US2531571A - Manufacture of glass yarn - Google Patents

Manufacture of glass yarn Download PDF

Info

Publication number
US2531571A
US2531571A US589688A US58968845A US2531571A US 2531571 A US2531571 A US 2531571A US 589688 A US589688 A US 589688A US 58968845 A US58968845 A US 58968845A US 2531571 A US2531571 A US 2531571A
Authority
US
United States
Prior art keywords
fibers
strand
coating
glass
guide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US589688A
Inventor
Hyde James Franklin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Owens Corning
Original Assignee
Owens Corning Fiberglas Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Owens Corning Fiberglas Corp filed Critical Owens Corning Fiberglas Corp
Priority to US589688A priority Critical patent/US2531571A/en
Application granted granted Critical
Publication of US2531571A publication Critical patent/US2531571A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10Coating
    • C03C25/24Coatings containing organic materials
    • C03C25/40Organo-silicon compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/2962Silane, silicone or siloxane in coating

Definitions

  • the present invention relates to coatings for glass fibers particularly when grouped in strand or yarn form.
  • binding fluid a liquid called a "binding fluid.”
  • the fibers pick up this binding fluid as they pass over the pad at very high velocities.
  • the fluid must be able to impart lubrication to the fibers as they are drawn over the pad and also it must lubricate the fibers against themselves to prevent breakage by abrasion during twisting and winding operations.
  • this fluid must contain adhesive ingredients for binding all the individual filaments from one bushing (100-400) into one strand. This strand must function as a single fine thread during the twisting process.
  • this .strand is not well bound, it will tend to separate fibers against abrasion from each other in the final yarn, but it should not inhibit the sticking properties of the binder.
  • a tightly bound strand without proper lubricant breaks very quickly under friction and abrasion during twisting and winding.
  • the present invention is also applicable to slivers of staple-type fibers made by the process of the Tucker and Lannan Patent No. 2,264,345, of December 2, 1941.
  • molten glass streams are attenuated by a gaseous blast and the fibers as they are formed are collected in a web which is elongated and narrowed into the form of a silver.
  • the sliver lacks sumcient integrity and handleability and the loose fibers and fiber ends are found objectionable.
  • One of the primar purposes of the coating itself is to bond the fibers together in strand form prior to twisting without fraying or subdividing. Once extremely fine fibers, that is, below .0004 inch and particularly below about .0002 inch in diameter, have been intertwisted into a thread, they will retain their coherence and strength without fraying or subdividing and without the necessity of an adhesive coating material. Before twisting and when in strand form without proper adhesive, it is diflicult to handle the strands and process them through the conventional textile machines.
  • Another object of the coating material is to retain the loose ends of any broken fibers in the strand without permitting them to break away and form a fuzz.
  • This feature is particularly important when attempting to unwind a strand strand cannot be removed in the proper manu from "a wound package thereof, owing to the fact that a loose fiber continues to break away from the main body of the strand as it is unwound and produces a fuzz around the package as the loose fiber is broken by the subsequent unwindinss of the main body of the strand. This causes other fibers to be broken away from the strand until the package is destroyed.
  • Another obJect of the invention is to provide a coating substance which will readily distribute itself uniformly over the fibers at extremely high speeds.
  • Fig. l is an elevational view of an apparatus for attenuating a multiplicity of fine glass fibers of substantially continuous length, grouping them in strand form, and applying a coating thereto in accordance with the present invention
  • FIG. 2 in a fragmentary perspective view of the apparatus shown in Fig. 1.
  • hydrolyzable organo-silanes I mean derivatives of SiH4, which contain readily hydrolyzable radicals such as halogens, amino groups, alkoxy, aroxy, and acyloxy radicals, etc., and organic radicals that are joined to the silicon atoms through carbon atoms.
  • organic radicals are as follows: aliphatic radicals, such as methyl, ethyl, propyl, isopropyl, butyl, amyl, hexyl, heptyl to octadecyl and higher; alicyclic radicals such as cyclopentyl, cyclohexyl, etc.; aryl and alkaryl radicals such as phenyl, monoand poly-alkyl phenyls as tolyl, xylyl, mesityl, mono-, di-, and tri-ethyl phenyls, mono-, diand tri-propyl phenyls, etc., naphthyl, monoand poly-alkyl naphthyls as methyl naphthyl, diethyl naphthyl, tri-propyl naphthyl, etc.; tetrahydronaphthyl, anthracyl, etc.; aral
  • the coating materials of my invention are generally applied in the form of solutions in organic solvents, the nature of the solvent depending upon the specific characteristics and properties of the compound or compounds involved.
  • concentration of the solution also depends upon the par-' ticular compositions being employed by the optimum concentration may be readily determined by preliminary tests. I have also found that other substances may be added in small amounts such as waxes and vegetable oils in order to improve the binding or lubricating effect.
  • the coating materials may be applied to the glass fibers by any suitable means, such as a pad, groove, roller, or other suitable methods. The glass fibers are passed through the coating material, or films thereof, picking up the proper amount, and producing a flexible, coherent strand which may be easily wound into a package.
  • hydrolyzable organo-silanes which may be employed in practicing my invention are as follows: methylsilicon trichlorlde, dimethylsilicon dichloride, trimethylsilicon chloride, methyltriethoxysilane, dimethyldiethoxysilane, trimethylethoxysilane, methyldichlorsilane, dimethylchlorsilane, ethylsilicon trichlorlde, diethyldiethoxysilane, phenylmethyldiethoxysilane, and diphenylsilicon dichloride.
  • RSiCl where R is an alkyl radical having from 10 to 31 carbon atoms.
  • reaction mass was stirred for another hour with the temperature being held at reflux. The stirring was then stopped and the mixture allowed to stand to permit settling of the salt and cooling. to room temperature. The supernatant liquor was then carefully siphoned into a closed dropping funnel on the coupling reactor which, likewise, was a 3- necked flask provided with the aforementioned funnel, a stirrer, and a condenser.
  • Tetradeculsilicon trichloride (CuHzoSiCla) was prepared in a manner similar to the preparation of the dodecylsilicon tricbioride of Example 1 with the exception that the Grignard reagent which was prepared from myristyl bromide (CuHzoBr) was diluted with ether to a relatively EXAMPLE 3
  • Octadeculsilicon trichloride Octadecylsilicon trichloride was likewise prepared in a manner similar to that described in Example 1.
  • the Grignard reagent was made from pure stearyl bromide (CmHznSiBr) An ether solution containing 3.54 mols of the Grignard reagent was slowly introduced into a coupling reactor containing 7.3 mols of silicon tetrachloride and 1.5 liters of benzene. The coupling product was filtered in the usual manner and the filtrate fractionally distilled in vacuo. A fraction boiling at 159 to 162 C. at 13 mm. was identifled by analysi to be CraHazSiCl. Its density was 0.95 g./cc. at 22 0.
  • reference character 5 designates broadly to the filamentizing apparatus wherein a multiplicity of individual filaments 6 are simultaneously being supplied continuously from a single source such as a feeder I or other supply means and are being drawn and attenuated by means of a revolving spool or drum 9 on which the fibers are wound to form a package l thereon.
  • a blower II which may be provided in proximity to the feeder I, is adapted to chill the glass as it emerges from the feeder, although the present invention is not limited to any particular filamentizing apparatus.
  • the filaments 6 as they emerge from the filamentizing apparatus are grouped together in substantially parallel relation and drawn over a concave guide l2 in the form of a groove or eye which serves to size the filaments and simultaneously group them into a strand l3.
  • the filaments are preferably turned through as small an angle as possible in order to reduce to a minimum the amount of force exerted by the strand upon the guide and the resultant friction.
  • the strand l3 may then be traversed by means of traverse II which assists in the formation of the package III upon the drum or spool 9.
  • the gathering and lubrication guide I2 is preferably made from a very light metal, such as aluminum, in order to keep its inertia as low as possible.
  • the free end of the guide is provided with agroove 4 (see Fig. 2) having a rounded outer surface which may be covered by means of a pad l2a composed of suitable porous material such as a felt, muslin, sponge, cloth, or the like.
  • the upper portion l5 of the guide [2 is in the form or an inclined trough upon which the coating substance may be fed and introduced to the groove 4 over which the filaments are drawn.
  • the guide l2 may be fastened to a support It by means of a screw il or the like.
  • the support I is preferably provided with two upstanding flanges I8, one at each end thereof, and each secured to and suspended from yielding means ll which are preferably in the form of flexible metal tapes, composed, for example, of spring steel or the like.
  • the upper ends of the tapes I9 may be secured to an upper support 20 having dimensions comparable to the lower support It, whereby supports it and 20 and the tapes l9 define a parallelogram which gives approximately straight line motion to the guide l2 as it is moved by the strand l3.
  • the upper support 20 may be mounted upon 9. lug 50 by means of set screws 5
  • the lug 50 may be pivotally secured to a bushing 2
  • a bolt 53 may be provided to hold the lug in place and permit the same to pivot in relation to the container 22.
  • the container 22 is provided with an outlet orifice 23 through which sizing material may be fed.
  • a conduit 24 communicates with the outlet 23 and serves to convey the sizing material to the guide l2 by gravitational means.
  • An adjusting needle 25 fits into the orifice 23 and may be placed in any desired vertical position by means of an adjusting pin 23, similar in design to a conventional oil dripper.
  • a heating means 28 such as an immersion type heater using electrical energy supplied through the electrical connections 29.
  • the container 22 may be adjustably mounted upon a suitable elbow 30 to which it is pivotally attached for tilting movement by means of a pivot bolt 3
  • the container is held in any de sired position of adjustment by means of a screw rod 32 and wing nut 33.
  • the elbow 30 in turn may be mounted upon one end of an arm 35 having a collar 38 at the opposite end thereof, fitting around a vertical supporting rod 31.
  • the collar 36 may swing around on the rod 31 and be held in adjusted position by means of thebolt and nut 38.
  • a system of rods 40 having an adjustable connection 4
  • a cup 42 which is spaced below the guide i 2 to receive any surplus drippings of sizing material which may fall from the guide l2.
  • the cup may be provided with an opening 44 through which the strand l3 may pass without touching the sides of the cup. When not in operation the cup may be swung about the connection 4
  • the organosilicon compositions of my invention or mixtures thereof may be held in the container 22, heated to the desired temperature by means of the heater 23, and fed through the orifice 23 and through the conduit 24 to the guide 12.
  • the pad He may be saturated with the coating material, especially the groove 4 around which' the filaments 3 are drawn.
  • the filaments in being drawn over the pad l2a are lubricated by the liquid coating material and are simultaneously coated thereby.
  • the coating material In traveling from the guide l2 to the package iii, the coating material may be sufllciently solidified that it will not cause the adjacent strands upon the package to adhere to one another. However, when such substances as oils or thin solutions are applied, the coating may remain substantially in a fluid or slightly viscous condition on the package which, however, does not prevent the strand from being unwound.
  • the guide 121s supported yieldingly by means of the fiexible tapes l9 so that when the strand I3 is subjected to any unusual stresses or irregular pulling forces, even of minute magnitude, the guide I! will yield, maintaining a substantially uniform friction and force against the strand.
  • the guide I2 is permitted to follow the sideway movements by oscillating around the axis of the bolt 53, and thus any jerking movements emanating from the packaging process are smoothed out and dissipated. This arrangement has been found to materially assist-in the efiiciency of the sizing operation.
  • the coating liquid surrounding each fiber conditions the fibers to provide a soft, supple fabric that is smooth and lustrous.
  • the good electrical properties of the organo-silicon compounds also make the fabrics well suited for use in electrical insulation.
  • the moisture repellent character of the compounds adapts the fabrics to uses where high humidity and other moisture conditions prevail.
  • the organo-silicon coatings of my invention For certain industrial applications, it has been found unnecessary to remove the organo-silicon coatings of my invention. In fact, the continued presence of the organo-silicon compounds has been found desirable. For example, if an electrical insulating varnish 'is to be applied to the glass fibers, the organo-silicon compound not only possesses such electrical properties as not to impair the insulating character of the product, but it also serves to waterproof the glass and to act as a primer for the insulating varnish causing it to adhere much more tenaciously than it otherwise would.
  • a strand composed of a multiplicity of long, fine attenuated glass fibers that have been coated with an adhesive and lubricating liquid composition comprising a hydrolyzable organomonosilane, the organic substituents of the silane being alkyl radicals attached to silicon through direct carbon linkage.
  • a strand composed of a multiplicity of long, fine attenuated glass fibers that have been coated with an adhesive and lubricating liquid composition comprising a hydrolyzable organo-silane of the formula RSiCla, where R is an alkyl radical having from ten to thirty-one carbon atoms.

Description

I J. F. HYDE MANUFACTURE OF GLASS YARN Nov. 28, 1950 Filed April 21, 1945 Zinhmtur films-s Fae/141M640:
MQL M M Qtlormgs Patented Nov. 28, 1950 James Franklin Hyde, Corning, N. Y., assignor, by mesne assignments, to Owens-Corning Fiberglas Corporation Application April 21, 1945, Serial No. ssacss 7 Claims.
The present invention relates to coatings for glass fibers particularly when grouped in strand or yarn form.
This application is a continuation-in-part of my copending applications Serial Number 490,517, filed June 11, 1943, now Patent No. 2,439,689, dated April 13,- 1948, and Serial Number 505,833, filed October 11,1943, now Patent No. 2,390,370, dated December 4, 1945. g
It is the purpose of the present invention to provide coatings for glass fibers that facilitate the formation of strands of the fibers, that assure ready fabrication of the strands into yarns and woven fabrics, and that improve the handleability of strands, yarns, and slivers and lend new properties to the finished article.
' In the mechanical drawing method for the production of a plurality of extremely fine, long, continuous fibers, as, for example, by the method illustrated and described in the Slayter and Thom-as Patent No. 2,234,986 dated March 18, 1941, it has been found that the speed of attenuation and production of fibers was limited by the speeds at which the fibers could be formed into strands and wound on packages in such a manner that the strands could be unwound and proc-,
essed thereafter in the conventional textile machines. When the bundle of fibers is drawn from the molten glass flowing from the hot bushing, it is pressed against a pad continually saturated with a liquid called a "binding fluid." The fibers pick up this binding fluid as they pass over the pad at very high velocities. The fluid must be able to impart lubrication to the fibers as they are drawn over the pad and also it must lubricate the fibers against themselves to prevent breakage by abrasion during twisting and winding operations. Also this fluid must contain adhesive ingredients for binding all the individual filaments from one bushing (100-400) into one strand. This strand must function as a single fine thread during the twisting process. If this .strand is not well bound, it will tend to separate fibers against abrasion from each other in the final yarn, but it should not inhibit the sticking properties of the binder. An over lubricated ner from the winding tubes in the twisting operation. A tightly bound strand without proper lubricant breaks very quickly under friction and abrasion during twisting and winding. Thus, the problem resolves itself into balancing two opposing eifects: (1) that of sticking the fibers together, and (2) that of lubricating them against themselves and against abrasion from fabricating equipment. It is an object of this invention to provide a coating that permits glass fibers to be producedat extremely high speeds, as, for example, above 5,000 or even 20,000 feet per minute, and yet enable the fibers to be gathered into strand form and packaged into a useful article.
The present invention is also applicable to slivers of staple-type fibers made by the process of the Tucker and Lannan Patent No. 2,264,345, of December 2, 1941. In this process molten glass streams are attenuated by a gaseous blast and the fibers as they are formed are collected in a web which is elongated and narrowed into the form of a silver. For some uses the sliver lacks sumcient integrity and handleability and the loose fibers and fiber ends are found objectionable.
One of the primar purposes of the coating itself is to bond the fibers together in strand form prior to twisting without fraying or subdividing. Once extremely fine fibers, that is, below .0004 inch and particularly below about .0002 inch in diameter, have been intertwisted into a thread, they will retain their coherence and strength without fraying or subdividing and without the necessity of an adhesive coating material. Before twisting and when in strand form without proper adhesive, it is diflicult to handle the strands and process them through the conventional textile machines.
It is a further object of the present invention to provide a coating for the fibers that will bind the fibers in the sliver and bind down loose fiber ends and facilitate subsequent fabricating operations such as twisting and we ving.
It is a further object to provide a strand of glass fibers wherein the individual fibers are provided with a coating which permits relative movement of the fibers in the strand, thereby preventing breaking of the fibers as the strand is twisted and woven or braided.
Another object of the coating material is to retain the loose ends of any broken fibers in the strand without permitting them to break away and form a fuzz. This feature is particularly important when attempting to unwind a strand strand cannot be removed in the proper manu from "a wound package thereof, owing to the fact that a loose fiber continues to break away from the main body of the strand as it is unwound and produces a fuzz around the package as the loose fiber is broken by the subsequent unwindinss of the main body of the strand. This causes other fibers to be broken away from the strand until the package is destroyed.
Another obJect of the invention is to provide a coating substance which will readily distribute itself uniformly over the fibers at extremely high speeds. v
It is also an object of this invention to provide a coating which will not have to be removed where the glass yarn is to be subsequently impregnated with insulating varnishes.
Other objects and advantages of the present invention will become apparent from the following description taken in conjunction with the drawing, in which- Fig. l is an elevational view of an apparatus for attenuating a multiplicity of fine glass fibers of substantially continuous length, grouping them in strand form, and applying a coating thereto in accordance with the present invention; and
Fig. 2 in a fragmentary perspective view of the apparatus shown in Fig. 1.
In accordance with my invention, I have discovered that the foregoing objects are realized if the individual fibers in the strand are provided with a coating comprising one or more hydrolyzable organo-silanes. These serve admirably as coatings for the individual fine glass filaments and enable the production and fabrication thereof to be carried on at high speeds.
By hydrolyzable organo-silanes, I mean derivatives of SiH4, which contain readily hydrolyzable radicals such as halogens, amino groups, alkoxy, aroxy, and acyloxy radicals, etc., and organic radicals that are joined to the silicon atoms through carbon atoms. Examples of such organic radicals are as follows: aliphatic radicals, such as methyl, ethyl, propyl, isopropyl, butyl, amyl, hexyl, heptyl to octadecyl and higher; alicyclic radicals such as cyclopentyl, cyclohexyl, etc.; aryl and alkaryl radicals such as phenyl, monoand poly-alkyl phenyls as tolyl, xylyl, mesityl, mono-, di-, and tri-ethyl phenyls, mono-, diand tri-propyl phenyls, etc., naphthyl, monoand poly-alkyl naphthyls as methyl naphthyl, diethyl naphthyl, tri-propyl naphthyl, etc.; tetrahydronaphthyl, anthracyl, etc.; aralkyl such as benzyl, phenylethyl, eta; alkenyl such as methallyl, allyl, etc.; and heterocyclic radicals. The above organic radicals may also, if desired, contain inorganic substituents such as halogens, etc.
The coating materials of my invention are generally applied in the form of solutions in organic solvents, the nature of the solvent depending upon the specific characteristics and properties of the compound or compounds involved. The concentration of the solution also depends upon the par-' ticular compositions being employed by the optimum concentration may be readily determined by preliminary tests. I have also found that other substances may be added in small amounts such as waxes and vegetable oils in order to improve the binding or lubricating effect. The coating materials may be applied to the glass fibers by any suitable means, such as a pad, groove, roller, or other suitable methods. The glass fibers are passed through the coating material, or films thereof, picking up the proper amount, and producing a flexible, coherent strand which may be easily wound into a package. In winding the I have found to be particularly useful in the practice of my invention are the following when dissolved in either Stoddard solvent or toluene to yield approximately ten per cent solutions: laurylsilicon trichloride (C12H25SiCla), tetradecylsilicon trichloride (Ci4H2sSiC13) and octadecylsilicon trichloride (CraHarSiCla). Other examples of hydrolyzable organo-silanes which may be employed in practicing my invention are as follows: methylsilicon trichlorlde, dimethylsilicon dichloride, trimethylsilicon chloride, methyltriethoxysilane, dimethyldiethoxysilane, trimethylethoxysilane, methyldichlorsilane, dimethylchlorsilane, ethylsilicon trichlorlde, diethyldiethoxysilane, phenylmethyldiethoxysilane, and diphenylsilicon dichloride. In general, I prefer to employ those hydrolyzable organosilanes having the general formula RSiCl: where R is an alkyl radical having from 10 to 31 carbon atoms. Such compounds, I have found to possess unusual waterproofing and lubricating properties.
By way of illustration the preparation and properties of certain of the silanes of my invention are described in the following examples.
EXAMPLE 1 Dodecyl silicon trichloride parts (0.43 mol) of lauryl chloride (CizHzsCl) dissolved in 68 parts (0.92 mol) of anhydrous ethyl ether were added slowly to 12.5 parts (0.51 mol) of magnesium turnings under .35 parts of ethyl ether. The latter was in a 3-necked glass flask provided with a stirrer, a condenser, and a dropping funnel, respectively. The addition of the chloride was accomplished through the dropping funnel. Reaction was initiated by the addition of a little bromide in ether. The addition of the chloride was such thereafter as to maintain a gentle reflux of the ether. After all the chloride had been admitted, the reaction mass was stirred for another hour with the temperature being held at reflux. The stirring was then stopped and the mixture allowed to stand to permit settling of the salt and cooling. to room temperature. The supernatant liquor was then carefully siphoned into a closed dropping funnel on the coupling reactor which, likewise, was a 3- necked flask provided with the aforementioned funnel, a stirrer, and a condenser.
The Grignard reagent so produced was added to a twofold excess of parts of silicon tetrachloride (0.83 mole) in parts of benzene. The reaction mas was stirred for 3 hours and then heated to reflux temperature for another 3 hours with stirring being continued. The product was filtered and the filtrate was then fractionally distilled, yielding a fraction at 162-l71'C. at 18 mm. in an amount corresponding to 67% of theory. An analysis of this fraction was as follows:
Per Cent Per Cent Per Cent Per Cent C H C] Si Found 34. Theory 5 EXAMPLE2 Tetradeculsilicon trichloride Tetradecylsilicon trichloride (CuHzoSiCla) was prepared in a manner similar to the preparation of the dodecylsilicon tricbioride of Example 1 with the exception that the Grignard reagent which was prepared from myristyl bromide (CuHzoBr) was diluted with ether to a relatively EXAMPLE 3 Octadeculsilicon trichloride Octadecylsilicon trichloride was likewise prepared in a manner similar to that described in Example 1. The Grignard reagent was made from pure stearyl bromide (CmHznSiBr) An ether solution containing 3.54 mols of the Grignard reagent was slowly introduced into a coupling reactor containing 7.3 mols of silicon tetrachloride and 1.5 liters of benzene. The coupling product was filtered in the usual manner and the filtrate fractionally distilled in vacuo. A fraction boiling at 159 to 162 C. at 13 mm. was identifled by analysi to be CraHazSiCl. Its density was 0.95 g./cc. at 22 0.
Referring now more particularly to the drawing, reference character 5 designates broadly to the filamentizing apparatus wherein a multiplicity of individual filaments 6 are simultaneously being supplied continuously from a single source such as a feeder I or other supply means and are being drawn and attenuated by means of a revolving spool or drum 9 on which the fibers are wound to form a package l thereon. A blower II which may be provided in proximity to the feeder I, is adapted to chill the glass as it emerges from the feeder, although the present invention is not limited to any particular filamentizing apparatus.
The filaments 6 as they emerge from the filamentizing apparatus are grouped together in substantially parallel relation and drawn over a concave guide l2 in the form of a groove or eye which serves to size the filaments and simultaneously group them into a strand l3. In being drawn over the guide l2, the filaments are preferably turned through as small an angle as possible in order to reduce to a minimum the amount of force exerted by the strand upon the guide and the resultant friction. The strand l3 may then be traversed by means of traverse II which assists in the formation of the package III upon the drum or spool 9. v
The gathering and lubrication guide I2 is preferably made from a very light metal, such as aluminum, in order to keep its inertia as low as possible. The free end of the guide is provided with agroove 4 (see Fig. 2) having a rounded outer surface which may be covered by means of a pad l2a composed of suitable porous material such as a felt, muslin, sponge, cloth, or the like. The upper portion l5 of the guide [2 is in the form or an inclined trough upon which the coating substance may be fed and introduced to the groove 4 over which the filaments are drawn. The guide l2 may be fastened to a support It by means of a screw il or the like. The support I is preferably provided with two upstanding flanges I8, one at each end thereof, and each secured to and suspended from yielding means ll which are preferably in the form of flexible metal tapes, composed, for example, of spring steel or the like. The upper ends of the tapes I9 may be secured to an upper support 20 having dimensions comparable to the lower support It, whereby supports it and 20 and the tapes l9 define a parallelogram which gives approximately straight line motion to the guide l2 as it is moved by the strand l3. The upper support 20 may be mounted upon 9. lug 50 by means of set screws 5|. In order to permit pivoting of the system under the influence of the traversing movement of the strand Hi, the lug 50 may be pivotally secured to a bushing 2| which is located at the bottom of a sizing container 22. A bolt 53 may be provided to hold the lug in place and permit the same to pivot in relation to the container 22.
The container 22 is provided with an outlet orifice 23 through which sizing material may be fed. A conduit 24 communicates with the outlet 23 and serves to convey the sizing material to the guide l2 by gravitational means. An adjusting needle 25 fits into the orifice 23 and may be placed in any desired vertical position by means of an adjusting pin 23, similar in design to a conventional oil dripper.
Arranged preferably in the lower portion of the container 22 is a heating means 28, such as an immersion type heater using electrical energy supplied through the electrical connections 29.
The container 22 may be adjustably mounted upon a suitable elbow 30 to which it is pivotally attached for tilting movement by means of a pivot bolt 3|. The container is held in any de sired position of adjustment by means of a screw rod 32 and wing nut 33.
The elbow 30 in turn may be mounted upon one end of an arm 35 having a collar 38 at the opposite end thereof, fitting around a vertical supporting rod 31. The collar 36 may swing around on the rod 31 and be held in adjusted position by means of thebolt and nut 38.
Depending from the elbow 30 is a system of rods 40 having an adjustable connection 4|. Supported at the free end thereof is a cup 42 which is spaced below the guide i 2 to receive any surplus drippings of sizing material which may fall from the guide l2. As shown in Fig. 2, the cup may be provided with an opening 44 through which the strand l3 may pass without touching the sides of the cup. When not in operation the cup may be swung about the connection 4| out of the path of the strand l3.
In the operation of the present device, the organosilicon compositions of my invention or mixtures thereof, may be held in the container 22, heated to the desired temperature by means of the heater 23, and fed through the orifice 23 and through the conduit 24 to the guide 12. The pad He may be saturated with the coating material, especially the groove 4 around which' the filaments 3 are drawn. The filaments in being drawn over the pad l2a are lubricated by the liquid coating material and are simultaneously coated thereby. In traveling from the guide l2 to the package iii, the coating material may be sufllciently solidified that it will not cause the adjacent strands upon the package to adhere to one another. However, when such substances as oils or thin solutions are applied, the coating may remain substantially in a fluid or slightly viscous condition on the package which, however, does not prevent the strand from being unwound.
Should any filament 6 break during its attenuation, an operator may restart the stream flow by means of a bait or the like and after a preliminary attenuation may draw the filament adjacent the others across the groove 4, and as it takes on its allotment of coating material, it Joins with the other filaments in the strand and passes on into the package automatically.
It is to be observed that in the process of coating, the guide 121s supported yieldingly by means of the fiexible tapes l9 so that when the strand I3 is subjected to any unusual stresses or irregular pulling forces, even of minute magnitude, the guide I! will yield, maintaining a substantially uniform friction and force against the strand. Moreover, as the strand is traversed back and forth by the traverse I4, the guide I2 is permitted to follow the sideway movements by oscillating around the axis of the bolt 53, and thus any jerking movements emanating from the packaging process are smoothed out and dissipated. This arrangement has been found to materially assist-in the efiiciency of the sizing operation.
After the strands have been fabricated into the finished product, as, for example, into a woven, knitted, braided, or otherwise interlaced glass fabric, the coating liquid surrounding each fiber conditions the fibers to provide a soft, supple fabric that is smooth and lustrous. The good electrical properties of the organo-silicon compounds also make the fabrics well suited for use in electrical insulation. Furthermore, the moisture repellent character of the compounds adapts the fabrics to uses where high humidity and other moisture conditions prevail.
For certain industrial applications, it has been found unnecessary to remove the organo-silicon coatings of my invention. In fact, the continued presence of the organo-silicon compounds has been found desirable. For example, if an electrical insulating varnish 'is to be applied to the glass fibers, the organo-silicon compound not only possesses such electrical properties as not to impair the insulating character of the product, but it also serves to waterproof the glass and to act as a primer for the insulating varnish causing it to adhere much more tenaciously than it otherwise would.
Modifications and variations may be resorted to within the scope and the spirit of the present invention as defined in the appended claims.
I claim:
1. A strand composed of a multiplicity of long, fine attenuated glass fibers that have been coated with an adhesive and lubricating liquid composition comprising a hydrolyzable organomonosilane, the organic substituents of the silane being alkyl radicals attached to silicon through direct carbon linkage.
2. A strand composed of a multiplicity of long, fine attenuated glass fibers that have been coated with an adhesive and lubricating liquid composition comprising a hydrolyzable organo-silane of the formula RSiCla, where R is an alkyl radical having from ten to thirty-one carbon atoms.
' 3. A strand composed of a multiplicity of long extremely fine glass fibers that have been coated with an adhesive and lubricating liquid composition comprising lauryl silicon trichloride.
4. A strand composed of a multiplicity of long, extremely fine glass fibers that have been coated with an adhesive and lubricating liquid composition comprising tetradecylsilicon trichloride.
5. A strand composed of a multiplicity of long, extremely fine glass fibers that have been coated with an adhesive and lubricating liquid composition comprising octadecylsilicon trichloride.
6. In the method of grouping glass fibers into a yarn, the step of treating such fibers with a solution of a hydrolyzable organomonosilane in an organic solvent therefor, the organic substituents of the silane being alkyl radicals attached to silicon through direct carbon linkage.
7. In the method of grouping glass fibers into a yarn, the step of treating such fibers with a solution of a hydrolyzable organomonosilane having the general formula RSiCla in an organic solvent therefor where R, is an alkyl radical having from 10 to 31 carbon atoms.
JAMES FRANKLIN HYDE.
REFERENCES CITED The following references are of record in the Great Britain Feb. 25, 1942 Certificate of Correction Patent No. 2,531,571 November 28, 1950 JAMES FRANKLIN HYDE It is hereby certified that error appears in the printed specification of the above numbered patent requiring correctlon as follows:
Column 3, line 63, for the words employed by read employed but; column 4, line 60, for mole read moZ and that the said Letters Patent should be read as corrected above, so that the same may conform to the record of the case in the Patent Oflice.
Signed and sealed this 13th day of March, A. D. 1951.
THOMAS F. MURPHY,
Assistant Oommz'ssz'oner of Patents.

Claims (1)

  1. 6. IN THE METHOD OF GROUPING GLASS FIBERS INTO A YARN, THE STEP OF TRETING SUCH FIBERS WITH A SOLUTION OF A HYDROLYZABLE ORGANOMONOSILANE IN AN ORGANIC SOLVENT THEREFOR, THE ORGANIC SUBSTITUENTS OF THE SILANE BEING ALKYL RADICALS ATTACHED TO SILICON THROUGH DIRECT CARBON LINKAGE.
US589688A 1945-04-21 1945-04-21 Manufacture of glass yarn Expired - Lifetime US2531571A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US589688A US2531571A (en) 1945-04-21 1945-04-21 Manufacture of glass yarn

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US589688A US2531571A (en) 1945-04-21 1945-04-21 Manufacture of glass yarn

Publications (1)

Publication Number Publication Date
US2531571A true US2531571A (en) 1950-11-28

Family

ID=24359066

Family Applications (1)

Application Number Title Priority Date Filing Date
US589688A Expired - Lifetime US2531571A (en) 1945-04-21 1945-04-21 Manufacture of glass yarn

Country Status (1)

Country Link
US (1) US2531571A (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2710275A (en) * 1951-05-01 1955-06-07 Owens Corning Fiberglass Corp Method of bulking glass fiber strands
US2723211A (en) * 1953-04-13 1955-11-08 Cowles Chem Co Stable silane triol composition and method of treating glass therewith
US2769740A (en) * 1953-11-09 1956-11-06 Richard A Gordon Nylon trimming with a securing member thereon impregnated with a polyvinyl resin coupled to an acid radical
US2772518A (en) * 1952-11-10 1956-12-04 Owens Corning Fiberglass Corp Method of coating glass filaments with metal
US2778764A (en) * 1951-09-13 1957-01-22 Owens Corning Fiberglass Corp Method of sizing glass fibers to form strands
US2793130A (en) * 1953-07-29 1957-05-21 Owens Corning Fiberglass Corp Pressure molded cement products and methods for producing same
US2897774A (en) * 1958-02-04 1959-08-04 Distributor S Group Inc Method and article for lubricating sewing machines and the like
US3002874A (en) * 1955-02-01 1961-10-03 Dunlop Tire & Rubber Corp Apparatus for the manufacture of pneumatic tyres
US3032813A (en) * 1957-07-09 1962-05-08 Owens Corning Fiberglass Corp Apparatus for forming and processing continuous filaments
US3262810A (en) * 1962-07-20 1966-07-26 Dow Corning Glass cloth
US4233809A (en) * 1978-12-20 1980-11-18 Ppg Industries, Inc. Size composition for glass fibers
US4780369A (en) * 1974-11-14 1988-10-25 Jenaer Glaswerk, Schott & Gen. Porous glass membrane tubes
US5209976A (en) * 1988-07-04 1993-05-11 Matsushita Electric Industrial Co., Ltd. Structure having a surface covered with a monomolecular film
US5571622A (en) * 1991-07-26 1996-11-05 Matsushita Electric Industrial Co., Ltd. Water- and oil repellent substrate and method of treatment
US5587241A (en) * 1995-06-01 1996-12-24 Vaughan; Gerald L. Mineral fibers and whiskers exhibiting reduced mammalian cell toxicity, and method for their preparation
US5629088A (en) * 1991-07-23 1997-05-13 Matsushita Electric Industrial Co., Ltd. Hydrophilic substrate and method of manufacturing the same

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2133238A (en) * 1937-06-22 1938-10-11 Owens Illinois Glass Co Glass fabric
US2234986A (en) * 1936-10-13 1941-03-18 Owens Corning Fiberglass Corp Mechanically drawing fibers
US2245824A (en) * 1940-08-03 1941-06-17 Eraser Company Inc Method of manufacturing glass rope
US2258218A (en) * 1939-08-01 1941-10-07 Gen Electric Methyl silicones and related products
US2272588A (en) * 1937-07-31 1942-02-10 Owens Corning Fiberglass Corp Coating for fibrous glass strands
GB543434A (en) * 1939-09-16 1942-02-25 British Thomson Houston Co Ltd Improvements in spun glass products
US2306222A (en) * 1940-11-16 1942-12-22 Gen Electric Method of rendering materials water repellent
US2380996A (en) * 1941-09-26 1945-08-07 Gen Electric Preparation of organosilicon halides
US2380995A (en) * 1941-09-26 1945-08-07 Gen Electric Preparation of organosilicon halides
US2439689A (en) * 1948-04-13 Method of rendering glass

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2439689A (en) * 1948-04-13 Method of rendering glass
US2234986A (en) * 1936-10-13 1941-03-18 Owens Corning Fiberglass Corp Mechanically drawing fibers
US2133238A (en) * 1937-06-22 1938-10-11 Owens Illinois Glass Co Glass fabric
US2272588A (en) * 1937-07-31 1942-02-10 Owens Corning Fiberglass Corp Coating for fibrous glass strands
US2258218A (en) * 1939-08-01 1941-10-07 Gen Electric Methyl silicones and related products
GB543434A (en) * 1939-09-16 1942-02-25 British Thomson Houston Co Ltd Improvements in spun glass products
US2245824A (en) * 1940-08-03 1941-06-17 Eraser Company Inc Method of manufacturing glass rope
US2306222A (en) * 1940-11-16 1942-12-22 Gen Electric Method of rendering materials water repellent
US2380996A (en) * 1941-09-26 1945-08-07 Gen Electric Preparation of organosilicon halides
US2380995A (en) * 1941-09-26 1945-08-07 Gen Electric Preparation of organosilicon halides

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2710275A (en) * 1951-05-01 1955-06-07 Owens Corning Fiberglass Corp Method of bulking glass fiber strands
US2778764A (en) * 1951-09-13 1957-01-22 Owens Corning Fiberglass Corp Method of sizing glass fibers to form strands
US2772518A (en) * 1952-11-10 1956-12-04 Owens Corning Fiberglass Corp Method of coating glass filaments with metal
US2723211A (en) * 1953-04-13 1955-11-08 Cowles Chem Co Stable silane triol composition and method of treating glass therewith
US2793130A (en) * 1953-07-29 1957-05-21 Owens Corning Fiberglass Corp Pressure molded cement products and methods for producing same
US2769740A (en) * 1953-11-09 1956-11-06 Richard A Gordon Nylon trimming with a securing member thereon impregnated with a polyvinyl resin coupled to an acid radical
US3002874A (en) * 1955-02-01 1961-10-03 Dunlop Tire & Rubber Corp Apparatus for the manufacture of pneumatic tyres
US3032813A (en) * 1957-07-09 1962-05-08 Owens Corning Fiberglass Corp Apparatus for forming and processing continuous filaments
US2897774A (en) * 1958-02-04 1959-08-04 Distributor S Group Inc Method and article for lubricating sewing machines and the like
US3262810A (en) * 1962-07-20 1966-07-26 Dow Corning Glass cloth
US4780369A (en) * 1974-11-14 1988-10-25 Jenaer Glaswerk, Schott & Gen. Porous glass membrane tubes
US4233809A (en) * 1978-12-20 1980-11-18 Ppg Industries, Inc. Size composition for glass fibers
US5209976A (en) * 1988-07-04 1993-05-11 Matsushita Electric Industrial Co., Ltd. Structure having a surface covered with a monomolecular film
US5445886A (en) * 1988-07-04 1995-08-29 Matsushita Electric Industrial Co., Ltd. Structure having a surface covered with a monomolecular film
US5629088A (en) * 1991-07-23 1997-05-13 Matsushita Electric Industrial Co., Ltd. Hydrophilic substrate and method of manufacturing the same
US5716704A (en) * 1991-07-23 1998-02-10 Matsushita Electric Industrial Co., Ltd. Hydrophylic substrate and method of manufacturing the same
US5571622A (en) * 1991-07-26 1996-11-05 Matsushita Electric Industrial Co., Ltd. Water- and oil repellent substrate and method of treatment
US5804252A (en) * 1991-07-26 1998-09-08 Matsushita Electric Industrial Co., Ltd. Water- and oil repellent substrate and method of treatment
US5587241A (en) * 1995-06-01 1996-12-24 Vaughan; Gerald L. Mineral fibers and whiskers exhibiting reduced mammalian cell toxicity, and method for their preparation

Similar Documents

Publication Publication Date Title
US2390370A (en) Manufacture of glass yarn
US2531571A (en) Manufacture of glass yarn
US2272588A (en) Coating for fibrous glass strands
US2392805A (en) Glass fiber strand
US2224149A (en) Apparatus for coating strands
US2772518A (en) Method of coating glass filaments with metal
US2323684A (en) Coated glass fiber strand
US3664855A (en) Size for fibers and glass fibers coated therewith
US2780909A (en) Method of forming yarns from staple glass fibers
CA1237411A (en) Apparatus and method for packaging a plurality of filaments or bundles of filaments and said packages
US3265516A (en) Glass fiber sizing composition
GB824223A (en) Method and apparatus for handling continuous strands and the like
US2778764A (en) Method of sizing glass fibers to form strands
US2845364A (en) Process for burning size from glass fabric and coating the resulting fabric
US2712509A (en) Glass fiber filament strand and method of manufacturing glass fabric
US2741009A (en) Method of and apparatus for the high speed packaging of filamentary or strand-like materials
US3143405A (en) Method of producing polyamide coated glass fibers
US2395157A (en) Coated strand material
US4027071A (en) Forming size for glass fibers
US2980956A (en) Metal applicators for glass filaments
US3547361A (en) Apparatus for winding textile material
US5700574A (en) Sizing composition for glass roving
US2411326A (en) Making reinforced slivers
CN113699630A (en) Processing technology of flower-type special blended yarn
GB877492A (en) Improvements in or relating to strand products