silicate negatively charged.
Besonders bevorzugt als silikathaltige Partikel sind kolloide Kieselsole, die von der Firma Clariant GmbH als ® Klebosol und von der Firma Bayer als ® Baykisol vertrieben werden. Weiterhin besonders geeignet sind auch die synthetischen Tonminerale Hectorit und Saponit der Firmen Laporte (® Laponite-Typen), Südchemie (® Optigel) und Clariant GmbH (® SKS-20 und ® SKS-21).Particularly preferred as silicate-containing particles are colloidal silica sols which are derived from the Clariant GmbH as ® Klebosol and from Bayer as ® Baykisol to be expelled. The synthetic ones are also particularly suitable Clay minerals hectorite and saponite from Laporte (® Laponite types), Südchemie (® Optigel) and Clariant GmbH (® SKS-20 and ® SKS-21).
In einer bevorzugten Ausführungsform werden die silikathaltigen Partikel gleichzeitig mit hydrophobierenden Agenzien verwendet, was die Schmutzablösung verstärkt und die Wiederanschmutzneigung verringert.In a preferred embodiment, the silicate-containing particles become simultaneous used with hydrophobizing agents, which increases dirt removal and reduces the tendency to re-soiling.
Bevorzugte hydrophobierende Agenzien sind Silicone, Siliconöle und/oder Fluorsiliconöle, z.B. die Antischaumemulsionen ® SE36 und ® SE39, das Antischaummittel ® S850 und die Antischaumpulver ® ASP 8, ® ASP 15, ® ASP16, ® ASP 20 und ® ASP30 der Firma Wacker.Preferred hydrophobicizing agents are silicones, silicone oils and / or Fluorosilicone oils, e.g. the antifoam emulsions ® SE36 and ® SE39, the Antifoam ® S850 and the antifoam powder ® ASP 8, ® ASP 15, ® ASP16, ® ASP 20 and ® ASP30 from Wacker.
Weiterhin bevorzugt geeignet sind Polyorganosiloxane, wie z.B. Polydimethylsiloxane, Polysiloxane, alkylmodifizierte Siloxane und aminofunktionelle Siloxane, besonders bevorzugt ® Finish CT 34 E (Slliconweichmacher-Emuisionen der Firma Wacker).Polyorganosiloxanes, such as e.g. Polydimethylsiloxanes, polysiloxanes, alkyl modified siloxanes and amino functional ones Siloxanes, particularly preferred ® Finish CT 34 E (silicone softener emissions from Wacker).
Weiterhin geeignet als hydrophobierende Agenzien sind sogenannte Soil-release-Polymere, z.B. Polymere der Phthalsäure und/oder der Terephthalsäure bzw. deren Derivaten, insbesondere oligomere Terephthalatester, Polymere aus Ethylenterephthalaten und Polyethylenglykolterephthalaten oder auch anionische und/oder nichtionische Derivate derselben.So-called soil release polymers are also suitable as hydrophobizing agents, e.g. Polymers of phthalic acid and / or terephthalic acid or their Derivatives, especially oligomeric terephthalate esters, polymers Ethylene terephthalates and polyethylene glycol terephthalates or also anionic and / or nonionic derivatives thereof.
Als hydrophobierende Agenzien weiterhin geeignet sind kationische Tenside bestehend aus quaternären Mono-(C8-C16)-N-Alkyl oder -Alkenyl Ammoniumsalzen, deren N-Positionen mit Methyl-, Hydroxymethyl- oder Hydroxypropylgruppen besetzt sind. Besonders bevorzugt sind Distearyldimethylammoniumchlorid, Ditalgdimethylammoniumchlorid, Diethanolamindiesterquat, Triethanolamindiesterquat und Alkylhydroxyethyldimethylammoniumchlorid.Also suitable as hydrophobizing agents are cationic surfactants consisting of quaternary mono- (C 8 -C 16 ) -N-alkyl or alkenyl ammonium salts, the N positions of which are occupied by methyl, hydroxymethyl or hydroxypropyl groups. Distearyldimethylammonium chloride, ditallow dimethylammonium chloride, diethanolamine diester quat, triethanolamine diester quat and alkylhydroxyethyldimethylammonium chloride are particularly preferred.
Als hydrophobierenden Agenzien ebenfalls geeignet sind Fluorverbindungen, z.B. die der Firma 3M.Also suitable as hydrophobizing agents are fluorine compounds, e.g. that of the 3M company.
Bevorzugt enthalten die Wasch- und Reinigungsmittel 0,01 bis 10 Gew.-%, besonders bevorzugt 0,1 bis 5 Gew.-%, an silikathaltigen Partikeln.The detergents and cleaning agents preferably contain 0.01 to 10% by weight, particularly preferably 0.1 to 5% by weight of silicate-containing particles.
Bevorzugt sind auch Konzentrate, die bis zu 80 Gew.-% an silikathaltigen Partikeln enthalten. Concentrates containing up to 80% by weight of particles containing silicate are also preferred contain.
In den Wasch- und Reinigungsmitteln beträgt das Gewichtsverhältnis von Wasser zu silikathaltigen Partikeln zwischen 10000 zu 1 und 1:4.The weight ratio of water in the washing and cleaning agents is to silicate-containing particles between 10,000 to 1 and 1: 4.
Das Gewichtsverhältnis von silikathaltigen Partikeln zu Hydrophobierungsmitteln
beträgt bevorzugt zwischen 100 zu 1 und 1 zu 100.
Bevorzugt sind Wasch- und Reinigungsmittel die
0,01 bis 10 Gew.-% silikathaltige Partikel,
0,01 bis 10 Gew.-% Hydrophobierungsmittel und
bis 99,5% sonstige Wasch-/Reinigungsmittelinhaltsstoffe enthalten.The weight ratio of silicate-containing particles to water repellents is preferably between 100 to 1 and 1 to 100.
Washing and cleaning agents are preferred
0.01 to 10% by weight of silicate-containing particles,
0.01 to 10 wt .-% water repellents and
contain up to 99.5% other detergent ingredients.
Weiterhin bevorzugt sind Wasch- und Reinigungsmittel die
0,01 bis 10 Gew.-% silikathaltige Partikel,
0,5 bis 60 Gew.-% grenzflächenaktive Stoffe und
bis 99,5 Gew.-% sonstige Wasch-/Reinigungsmittelinhaltsstoffe enthalten.Washing and cleaning agents are also preferred
0.01 to 10% by weight of silicate-containing particles,
0.5 to 60% by weight of surfactants and
up to 99.5% by weight of other detergent ingredients.
Weiterhin bevorzugt sind Wasch- und Reinigungsmittel die
0,01 bis 10 Gew.-% silikathaltige Partikel,
0,01 bis 10 Gew.-% Hydrophobierungsmittel,
0,5 bis 60 Gew.-% grenzflächenaktive Stoffe und
bis 99,5 Gew.-% sonstige Waschmittel/ Reinigungsmittelinhaltsstoffe enthalten,Washing and cleaning agents are also preferred
0.01 to 10% by weight of silicate-containing particles,
0.01 to 10% by weight of water repellent,
0.5 to 60% by weight of surfactants and
contain up to 99.5% by weight of other detergents / cleaning agent ingredients,
Bei den grenzflächenaktiven Substanzen kann es sich um anionische, kationische, nicht-ionische und/oder zwitterionische Tenside handeln.The surface-active substances can be anionic, cationic, act non-ionic and / or zwitterionic surfactants.
Als nichtionische Tenside sind Alkylalkoxylate, Gluconamide und Alkylpolyglycoside besonders bevorzugt.Alkyl alkoxylates, gluconamides and alkyl polyglycosides are nonionic surfactants particularly preferred.
Unter den Alkylalkoxylaten werden bevorzugt ethoxylierte Alkohole, bevorzugt
primäre Alkohole, mit bevorzugt 8 bis 22 C-Atomen und bevorzugt 1 bis 80 EO-Einheiten
pro Mol Alkohol, eingesetzt, wobei der Alkoholrest linear oder bevorzugt in
2-Stellung methylverzweigt ist oder lineare und methylverzweigte Reste im Gemisch
enthält, so wie dies üblicherweise in Oxoalkoholresten der Fall ist. Zu den
bevorzugten ethoxylierten Alkoholen gehören beispielsweise C11-Alkohole mit 3, 5,
7, 8 und 11 EO-Einheiten, (C12-C15)-Alkohole mit 3, 6, 7, 8, 10 bzw. 13 EO-Einheiten,
(C14-C15)-Alkohole mit 4, 7 bzw. 8 EO-Einheiten, (C16-C18)-Alkohole mit 8,
11, 15, 20, 25, 50 bzw. 80 EO-Einheiten und Mischungen derselben. Die
angegebenen Ethoxylierungsgrade stellen statistische Mittelwerte dar, die für ein
spezielles Produkt eine ganze oder eine gebrochene Zahl sein können. Zusätzlich
zu diesen können auch Fettalkohol-EO/PO-Addukte eingesetzt werden, wie z.B. die
®Genapol-Typen 3970, 2909 und 2822 der Fa. Clariant GmbH.
Weitere geeignete Tenside sind Polyhydroxyfettsäureamide der Formel R2-CO-N(R3)-Z,
in der R2CO für einen aliphatischen Acylrest mit 6 bis 22
Kohlenstoffatomen, R3 für Wasserstoff, einen Alkyl oder Hydroxyalkylrest mit 1 bis 4
Kohlenstoffatomen und Z für einen linearen oder verzweigten Polyhydroxyalkylrest
mit 3 bis 10 Kohlenstoffatomen und 3 bis 10 Hydroxylgruppen steht.
Bevorzugt können Alkylglykoside der allgemeinen Formel RO(G)x eingesetzt
werden, in der R einen primären geradkettigen oder methylverzweigten,
insbesondere in 2-Stellung methylverzweigten aliphatischen Rest mit 8 bis 22,
vorzugsweise 12 bis 18 Kohlenstoffatomen, bedeutet und G für eine Glykoseeinheit
mit 5 oder 6 Kohlenstoffatomen, vorzugsweise für Glucose, steht. Der
Oligomerisierungsgrad x, der die Verteilung von Monoglykosiden und
Oligoglykosiden angibt, ist eine beliebige Zahl zwischen 1 und 10; vorzugsweise liegt
x bei 1,2 bis 1,4.Among the alkyl alkoxylates, preference is given to using ethoxylated alcohols, preferably primary alcohols, preferably having 8 to 22 carbon atoms and preferably 1 to 80 EO units per mole of alcohol, the alcohol radical being linearly or preferably 2-methyl-branched or linear and methyl-branched Contains residues in the mixture, as is usually the case in oxo alcohol residues. The preferred ethoxylated alcohols include, for example, C 11 alcohols with 3, 5, 7, 8 and 11 EO units, (C 12 -C 15 ) alcohols with 3, 6, 7, 8, 10 and 13 EO units , (C 14 -C 15 ) alcohols with 4, 7 or 8 EO units, (C 16 -C 18 ) alcohols with 8, 11, 15, 20, 25, 50 or 80 EO units and mixtures the same. The degrees of ethoxylation given represent statistical averages, which can be an integer or a fraction for a specific product. In addition to these, fatty alcohol EO / PO adducts can also be used, such as the ®Genapol types 3970, 2909 and 2822 from Clariant GmbH.
Other suitable surfactants are polyhydroxy fatty acid amides of the formula R 2 -CO-N (R 3 ) -Z, in which R 2 CO for an aliphatic acyl radical having 6 to 22 carbon atoms, R 3 for hydrogen, an alkyl or hydroxyalkyl radical with 1 to 4 carbon atoms and Z represents a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
Alkyl glycosides of the general formula RO (G) x can preferably be used, in which R denotes a primary straight-chain or methyl-branched, in particular methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms, and G represents a glycose unit with 5 or 6 carbon atoms, preferably for glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; x is preferably 1.2 to 1.4.
Bevorzugt sind auch alkoxylierte, vorzugsweise ethoxylierte oder ethoxylierte und propoxylierte, Fettsäurealkylester, vorzugsweise mit 1 bis 4 Kohlenstoffatomen in der Alkylkette, insbesondere Fettsäuremethylester, wie sie beispielsweise in der japanischen Patentanmeldung JP 58/217598 beschrieben sind, oder vorzugsweise solche wie sie nach dem in der internationalen Patentanmeldung WO A 90/13533 beschriebenen Verfahren hergestellt werden.Also preferred are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated, fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl esters, as described, for example, in Japanese patent application JP 58/217598 are described, or preferably such as those described in international patent application WO A 90/13533 described methods are produced.
Als anionische Tenside vom Sulfonat-Typ kommen vorzugsweise die bekannten (C9-C13)-Alkylbenzolsulfonate, alpha-Olefinsulfonate und Alkansulfonate in Betracht. Geeignet sind auch Ester von Sulfofettsäuren bzw. die Disalze der alpha-Sulfofettsäuren. Weitere geeignete anionische Tenside sind sulfierte Fettsäureglycerinester, welche Mono-, Di- und Triester sowie deren Gemische darstellen, wie sie bei der Herstellung durch Veresterung durch 1 Mol Monoglycerin mit 1 bis 3 Mol Fettsäure oder bei der Umesterung von Triglyceriden mit 0,3 bis 2 Mol Glycerin erhalten werden. Als Alkylsulfate eignen sich insbesondere die Schwefelsäuremonoester der (C12-C18)-Fettalkohole, wie Lauryl-, Myristyl-, Cetyl- oder Stearylalkohol, und die aus Kokosöl, Palm- und Palmkernöl gewonnenen Fettalkoholgemische, die zusätzlich noch Anteile an ungesättigten Alkoholen, z.B. Oleylalkohol, enthalten können.Preferred anionic surfactants of the sulfonate type are the known (C 9 -C 13 ) alkylbenzenesulfonates, alpha-olefin sulfonates and alkanesulfonates. Esters of sulfo fatty acids or the disalts of alpha sulfo fatty acids are also suitable. Other suitable anionic surfactants are sulfonated fatty acid glycerol esters, which are mono-, di- and triesters and their mixtures, such as those produced by esterification by 1 mol of monoglycerol with 1 to 3 mol of fatty acid or in the transesterification of triglycerides with 0.3 to 2 Moles of glycerol can be obtained. Particularly suitable as alkyl sulfates are the sulfuric acid monoesters of the (C 12 -C 18 ) fatty alcohols, such as lauryl, myristyl, cetyl or stearyl alcohol, and the fatty alcohol mixtures obtained from coconut oil, palm and palm kernel oil, which additionally contain proportions of unsaturated alcohols, for example, oleyl alcohol.
Als weitere anionische Tenside kommen insbesondere Seifen in Betracht. Geeignet sind gesättigte Fettsäureseifen, wie die Salze der Laurinsäure, Myristinsäure, Palmitinsäure, Stearinsäure, hydrierten Erucasäure und Behensäure, sowie insbesondere aus natürlichen Fettsäuren, z.B. Kokos-, Palmkern- oder Talgfettsäuren, abgeleitete Seifengemische. Die anionischen Tenside können in Form ihrer Natrium-, Kalium- oder Ammoniumsalze, sowie als lösliche Salze organischer Basen, wie Mono-, Di- oder Triethanolamin, vorliegen. Vorzugsweise liegen die anionischen Tenside in Form ihrer Natrium- oder Kaliumsalze, insbesondere in Form der Natriumsalze, vor.Soaps are particularly suitable as further anionic surfactants. Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, Palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, as well especially from natural fatty acids, e.g. Coconut, palm kernel or Tallow fatty acids, derived soap mixtures. The anionic surfactants can be used in Form of their sodium, potassium or ammonium salts, as well as soluble salts organic bases, such as mono-, di- or triethanolamine, are present. Preferably are the anionic surfactants in the form of their sodium or potassium salts, especially in the form of the sodium salts.
Weitere Waschmittel-/Reinigungsmittelinhaltsstoffe sind Builder, Cobuilder, Alkalilieferanten, Antischaummittel, Dispergatoren, pH-Regulatoren, Komplexbildner, Bleichmittel, Bleichaktivatoren und ―katalysatoren und/oder Enzyme.Other detergent / cleaning agent ingredients are builders, cobuilders, Alkali suppliers, anti-foaming agents, dispersants, pH regulators, complexing agents, Bleaching agents, bleach activators and catalysts and / or enzymes.
Bei den Buildern handelt es sich bevorzugt um kristalline Aluminosilikate, Alkalicarbonate, Alkaliortho-, Alkalipyro- und Alkalipolyphosphate, kristalline Schichtsilikate, kristalline Alkalisilikate ohne Schichtstruktur und/oder röntgenamorphe Alkalisilikate.The builders are preferably crystalline aluminosilicates, Alkali carbonates, alkali ortho-, alkali pyro- and alkali polyphosphates, crystalline Layered silicates, crystalline alkali silicates without a layered structure and / or X-ray amorphous alkali silicates.
Bei den Cobuildern handelt es sich bevorzugt um monomere, oligomere, polymere oder copolymere Carbonsäuren.The cobuilders are preferably monomeric, oligomeric, polymeric or copolymeric carboxylic acids.
Bei den Bleichsystemen handelt es sich bevorzugt um Aktivchlorträger und/oder organische oder anorganische Aktivsauerstoffträger, Bleichaktivatoren (z.B. TAED), Bleichkatalysatoren, Enzyme zur Entfernung von Verfärbungen, Perborate und/oder Percarbonate.The bleaching systems are preferably active chlorine carriers and / or organic or inorganic active oxygen carriers, bleach activators (e.g. TAED), Bleaching catalysts, enzymes for removing discoloration, perborates and / or Percarbonates.
Bei den pH-Regulatoren handelt es sich bevorzugt um Soda, Zitronensäure, Natriumcitrat und/oder Bicarbonat.The pH regulators are preferably soda, citric acid, Sodium citrate and / or bicarbonate.
Schließlich können die Wasch- und Reinigungsmittel gegebenenfalls noch Enzyme, wie z.B. Proteasen, Amylasen, Lipasen und Cellulasen, enthalten.Finally, the detergents and cleaning agents can optionally also contain enzymes, such as. Proteases, amylases, lipases and cellulases.
Die Wasch- und Reinigungsmittel können zur Behandlung von Faser- und Textiloberflächen, aber auch zur Behandlung harter Oberflächen aus den verschiedensten Materialien, z.B. Metallen, Glas, Keramiken, Kunststoffen etc., eingesetzt werden.The detergents and cleaning agents can be used to treat fiber and Textile surfaces, but also for the treatment of hard surfaces from the various materials, e.g. Metals, glass, ceramics, plastics etc., be used.
Bei den Waschmitteln handelt es sich bevorzugt um Vollwaschmittel, Compact-Vollwaschmittel, Compact-Colorwaschmittel, Vollwaschmittel geringer Schüttdichte, Spezialwaschmittel, wie z.B. Wäschenachbehandlungsmittel, Wäscheweichmacher, Fleckensalze, Bleichbooster, Gardinenwaschmittel, Wollwaschmittel, Baukasten-Waschmittel und gewerbliche Waschmittel.The detergents are preferably heavy duty detergents, compact heavy duty detergents, Compact color detergent, full detergent with low bulk density, Special detergents, e.g. Laundry after-treatment agent, fabric softener, Stain salts, bleach boosters, curtain detergents, wool detergents, modular detergents and commercial detergents.
Bei den Reinigungsmitteln handelt es sich allgemein um Reinigungsmittel für harte Oberflächen, wie z.B. Fassaden-, Glas-, Keramik-, Metall, Fenster-, Fußboden- und Teppichbodenreiniger.The cleaning agents are generally cleaning agents for hard ones Surfaces such as Facade, glass, ceramic, metal, window, floor and Carpet cleaner.
Bevorzugt handelt es sich bei den Reinigungsmitteln um Handgeschirrspülmittel, Maschinengeschirreiniger, Maschinengeschirrspülmittel und Klarspüler.The cleaning agents are preferably hand dishwashing detergents, Machine dishwashing detergent, dishwasher detergent and rinse aid.
Weiterhin bevorzugte Reinigungsmitteln sind Automobil- und Lackreiniger für die manuelle Anwendung und für die automatische Anwendung in Waschstraßen. Further preferred cleaning agents are automotive and paint cleaners for the manual application and for automatic application in car washes.
Die nachfolgenden Beispiele dienen der Erläuterung der Erfindung, ohne sie jedoch einzuschränken. Die Zusammensetzungen der erfindungsgemäßen Mittel werden dabei in Gewichtsprozent angegeben.The following examples serve to illustrate the invention, but without it limit. The compositions of the agents according to the invention will stated in percent by weight.
Durchführung des Gardnertests:
Der Gardnertest ist ein Reinigungstest für harte Oberflächen, vorwiegend Fußböden
etc.. Dabei weren Probestreifen (maximal 45cm lang und 5-6 cm breit) mit der
Untersuchungslösung behandelt, getrocknet und dann angeschmutzt. Zur
Untersuchung des Reinigungsprozesses werden 10 g der Reinigungslösung auf den
Streifen gegeben und ein Stück Wischtuch an einer Halterung befestigt. Das Tuch
wird mittels Spannseilen, über einen Exzenter angetrieben, auf dem präparierten
Probenstreifen hin- und herbewegt. Die Anzahl der Wischbewegungen wird an
einem Zählwerk abgelesen. Ausgewertet wird die Anzahl der Wischbewegungen bis
zur absoluten Sauberkeit, oder nach maximal 50 Wischbewegungen die Benotung
des Reinigungsergebnisses auf der Skala von 1 (sauber) bis 5.
Die Bewertung 50/3 bedeutet hierbei, daß nach der Maximalanzahl von 50
Wischgängen die Abmusterung die Note 3 auf der Skala von 1 bis 5 ergab.
Die Bewertung 5/1 bedeutet hierbei, daß schon nach 5 Wischgängen die
Abmusterung die Note 1 (sauber) auf der Skala von 1 bis 5 ergab.Execution of the Gardner test:
The Gardnertest is a cleaning test for hard surfaces, mainly floors, etc. Test strips (maximum 45 cm long and 5-6 cm wide) are treated with the test solution, dried and then soiled. To examine the cleaning process, 10 g of the cleaning solution are placed on the strips and a piece of wipe is attached to a holder. The cloth is driven by means of tensioning ropes, driven by an eccentric, back and forth on the prepared sample strip. The number of wiping movements is read on a counter. The number of wiping movements up to absolute cleanliness is evaluated, or after a maximum of 50 wiping movements the cleaning result is rated on a scale from 1 (clean) to 5.
The rating 50/3 means that after the maximum number of 50 wiping cycles, the sampling gave the mark 3 on the scale from 1 to 5.
The rating 5/1 means that after 5 wiping steps, the sampling gave the mark 1 (clean) on the scale from 1 to 5.
Als Oberflächen wurden Keramik-Wandfließen und PVC-Bodenplatten eingesetzt. Als Anschmutzungen wurden Edding permanent Stift, Signierkreidestift und Bleistift (Graphit) verwendet.Ceramic wall tiles and PVC floor panels were used as surfaces. Edding became permanent pen, chalk marker and pencil (Graphite) used.
Durchführung der Maschinengeschirrreinigertests:
Anlehnend an IEC-Norm 436 und IKW-Methode wurden Tests in 4
Haushaltsgeschirrspülmaschinen (2 Miele G 688 SC und 2 Bosch 6902) bei 55°C
Spültemperatur und 20g Dosierung durchgeführt.Execution of machine dishwasher test:
Based on the IEC standard 436 and IKW method, tests were carried out in 4 household dishwashers (2 Miele G 688 SC and 2 Bosch 6902) at 55 ° C washing temperature and 20g dosage.
Die Anschmutzungen waren:
Die Messwerte wurden arithmetisch zu einem Durchschnitt gemittelt und auf einen Maßstab von 0 bis 100 % gespreizt.The measured values were arithmetically averaged and an average Scale spread from 0 to 100%.
Es wurde ein Allzweckreiniger hergestellt, indem Genapol UD 080 und Hostapur SAS 60 miteinander gemischt wurden. Dann wurde Wasser und schließlich Cumolsulfonat zugemischt. Mit Hilfe des Gardnertests wurde die Reinigungswirkung untersucht. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.An all purpose cleaner was made by Genapol UD 080 and Hostapur SAS 60 were mixed together. Then there was water and finally Cumene sulfonate added. With the help of the Gardner test, the cleaning effect examined. The composition and the results are shown in Table 1.
Wie in Beispiel 1 wurde ein Allzweckreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 30 V 25 zugefügt. Dadurch kann im Gardner-Test im Vergleich zu Beispiel 1 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 1, a general purpose cleaner was made. In addition, with the Added water glue sol 30 V 25. This can be compared to in the Gardner test Example 1 an improvement in the cleaning effect can be achieved. The Composition and results are shown in Table 1.
Wie in Beispiel 1 wurde ein Allzweckreiniger hergestellt. Außerdem wurde mit dem Wasser Hectorit SKS-21 zugefügt. Dadurch kann im Gardner-Test im Vergleich zu Beispiel 1 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 1, a general purpose cleaner was made. In addition, with the Water hectorite SKS-21 added. This can be compared to in the Gardner test Example 1 an improvement in the cleaning effect can be achieved. The Composition and results are shown in Table 1.
Wie in Beispiel 1 wurde ein Allzweckreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 30 V 25 und mit dem Cumolsulfonat TexCare SRC-1 Dispersion zugefügt. Dadurch kann im Gardner-Test im Vergleich zu den Beispielen 1 bis 3 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 1, a general purpose cleaner was made. In addition, with the Water Klebosol 30 V 25 and with the cumene sulfonate TexCare SRC-1 dispersion added. As a result, in the Gardner test in comparison to Examples 1 to 3 an improvement in the cleaning effect can be achieved. The composition and the results are shown in Table 1.
Es wurde ein Fliesen-/Badreiniger hergestellt, indem Isopropanol und Wasser miteinander gemischt wurden. Dann wurden Genapol UD 080, Hordaphos CC MS und Hostapur SAS 60 unter starkem Rühren und zuletzt Zitronensäuremonohydrat zugemischt. Mit Hilfe des Gardner-Tests wurde die Reinigungswirkung untersucht. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.A tile / bathroom cleaner was made using isopropanol and water were mixed together. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 with vigorous stirring and finally citric acid monohydrate admixed. The cleaning effect was examined using the Gardner test. The composition and the results are shown in Table 1.
Wie in Beispiel 5 wurde ein Fliesen-/Badreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 20 H 12 zugefügt. Dadurch kann im Gardner-Test im Vergleich zu Beispiel 5 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 5, a tile / bathroom cleaner was made. In addition, with added Klebosol 20 H 12 to the water. In the Gardner test in Compared to example 5, an improvement in the cleaning effect can be achieved. The composition and the results are shown in Table 1.
Wie in Beispiel 5 wurde ein Fliesen-/Badreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 20 H 12 und mit der Zitronensäure Finish CT 34 E zugefügt. Dadurch kann im Gardner-Test im Vergleich zu den Beispielen 5 und 6 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 5, a tile / bathroom cleaner was made. In addition, with added to the water Klebosol 20 H 12 and with the citric acid finish CT 34 E. As a result, in the Gardner test in comparison to Examples 5 and 6 Improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.
Es wurde ein Handgeschirrspülmittel hergestellt, indem Hostapur SAS 60 mit Wasser und Klebosol 30 R 12 gemischt wurde. Dann wurden Genagen CAB 818, Genapol UD 080 und Genapol ZRO liquid unter langsamem Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A hand dishwashing liquid was made by using Hostapur SAS 60 Water and Klebosol 30 R 12 was mixed. Then Genagen CAB 818, Genapol UD 080 and Genapol ZRO liquid mixed in with slow stirring. The Composition is shown in Table 2.
Es wurde ein Fensterreiniger hergestellt, indem Genapol LRO liquid mit Wasser und Klebosol 30 N 12 gemischt wurde. Dann wurden Ammoniumhydroxid und Isopropanol unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A window cleaner was made using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide and Isopropanol mixed in with stirring. The composition is in Table 2 listed.
Es wurde ein Fensterreiniger hergestellt, indem Genapol LRO liquid mit Wasser und Klebosol 30 N 12 gemischt wurde. Dann wurden Ammoniumhydroxid, Isopropanol und Finish CT 34 E unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A window cleaner was made using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide, isopropanol and finish CT 34 E mixed in with stirring. The composition is in the table 2 listed.
Es wurde ein Allzweckreiniger hergestellt, indem Genapol UD 080 mit Hostapur SAS 60 gemischt wurde. Dann wurden Wasser, Klebosol 30 R 12 und Propylenglykol n-Butylether unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt. An all purpose cleaner was manufactured by Genapol UD 080 with Hostapur SAS 60 was mixed. Then water, Klebosol 30 R 12 and propylene glycol n-Butyl ether mixed in with stirring. The composition is in Table 2 listed.
Es wurde ein Fließen-/Badreiniger hergestellt, indem Isopropanol mit Wasser gemischt wurde. Dann wurden Genapol UD 080, Hordaphos CC MS und Hostapur SAS 60 und zum Schluss Klebosol 30H25 unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A tile / bath cleaner was made by mixing isopropanol with water was mixed. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 and finally Klebosol 30H25 mixed in with stirring. The Composition is shown in Table 2.
Es wurde ein Reiniger für Autowaschanlagen hergestellt, indem Genapol UD 110 und Genapol UD 50 nacheinander in Wasser gelöst wurden. Dann wurde Klebosol 30 R 12 zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A car wash cleaner was manufactured by Genapol UD 110 and Genapol UD 50 were successively dissolved in water. Then Klebosol 30 R 12 mixed. The composition is shown in Table 2.
Es wurde ein Trocknungsmittel für Autowaschanlagen hergestellt, indem nacheinander Butyldiglykol, Essigsäure, conc., Genamin LAP 100 D und Praepagen 4317 gemischt wurden. Dann wurde Wasser und Klebosol 30 H 25 zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A drying agent for car washes was manufactured by consecutively butyl diglycol, acetic acid, conc., Genamin LAP 100 D and Praepagen 4317 were mixed. Then water and Klebosol 30 H 25 were added. The Composition is shown in Table 2.
Es wurde ein Heißwachs für Autowaschanlagen hergestellt, indem nacheinander Balsamterpentinöl, Spindelöl, Butyldiglykol, Genapol X 080 und Hoechst-Wachs KST gemischt wurden. Dann wurden Praepagen WKT, Wasser und Klebosol 30 H 25 zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A hot wax for car washes was made one by one Balsamic turpentine, spindle oil, butyl diglycol, Genapol X 080 and Hoechst wax KST were mixed. Then Praepagen WKT, water and Klebosol 30 H 25 added. The composition is shown in Table 2.
Es wurde ein Maschinengeschirrreinerklarspüler hergestellt, indem nacheinander Zitronensäure, Cumolsulfonat, Genapol 2908 und Klebosol 30 H 25 in Wasser gelöst wurden. Nach der allgemeinen Vorschrift Durchführung der Maschinengeschirrreinigertests wurde Geschirr mit einem handelsüblichen Tabletten-Geschirrreiniger gespült. Als Klarspüler wurde obige Formulierung eingesetzt. Diese Prozedur aus Reinigen und Klarspülen wurde noch einmal wiederholt und das Geschirr danach abgemustert. Die Zusammensetzung und die Ergebnisse sind in Tabelle 3 aufgeführt. A dishwasher washer was made by one after the other Citric acid, cumene sulfonate, Genapol 2908 and Klebosol 30 H 25 in water were solved. According to the general rule implementation of Machine dishwashing detergent tests were tableware with a commercially available Rinsed tablet dishwasher detergent. The above wording was used as rinse aid used. This procedure of cleaning and rinsing was repeated repeated and the dishes then patterned. The composition and the Results are shown in Table 3.
Wie in Beispiel 16 wird ein Maschinengeschirrreinerklarspüler hergestellt. Zusätzlich wird Klebosol 30 H 25 untergemischt. Nach der allgemeinen Vorschrift Durchführung der Maschinengeschirrreinigertests wurde Geschirr zweimal mit einem handelsüblichen Tabletten-Geschirrreiniger gespült und mit dem Klarspüler behandelt. Die Verwendung von Kieselsol ergibt klare Vorteile für die Reinigungswirkung. Die Zusammensetzung und die Ergebnisse sind in Tabelle 3 aufgeführt.As in Example 16, a dishwasher cleaner is made. additionally is glue in 30 H 25 mixed. Implementation according to the general regulation of the machine dishwasher detergent tests, dishes were washed twice with one commercially available tablet dishwasher detergent and rinsed with the rinse aid treated. The use of silica sol gives clear advantages to the Cleaning effect. The composition and the results are in Table 3 listed.
In einem Pflugscharmischer der Fa. Lödige wird ein pulverförmiger Maschinengeschirreiniger dadurch hergestellt dass die festen Komponenten, außer Enzyme, Bleiche und Parfüm, vorgelegt und gut gemischt werden. Dann werden das Alkylethoxylat und das Klebosol 30 V 50 aufgesprüht. Enzyme, Parfüm und Bleichsystem werden zum Schluss untergemischt. Die Zusammensetzung ist in Tabelle 4 aufgeführt.In a ploughshare mixer from Lödige, a powdered Machine dish washer manufactured by making the solid components, except Enzymes, bleach and perfume, presented and mixed well. Then that will be Sprayed alkyl ethoxylate and the adhesive sol 30 V 50. Enzymes, perfume and Bleaching systems are mixed in at the end. The composition is in Table 4 listed.
Ein Flüssigwaschmittel wird dadurch hergestellt, dass man unter kräftigem Rühren Alkylbenzolsulfonat, Zitronensäure, Genapol 3070, Seife, Wasser, Siliconöl, Phosphonat, Polyglykolether und Klebosol 30 V 50 mischt. Die Zusammensetzung ist in Tabelle 4 aufgeführt.A liquid detergent is made by stirring vigorously Alkylbenzenesulfonate, citric acid, Genapol 3070, soap, water, silicone oil, Phosphonate, polyglycol ether and Klebosol 30 V 50 mixes. The composition is listed in Table 4.
Ein Pulverwaschmittel wird dadurch hergestellt, dass man in einem Pflugscharmischer der Fa. Lödige Antischaum, Schichtsilicat, Soda, Sokalan CP5 und Zeolith A mischt und Genapol 3070 aufsprüht. Die restlichen Komponenten werden kurz untergemischt. Die Zusammensetzung ist in Tabelle 4 aufgeführt.A powder detergent is made by washing in one Ploughshare mixer from Lödige Antifoam, layered silicate, soda, Sokalan CP5 and zeolite A mixes and sprayed Genapol 3070. The remaining components are mixed in briefly. The composition is shown in Table 4.
Ein Wäscheweichspüler wird dadurch hergestellt, dass bei 50 bis 60°C unter Rühren zunähst Lapnite RD und danach Praepagen WK in Wasser gelöst werden. Die Zusammensetzung ist in Tabelle 4 aufgeführt. A fabric softener is made by stirring at 50 to 60 ° C first dissolve Lapnite RD and then Praepagen WK in water. The Composition is shown in Table 4.
Ein Wäscheweichspüler wird dadurch hergestellt, dass bei 50°C geschmolzenes
Triethanolamin diesterquat (85 %) in vorgeheiztes Wasser gelöst wird, dann wird
Genapol UD 088 eingerührt und die Lösung abgekühlt. Zum Schluss wird TexCare
SRC-1 Dispersion und Klebosol 30 V 50 eingerührt.
- Alkylbenzolsulfonatalkylbenzenesulfonate
- Marlon ARL, Fa. HülsMarlon ARL, Hüls
- Ammoniumhydroxid (w= 25 %)Ammonium hydroxide (w = 25%)
- Fa. Riedel de HaenRiedel de Haen
- Antischaumantifoam
- Fa. WackerWacker
- BalsamterpentinölGum
- --
- Butyldiglycoldiglycol
- Fa. MerckMerck
- Citronensäurecitric acid
- Fa. JungbunzlauerJungbunzlauer
- Citronensäure monohydratCitric acid monohydrate
- Fa. JungbunzlauerJungbunzlauer
- Cumol sulphonatCumene sulphonate
- Fa.CondeaFa.Condea
- Essigsäure, conc.Acetic acid, conc.
- Fa. Riedel de HaenRiedel de Haen
- Finish CT 34 EFinish CT 34 E
- Fa. WackerWacker
- Genagen CAB 818Genagen CAB 818
- Fa. ClariantClariant
- Genamin LAP 100 DGenamin LAP 100 D.
- Fa. ClariantClariant
- Genapol 2822Genapol 2822
- Fa. ClariantClariant
- Genapol 2908Genapol 2908
- Fa. ClariantClariant
- Genapol 3070Genapol 3070
- Fa. ClariantClariant
- Genapol LRO liquidGenapol LRO liquid
- Fa. ClariantClariant
- Genapol O 020Genapol O 020
- Fa. ClariantClariant
- Genapol UD 080Genapol UD 080
- Fa. ClariantClariant
- Genapol UD 088Genapol UD 088
- Fa. ClariantClariant
- Genapol UD 110Genapol UD 110
- Fa. ClariantClariant
- Genapol UD 50Genapol UD 50
- Fa. ClariantClariant
- Genapol X 080Genapol X 080
- Fa. ClariantClariant
- Genapol ZRO liquidGenapol ZRO liquid
- Fa. ClariantClariant
- Hectorit SKS-21Hectorite SKS-21
- Fa. ClariantClariant
- Hoechst-Wachs KSTHoechst wax KST
- Fa. ClariantClariant
- Hordaphos CC MSHordaphos CC MS
- Fa. ClariantClariant
- Hostapur SAS 60Hostapur SAS 60
- Fa. ClariantClariant
- Isopropanolisopropanol
- Fa. Riedel de HaenRiedel de Haen
- Klebosol 20 H 12Klebosol 20 H 12
- Fa. ClariantClariant
- Klebosol 30 H 25Klebosol 30 H 25
- Fa. ClariantClariant
- Klebosol 30 N 12Klebosol 30 N 12
- Fa. Clariant Clariant
- Klebosol 30 R 12Klebosol 30 R 12
- Fa. ClariantClariant
- Klebosol 30 V 25Klebosol 30 V 25
- Fa. ClariantClariant
- Klebosol 30 V 50Klebosol 30 V 50
- Fa. ClariantClariant
- Laponite RDLaponite RD
- Fa. LaporteLaporte
- Makrophos 1018Macrophos 1018
- Fa. BK GiuliniBK Giulini
- ParfümPerfume
- Citronenparfüm 78122D, Fa OrissaLemon perfume 78122D, Orissa
- Peractive AC WhitePeractive AC White
- Fa. ClariantClariant
- Peractive ANPeractive ON
- Fa. ClariantClariant
- Perborat mhPerborate mh
- Fa. DegussaDegussa
- Percarbonatpercarbonate
- Oxyper C, Fa. Solvay InteroxOxyper C, from Solvay Interox
- Phosphonatphosphonate
- Dequest 2041, Fa. MonsantoDequest 2041, Monsanto
- Polyglycoletherpolyglycol
- Fa. ClariantClariant
- Praepagen 4317Praepagen 4317
- Fa. ClariantClariant
- Praepagen WKPraepagen WK
- Fa. ClariantClariant
- Praepagen WKTPraepagen WKT
- Fa. ClariantClariant
- Propylenglycol n-butyletherPropylene glycol n-butyl ether
- Fa. MerckMerck
- Savinase 6.0 TWSavinase 6.0 TW
- Fa. Solvay EnzymesSolvay Enzymes
- Schichtsilicatlayered
- Fa. ClariantClariant
- SeifeSoap
- Liga Grundseife HM11ELiga basic soap HM11E
- Sodasoda
- Schwersoda, Fa. Matthes&WeberSchwersoda, Matthes & Weber
- Sokalan CP45Sokalan CP45
- Fa. BASFBASF
- Sokalan CP5Sokalan CP5
- Fa. BASFBASF
- Spindelölspindle oil
- --
- Termamyl 120TTermamyl 120T
- Fa. Solvay EnzymesSolvay Enzymes
- Termamyl 60TTermamyl 60T
- Fa. Solvay EnzymesSolvay Enzymes
- TexCare SRC-1 DispersionTexCare SRC-1 dispersion
- Fa. ClariantClariant
- Triethanolamin diesterquatTriethanolamine diesterquat
- Fa. ClariantClariant
- Wacker SiliconölWacker silicone oil
- Fa. WackerWacker
- Wasserwater
- --
- Zeolith AZeolite A
- Wessalith P, Fa. DegussaWessalith P, Degussa
Claims (20)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10061897A DE10061897A1 (en) | 2000-12-12 | 2000-12-12 | Washing or cleaning composition, useful for fabrics or hard surfaces, contains microdisperse, hydrophilic silicate particles that improve soil removal and prevent resoiling |
DE10061897 | 2000-12-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1215276A1 true EP1215276A1 (en) | 2002-06-19 |
EP1215276B1 EP1215276B1 (en) | 2005-08-03 |
Family
ID=7666852
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01128892A Revoked EP1215276B1 (en) | 2000-12-12 | 2001-12-05 | Detergent composition comprising microdispersed particles containing silicate |
Country Status (4)
Country | Link |
---|---|
US (1) | US6784149B2 (en) |
EP (1) | EP1215276B1 (en) |
JP (1) | JP2002285194A (en) |
DE (2) | DE10061897A1 (en) |
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Also Published As
Publication number | Publication date |
---|---|
JP2002285194A (en) | 2002-10-03 |
DE50106965D1 (en) | 2005-09-08 |
EP1215276B1 (en) | 2005-08-03 |
DE10061897A1 (en) | 2002-06-13 |
US20020111287A1 (en) | 2002-08-15 |
US6784149B2 (en) | 2004-08-31 |
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