US20120027939A1 - Nanocomposite coating and the method of coating thereof - Google Patents

Nanocomposite coating and the method of coating thereof Download PDF

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Publication number
US20120027939A1
US20120027939A1 US13/251,845 US201113251845A US2012027939A1 US 20120027939 A1 US20120027939 A1 US 20120027939A1 US 201113251845 A US201113251845 A US 201113251845A US 2012027939 A1 US2012027939 A1 US 2012027939A1
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Prior art keywords
nanometer
powder
product
nanocomposite coating
coating
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Abandoned
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US13/251,845
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Chih-Hao Huang
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Cheng Uei Precision Industry Co Ltd
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Cheng Uei Precision Industry Co Ltd
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Priority to US13/251,845 priority Critical patent/US20120027939A1/en
Publication of US20120027939A1 publication Critical patent/US20120027939A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/62Metallic pigments or fillers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2401/00Form of the coating product, e.g. solution, water dispersion, powders or the like
    • B05D2401/30Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant
    • B05D2401/32Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant applied as powders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/64Nanometer sized, i.e. from 1-100 nanometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals

Definitions

  • the present invention generally relates to a coating and uses thereof, and more particularly to a nanocomposite coating and a method of coating for protecting a product with the nanocomposite coating.
  • An object of the present invention is to provide a nanocomposite coating and a method of coating for protecting a product with the nanocomposite coating.
  • the nanocomposite coating is formed by mixing a nanometer inorganic oxide gel, an organic solvent and a nanometer powder together.
  • the nanometer inorganic oxide gel is made by a sol-gel method and has 22.5 ⁇ 49.5% weight in the nanocomposite coating.
  • the organic solvent has 45 ⁇ 74.25% weight in the nanocomposite coating.
  • the nanometer powder has 1 ⁇ 10% weight in the nanocomposite coating.
  • the method is adapted to protect the product from being corroded and damaged by some exterior chemicals and is described hereinafter. Firstly, prepare the foregoing nanocomposite coating.
  • the nanocomposite coating of the present invention can protect the product from being corroded and damaged by the exterior chemicals by way of forming the nanometer protective films on the surfaces of the product.
  • a nanocomposite coating according to the present invention is a mixture of a nanometer inorganic oxide gel, an organic solvent and a nanometer powder, wherein the weight percentage of the nanometer inorganic oxide gel, the organic solvent and the nanometer powder in the nanocomposite coating is respectively 22.5 ⁇ 49.5%, 45 ⁇ 74.25% and 1 ⁇ 10%.
  • the nanometer inorganic oxide gel is made by a sol-gel method and can be any one of or a mixture of at least two selected from a nanometer silicon dioxide gel, a nanometer titanium dioxide gel and a nanometer zirconium dioxide gel.
  • the organic solvent can be any one of or a mixture of an ethanol solvent and an isopropanol solvent.
  • the nanometer powder has a 5 ⁇ 100 nm diameter and can be any one of or a mixture of a nanometer metal powder and a nanometer metal-oxide powder, wherein the nanometer metal powder can be any one of or a mixture of at least two selected from a nanometer platinum powder, a nanometer copper powder and a nanometer nickel powder and so on, the nanometer metal-oxide powder can be any one of or a mixture of at least two selected from a nanometer silicon dioxide powder, a nanometer titanium dioxide powder and a nanometer zirconium dioxide powder and so on.
  • the nanometer powder is processed by a surfactant before being mixed with the nanometer inorganic oxide gel and the organic solvent for improving a corrosion resistance thereof and further improving a corrosion resistance of the nanocomposite coating, wherein the surfactant can be any one of or a mixture of a sodium dodecylsulphonate and a polyvinyl pyrrolidone.
  • a method of coating for protecting a product with the foregoing nanocomposite coating is mainly adapted to protect the product from being corroded and damaged by some exterior chemicals, such as organic alcohol, organic ketone, acid, alkali and oil etc. The method is described hereinafter.
  • the foregoing nanocomposite coating is prepared.
  • the nanocomposite coating is coated onto surfaces of the product evenly by way of spraying, dipping or roll-to-rolling
  • the product coated with the nanocomposite coating is subjected to a room temperature or a heating environment lower than 170 degrees centigrade to make the nanocomposite coating dry (namely, evaporated to be a gas phase) for forming nanometer protective films on the surfaces of the product so as to protect the product from being corroded and damaged by the exterior chemicals.
  • the product is made of polyurethane plastic and the nanometer powder processed by the surfactant is a nanometer silicon dioxide powder having 2% weight in the nanocomposite coating and a 20 nm diameter.
  • the product is processed by the above-mentioned method for forming nanometer protective films of 50 microns thickness on the surfaces thereof.
  • do a corrosion-resisting test to the product with and without the nanometer protective films thereon respectively.
  • the nanocomposite coating of the present invention can well protect the product from being corroded and damaged by the exterior chemicals by way of forming the nanometer protective films on the surfaces of the product. Furthermore, the nanometer powder processed by the surfactant can further improve the corrosion resistance of the nanometer protective films.

Abstract

A nanocomposite coating and a method of coating for protecting a product with the nanocomposite coating are presented. Firstly, the nanocomposite coating is prepared, wherein the nanocomposite coating is formed by mixing 22.5˜49.5% nanometer inorganic oxide gel made by a sol-gel method, 45˜74.25% organic solvent and 1˜10% nanometer powder together. Next, the nanocomposite coating is coated onto surfaces of the product evenly by way of spraying, dipping or roll-to-rolling. Lastly, the product coated with the nanocomposite coating is subjected to a room temperature or a heating environment lower than 170 degrees centigrade to make the nanocomposite coating dry for forming nanometer protective films on the surfaces of the product.

Description

    CROSS REFERENCE
  • This is a divisional of U.S. application Ser. No. 12/276,117, filed on Nov. 21, 2008, which is incorporated herewith by reference.
  • BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention generally relates to a coating and uses thereof, and more particularly to a nanocomposite coating and a method of coating for protecting a product with the nanocomposite coating.
  • 2. The Related Art
  • At present, lots of products are made of engineering plastic materials. However, some engineering plastic materials, such as polycarbonate and modified polyphenylene oxide, are easily corroded and damaged by some exterior chemicals, such as organic alcohol, organic ketone, acid, alkali and oil etc. In order to protect the products made of the foregoing engineering plastic materials from being corroded and damaged, a nanocomposite coating and a method of coating for protecting the products with the nanocomposite coating are required.
  • SUMMARY OF THE INVENTION
  • An object of the present invention is to provide a nanocomposite coating and a method of coating for protecting a product with the nanocomposite coating. The nanocomposite coating is formed by mixing a nanometer inorganic oxide gel, an organic solvent and a nanometer powder together. The nanometer inorganic oxide gel is made by a sol-gel method and has 22.5˜49.5% weight in the nanocomposite coating. The organic solvent has 45˜74.25% weight in the nanocomposite coating. The nanometer powder has 1˜10% weight in the nanocomposite coating. The method is adapted to protect the product from being corroded and damaged by some exterior chemicals and is described hereinafter. Firstly, prepare the foregoing nanocomposite coating. Next, coat the nanocomposite coating onto surfaces of the product evenly by way of spraying, dipping or roll-to-rolling Lastly, subject the product coated with the nanocomposite coating to a room temperature or a heating environment lower than 170 degrees centigrade to make the nanocomposite coating dry for forming nanometer protective films on the surfaces of the product so as to protect the product from being corroded and damaged by the exterior chemicals.
  • As described above, the nanocomposite coating of the present invention can protect the product from being corroded and damaged by the exterior chemicals by way of forming the nanometer protective films on the surfaces of the product.
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
  • A nanocomposite coating according to the present invention is a mixture of a nanometer inorganic oxide gel, an organic solvent and a nanometer powder, wherein the weight percentage of the nanometer inorganic oxide gel, the organic solvent and the nanometer powder in the nanocomposite coating is respectively 22.5˜49.5%, 45˜74.25% and 1˜10%. The nanometer inorganic oxide gel is made by a sol-gel method and can be any one of or a mixture of at least two selected from a nanometer silicon dioxide gel, a nanometer titanium dioxide gel and a nanometer zirconium dioxide gel. The organic solvent can be any one of or a mixture of an ethanol solvent and an isopropanol solvent. The nanometer powder has a 5˜100 nm diameter and can be any one of or a mixture of a nanometer metal powder and a nanometer metal-oxide powder, wherein the nanometer metal powder can be any one of or a mixture of at least two selected from a nanometer platinum powder, a nanometer copper powder and a nanometer nickel powder and so on, the nanometer metal-oxide powder can be any one of or a mixture of at least two selected from a nanometer silicon dioxide powder, a nanometer titanium dioxide powder and a nanometer zirconium dioxide powder and so on. Furthermore, the nanometer powder is processed by a surfactant before being mixed with the nanometer inorganic oxide gel and the organic solvent for improving a corrosion resistance thereof and further improving a corrosion resistance of the nanocomposite coating, wherein the surfactant can be any one of or a mixture of a sodium dodecylsulphonate and a polyvinyl pyrrolidone.
  • A method of coating for protecting a product with the foregoing nanocomposite coating is mainly adapted to protect the product from being corroded and damaged by some exterior chemicals, such as organic alcohol, organic ketone, acid, alkali and oil etc. The method is described hereinafter.
  • Firstly, the foregoing nanocomposite coating is prepared.
  • Next, the nanocomposite coating is coated onto surfaces of the product evenly by way of spraying, dipping or roll-to-rolling
  • Lastly, the product coated with the nanocomposite coating is subjected to a room temperature or a heating environment lower than 170 degrees centigrade to make the nanocomposite coating dry (namely, evaporated to be a gas phase) for forming nanometer protective films on the surfaces of the product so as to protect the product from being corroded and damaged by the exterior chemicals.
  • An unlimited embodiment is described as following. In the unlimited embodiment, the product is made of polyurethane plastic and the nanometer powder processed by the surfactant is a nanometer silicon dioxide powder having 2% weight in the nanocomposite coating and a 20 nm diameter. The product is processed by the above-mentioned method for forming nanometer protective films of 50 microns thickness on the surfaces thereof. Next, do a corrosion-resisting test to the product with and without the nanometer protective films thereon respectively. Put the product with and without the nanometer protective films thereon respectively into 100% concentration of propyl alcohol solution, 95# leadless gasoline, engine oil and 6 mol/L of sodium hydroxide solution for being reacted about 12 hours. Experiment results show that, the product with the nanometer protective films thereon is scarcely corroded and damaged, while the product without the nanometer protective films thereon is seriously corroded and damaged in the propyl alcohol solution and is more or less corroded and damaged in another three solutions. Therefore, it is known from the unlimited embodiment that the nanometer protective films formed by the nanocomposite coating can really protect the product from being corroded and damaged by the exterior chemicals well.
  • As described above, the nanocomposite coating of the present invention can well protect the product from being corroded and damaged by the exterior chemicals by way of forming the nanometer protective films on the surfaces of the product. Furthermore, the nanometer powder processed by the surfactant can further improve the corrosion resistance of the nanometer protective films.

Claims (9)

1. A method of coating for protecting a product with a nanocomposite coating adapted to protect the product from being corroded and damaged by some exterior chemicals, the method comprising the steps of:
preparing the nanocomposite coating which is formed by mixing a nanometer inorganic oxide gel made by a sol-gel method, an organic solvent and a nanometer powder together;
coating the nanocomposite coating onto surfaces of the product evenly by way of spraying, dipping or roll-to-rolling; and
subjecting the product coated with the nanocomposite coating to a room temperature or a heating environment lower than 170 degrees centigrade to make the nanocomposite coating dry for forming nanometer protective films on the surfaces of the product so as to protect the product from being corroded and damaged by the exterior chemicals;
wherein the weight percentage of the nanometer inorganic oxide gel, the organic solvent and the nanometer powder in the nanocomposite coating is 22.5˜49.5%, 45˜74.25% and 1˜10% respectively.
2. The method as claimed in claim 1, wherein the nanometer powder is any one of or a mixture of a nanometer metal powder and a nanometer metal-oxide powder.
3. The method as claimed in claim 2, wherein the nanometer metal powder is any one of or a mixture of at least two selected from a nanometer platinum powder, a nanometer copper powder and a nanometer nickel powder.
4. The method as claimed in claim 2, wherein the nanometer metal-oxide powder is any one of or a mixture of at least two selected from a nanometer silicon dioxide powder, a nanometer titanium dioxide powder and a nanometer zirconium dioxide powder.
5. The method as claimed in claim 1, wherein the nanometer powder is processed by a surfactant before being mixed with the nanometer inorganic oxide gel and the organic solvent to form the nanocomposite coating.
6. The method as claimed in claim 5, wherein the surfactant is any one of or a mixture of a sodium dodecylsulphonate and a polyvinyl pyrrolidone.
7. The method as claimed in claim 1, wherein the diameter of the nanometer powder is 5˜100 nm.
8. The method as claimed in claim 1, wherein the nanometer inorganic oxide gel is any one of or a mixture of at least two selected from a nanometer silicon dioxide gel, a nanometer titanium dioxide gel and a nanometer zirconium dioxide gel.
9. The method as claimed in claim 1, wherein the organic solvent is any one of or a mixture of an ethanol solvent and an isopropanol solvent.
US13/251,845 2008-11-21 2011-10-03 Nanocomposite coating and the method of coating thereof Abandoned US20120027939A1 (en)

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US13/251,845 US20120027939A1 (en) 2008-11-21 2011-10-03 Nanocomposite coating and the method of coating thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109232023A (en) * 2018-08-31 2019-01-18 融铨半导体(苏州)有限公司 A kind of preparation method of double coat of silicon carbide graphite load plates
AU2016323778B2 (en) * 2015-09-18 2020-10-22 Carbon Sink, Inc. Devices, systems and methods for enhanced biomass growth in greenhouses

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8720570B2 (en) 2011-02-04 2014-05-13 Baker Hughes Incorporated Method of corrosion mitigation using nanoparticle additives
US9303171B2 (en) 2011-03-18 2016-04-05 Tesla Nanocoatings, Inc. Self-healing polymer compositions
WO2013033562A2 (en) * 2011-08-31 2013-03-07 Jorma Virtanen Composition for corrosion prevention
US10570296B2 (en) 2012-03-19 2020-02-25 Tesla Nanocoatings, Inc. Self-healing polymer compositions
US10479897B2 (en) 2014-01-16 2019-11-19 International Business Machines Corporation Producing an apparatus by covering an electronic component with a conformal coating containing metal nanoparticles
CN105296983A (en) * 2015-10-28 2016-02-03 天长市润达金属防锈助剂有限公司 Environment-friendly aluminum alloy anti-corrosion pulling sol and preparation method thereof
US10483464B1 (en) 2018-05-31 2019-11-19 Uchicago Argonne, Llc Resistive switching memory device

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4929278A (en) * 1988-01-26 1990-05-29 United States Department Of Energy Sol-gel antireflective coating on plastics
US5753373A (en) * 1995-12-21 1998-05-19 Minnesota Mining And Manufacturing Company Coating composition having anti-reflective and anti-fogging properties

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4338360A1 (en) * 1993-11-10 1995-05-11 Inst Neue Mat Gemein Gmbh Process for the production of functional glass-like layers
US6001164A (en) * 1995-06-13 1999-12-14 Nissan Chemical Industries, Ltd. Hydrated zinc stannate sols, coating compositions and optical elements
WO2001042155A1 (en) * 1999-12-13 2001-06-14 Nippon Sheet Glass Co., Ltd. Low-reflection glass article
US20060204655A1 (en) * 2003-02-06 2006-09-14 Koji Takahashi Method for producing article having been subjected to low reflection treatment, solution for forming low reflection layer and article having been subjected to low reflection treatment
US20070000407A1 (en) * 2003-10-09 2007-01-04 York International Corporation Nano composite photocatalytic coating
JPWO2005088352A1 (en) * 2004-03-16 2008-01-31 Hoya株式会社 Manufacturing method of plastic lens
US8222302B2 (en) * 2005-11-29 2012-07-17 The Hong Kong University Of Science And Technology Titania-silica aerogel monolith with ordered mesoporosity and preparation thereof
DE102006032755A1 (en) * 2006-07-14 2008-01-17 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Stable suspensions of crystalline TiO2 particles from hydrothermally treated sol-gel precursor powders
EP1882722A1 (en) * 2006-07-25 2008-01-30 Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO A coating composition
JP2008094972A (en) * 2006-10-12 2008-04-24 Adeka Corp Coating liquid and manufacturing method of titanic acid-based ceramic film using the coating liquid

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4929278A (en) * 1988-01-26 1990-05-29 United States Department Of Energy Sol-gel antireflective coating on plastics
US5753373A (en) * 1995-12-21 1998-05-19 Minnesota Mining And Manufacturing Company Coating composition having anti-reflective and anti-fogging properties

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Sakka, Volume III: Applications of Sol-Gel Technology, 2005, pg. 712-713 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2016323778B2 (en) * 2015-09-18 2020-10-22 Carbon Sink, Inc. Devices, systems and methods for enhanced biomass growth in greenhouses
CN109232023A (en) * 2018-08-31 2019-01-18 融铨半导体(苏州)有限公司 A kind of preparation method of double coat of silicon carbide graphite load plates

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US20100129555A1 (en) 2010-05-27

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