WO2000058410A1 - Verfahren zur herstellung von selbstreinigenden, ablösbaren oberflächen - Google Patents
Verfahren zur herstellung von selbstreinigenden, ablösbaren oberflächen Download PDFInfo
- Publication number
- WO2000058410A1 WO2000058410A1 PCT/EP2000/002424 EP0002424W WO0058410A1 WO 2000058410 A1 WO2000058410 A1 WO 2000058410A1 EP 0002424 W EP0002424 W EP 0002424W WO 0058410 A1 WO0058410 A1 WO 0058410A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- elevations
- hydrophobic material
- self
- range
- hydrophobic
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B17/00—Methods preventing fouling
- B08B17/02—Preventing deposition of fouling or of dust
- B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B17/00—Methods preventing fouling
- B08B17/02—Preventing deposition of fouling or of dust
- B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
- B08B17/065—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement the surface having a microscopic surface pattern to achieve the same effect as a lotus flower
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/056—Forming hydrophilic coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
- C08J7/065—Low-molecular-weight organic substances, e.g. absorption of additives in the surface of the article
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/008—Temporary coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/32—Processes for applying liquids or other fluent materials using means for protecting parts of a surface not to be coated, e.g. using stencils, resists
- B05D1/322—Removable films used as masks
- B05D1/327—Masking layer made of washable film
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
Definitions
- the present invention relates to a method for producing self-cleaning surfaces.
- the CH-PS-26 82 58 describes water-repellent surfaces that have a contact angle with water over 120 °. They are obtained by applying powders such as kaolin, talc, clay or silica gel on a base, the powder being previously hydrophobized by organic silicon compounds. It is applied together with curable resins or from solutions with organic solvents. Permanently hydrophobic surfaces cannot be produced in this way. There is also no indication of the particle size or particle size distribution of the powder. The properties of the surfaces thus obtained are compared with those of the leaves of the nasturtium. In this comparison is It should be noted that it was neither known nor technically analyzable what the properties of the leaf surface of nasturtium are based on. Studies now carried out have shown that the nasturtium has an extremely fine ultrastructure with structural elements smaller than 2 ⁇ m.
- US Pat. No. 3,354,022 describes a water-repellent surface with elevations and depressions and an air content of at least 60%, in which a surface contact angle of more than 90 ° is established.
- DE-PS-10 23 217 describes a mold for producing moldings with a rough surface.
- the mold is intended for the production of molded parts made of rubber or plastic with a rough surface.
- the walls of the mold are covered with coarse corundum powder and a stove-enamel.
- the molds produce products with occasional depressions and therefore improved adhesive properties. Even the usual vulcanization skin is avoided.
- the surfaces obtained in this way can be easily labeled, for example. The products are therefore certainly not self-cleaning with moving water.
- JP-A-62-191447 describes a method to increase the water repellency of a surface. For this purpose, a plasma polymer film is applied, this is roughened by etching and a second plasma polymer film is applied.
- JP-A-3-174279 (abstract) describes a method for producing matt, decorative surfaces on sheets or foils. They are produced by lacquers which are hardened by means of ionizing radiation and in which patterns which are not specified in any unspecified manner be imprinted. They are then fully cured by further radiation.
- the object of the present invention was to develop a process for the production of self-cleaning surfaces, which can be removed with detergent solutions.
- the object is achieved by a method having the features of patent claim 1.
- the method according to the invention for producing self-cleaning surfaces which have elevations and depressions, the distance between the elevations being in the range from 0.1 to 200 ⁇ m and the height of the elevations in the range from 0.1 to 100 ⁇ m, is based on the application a hydrophobic material, which forms a self-cleaning surface when the solvent evaporates, on a surface and subsequent drying, the applied material being detachable with aqueous detergent solutions.
- the hydro phobe material can be in the form of a solution, dispersion or emulsion.
- “Detachable with detergents” means that the applied material is detached by the action of aqueous detergent solutions - at least in the case of long-term action - by dissolving at least parts of the applied material. Such materials applied according to the invention can also be removed mechanically, for example by brushing, scratching or high pressure cleaning with water.
- the hydrophobic material is a wax that forms a micro-structured, self-cleaning, self-cleaning surface.
- the solution, dispersion or emulsion contains solid particles. These can themselves be hydrophobic or hydrophilic when used together with hydrophobic materials such as waxes.
- the hydrophobic material can be applied by spraying, for example using a spray can or a spray gun. Depending on the type of planned application, it may be advantageous for the hydrophobic material to be additionally oleophobic.
- Self-cleaning surfaces of objects that are translucent and that should retain this translucency for a long time for optical, aesthetic or technical reasons are of particular technical importance.
- these are translucent glazing of buildings, vehicles, solar panels, etc.
- the detachability of the hydrophobic material is particularly advantageous if the self-cleaning properties are only required temporarily, for example during storage or transport, but otherwise - for example for aesthetic reasons - are undesirable.
- Optimal results are achieved when the elevations of the surface structures are close enough together to prevent the depressions or depressions between the elevations from being touched by water drops. If the elevations of the surface structures are too close together or if the depressions are not deep enough, they will again act like a closed surface and can therefore be wetted better. The aim should therefore be that with increasing distance of the surveys, the height of the surveys from the underground should also increase. The previous measurements have shown that good results are achieved within the claimed limits for the distance and the height of the surveys. Surfaces with elevations that have 0.1 to 50 ⁇ m and in which the distance between the elevations is 0.1 to 100 ⁇ m provide optimal results.
- Hentriacontan-14,16-dione as a 0.1% solution in hexane or ethyl acetate is sprayed onto any surface using a spray can or a spray gun.
- the hentriacontane-14,16-dione self-organizes crystals in the form of small tubes, the majority of which have a diameter of 0.2 ⁇ m and a length of 0.5-5 ⁇ m.
- This coating makes a wettable surface hydrophobic and the contact angle increases up to 160 °. Contaminating particles are washed off from such surfaces by moving water, the coating itself also being removed in the long term.
- a hydrophilic e.g. quartz powder
- hydrophobic powder e.g. Teflon
- gypsum is mixed in a ratio of 1:10: 2 (percent by weight) with water and a siliconate (Wacker BS 15) and then applied with a brush or roller. When drying out forms there is a micro-rough surface, the structure of which is determined by the needle-shaped crystals of the plaster. After the water has evaporated, these are covered by a layer of the hydrophobicizing agent. The contact angles on such a surface are over 150 °.
- gypsum is mixed in a ratio of 1:10: 0.5 (percent by weight) with water and a silicone (Wacker Silkon WI) and then applied with a spray gun. When drying out, a micro-rough surface forms, the structure of which is determined by the needle-shaped crystals of the plaster. After the water has evaporated, these are covered by a layer of the hydrophobicizing agent. The contact angles on such a surface are over 150 °.
- a water vapor permeable polymer e.g. polyurethane
- a wax-like substance e.g. hentriacontane-14,16-dione
- the wax is transported and forms the desired microstructures on the surface.
- this system can also achieve a certain sustainability in that damaged or eroded structures can be reproduced for a certain time.
Abstract
Description
Claims
Priority Applications (16)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT00920513T ATE245681T1 (de) | 1999-03-25 | 2000-03-18 | Verfahren zur herstellung von selbstreinigenden, ablösbaren oberflächen |
KR1020017012117A KR20020000792A (ko) | 1999-03-25 | 2000-03-18 | 제거될 수 있는 자정 표면을 제조하는 방법 |
DE50003003T DE50003003D1 (de) | 1999-03-25 | 2000-03-18 | Verfahren zur herstellung von selbstreinigenden, ablösbaren oberflächen |
JP2000608696A JP2002540283A (ja) | 1999-03-25 | 2000-03-18 | 自己洗浄力のある除去可能な表面の製造方法 |
SK1340-2001A SK285771B6 (sk) | 1999-03-25 | 2000-03-18 | Spôsob výroby samočistiacich odstrániteľných povrchov, predmet s takým povrchom a použitie sekundárnych alkoholov |
DK00920513T DK1171529T3 (da) | 1999-03-25 | 2000-03-18 | Fremgangsmåde til fremstilling af selvrensende, aftagelige overflader |
EP00920513A EP1171529B1 (de) | 1999-03-25 | 2000-03-18 | Verfahren zur herstellung von selbstreinigenden, ablösbaren oberflächen |
AU41063/00A AU765310B2 (en) | 1999-03-25 | 2000-03-18 | Method of producing self-cleaning detachable surfaces |
PL350945A PL191143B1 (pl) | 1999-03-25 | 2000-03-18 | Sposób wytwarzania samoczyszczących powierzchni |
CA002368204A CA2368204C (en) | 1999-03-25 | 2000-03-18 | Method of producing self-cleaning detachable surfaces |
EEP200100494A EE200100494A (et) | 1999-03-25 | 2000-03-18 | Meetod isepuhastuvate eemaldatavate pindade valmistamiseks |
BG105920A BG105920A (en) | 1999-03-25 | 2001-09-19 | Method for producing self-cleaning detachable surfaces |
HR20010699A HRP20010699A2 (en) | 1999-03-25 | 2001-09-24 | Method of producing self-cleaning detachable surfaces |
NO20014618A NO20014618L (no) | 1999-03-25 | 2001-09-24 | Fremgangsmåte for fremstilling av selvrensende avlösbare overflater |
US11/047,741 US20050136217A1 (en) | 1999-03-25 | 2005-02-02 | Method for the preparation of self-cleaning removable surfaces |
US11/584,756 US20070098957A1 (en) | 1999-03-25 | 2006-10-23 | Method for the preparation of self-cleaning removable surfaces |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19913602 | 1999-03-25 | ||
DE19913602.5 | 1999-03-25 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/047,741 Continuation US20050136217A1 (en) | 1999-03-25 | 2005-02-02 | Method for the preparation of self-cleaning removable surfaces |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000058410A1 true WO2000058410A1 (de) | 2000-10-05 |
Family
ID=7902402
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2000/002424 WO2000058410A1 (de) | 1999-03-25 | 2000-03-18 | Verfahren zur herstellung von selbstreinigenden, ablösbaren oberflächen |
Country Status (24)
Country | Link |
---|---|
US (2) | US20050136217A1 (de) |
EP (1) | EP1171529B1 (de) |
JP (1) | JP2002540283A (de) |
KR (1) | KR20020000792A (de) |
CN (1) | CN1344297A (de) |
AT (1) | ATE245681T1 (de) |
AU (1) | AU765310B2 (de) |
BG (1) | BG105920A (de) |
CA (1) | CA2368204C (de) |
CZ (1) | CZ20013361A3 (de) |
DE (1) | DE50003003D1 (de) |
DK (1) | DK1171529T3 (de) |
EE (1) | EE200100494A (de) |
ES (1) | ES2203450T3 (de) |
HR (1) | HRP20010699A2 (de) |
HU (1) | HUP0200452A2 (de) |
NO (1) | NO20014618L (de) |
PL (1) | PL191143B1 (de) |
PT (1) | PT1171529E (de) |
RU (1) | RU2246514C2 (de) |
SK (1) | SK285771B6 (de) |
WO (1) | WO2000058410A1 (de) |
YU (1) | YU67701A (de) |
ZA (1) | ZA200107800B (de) |
Cited By (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002064510A1 (de) * | 2001-02-10 | 2002-08-22 | Aloys Wobben | Vorrichtung zum entsalzen von wasser mit der umkehrosmose |
DE10124076C1 (de) * | 2001-05-14 | 2002-10-10 | Fraunhofer Ges Forschung | Verfahren zur Herstellung von hydrophoben bis hydrophilen Oberflächen |
EP1249476A2 (de) * | 2001-04-10 | 2002-10-16 | Stiftung Alfred-Wegener-Institut für Polar- und Meeresforschung | Biozidfreie Antifouling-Beschichtung |
EP1249468A2 (de) * | 2001-04-12 | 2002-10-16 | Creavis Gesellschaft für Technologie und Innovation mbH | Selbstreinigende Oberflächen durch hydrophobe Strukturen und Verfahren zu deren Herstellung |
WO2002084016A1 (de) * | 2001-04-12 | 2002-10-24 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Textile flächengebilde mit selbstreinigender und wasserabweisender oberfläche |
WO2002084013A2 (de) * | 2001-04-12 | 2002-10-24 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Polymerfaser mit selbstreinigender und wasserabweisender oberfläche |
EP1318228A1 (de) * | 2001-12-05 | 2003-06-11 | Creavis Gesellschaft für Technologie und Innovation mbH | Verfahren zur Herstellung von Gegenständen mit antiallergischen Oberflächen |
WO2003051544A1 (de) * | 2001-12-19 | 2003-06-26 | Degussa Ag | Oberflächenstrukturierte einbauten für mehrphasentrennapparate |
WO2003066241A1 (de) * | 2002-02-07 | 2003-08-14 | Degussa Ag | Verfahren zur herstellung von schutzschichten mit schmutz- und wasserabweisenden eigenschaften |
US6811856B2 (en) | 2001-04-12 | 2004-11-02 | Creavis Gesellschaft Fuer Technologie Und Innovation Mbh | Properties of structure-formers for self-cleaning surfaces, and the production of the same |
US6858284B2 (en) | 2001-04-12 | 2005-02-22 | Creavis Gesellschaft Fuer Technologie Und Innovation Mbh | Surfaces rendered self-cleaning by hydrophobic structures, and process for their production |
WO2005090490A2 (en) * | 2004-03-17 | 2005-09-29 | The Lubrizol Corporation | Method to use an emulsified material as a coating |
US7083828B2 (en) | 2003-04-24 | 2006-08-01 | Goldschmidt Gmbh | Process for producing detachable dirt- and water-repellent surface coatings |
US7211313B2 (en) | 2001-07-16 | 2007-05-01 | Degussa Ag | Surfaces rendered self-cleaning by hydrophobic structures and a process for their production |
WO2007130228A1 (en) * | 2006-04-03 | 2007-11-15 | General Electric Company | Articles having low wettability and high light transmission |
DE102006050365A1 (de) * | 2006-10-25 | 2008-04-30 | MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. | Strukturierte Oberfläche mit schaltbarer Haftfähigkeit |
WO2008071202A1 (en) * | 2006-12-11 | 2008-06-19 | Sca Hygiene Products Ab | Absorbent article with a strongly hydrophobic layer |
US7650848B2 (en) * | 2004-02-17 | 2010-01-26 | University Of Florida Research Foundation, Inc. | Surface topographies for non-toxic bioadhesion control |
DE102009013315A1 (de) | 2009-03-18 | 2010-09-23 | Sasol Germany Gmbh | Beschichtungen unter Einsatz von Dialkyl-/Dialkenylethern als Hydrophobierungsmittel, deren Verwendung und Metalle versehen mit der Beschichtung |
DE102009051598A1 (de) | 2009-11-02 | 2011-07-07 | Vereinigung zur Förderung des Instituts für Kunststoffverarbeitung in Industrie und Handwerk an der Rhein.-Westf. Technischen Hochschule Aachen e.V., 52062 | Verfahren zur Herstellung von Mikrostrukturen auf Kunststoffformteilen mittels Verstreckung zum Zwecke der Selbstreinigung |
US8034173B2 (en) | 2003-12-18 | 2011-10-11 | Evonik Degussa Gmbh | Processing compositions and method of forming the same |
AT504995B1 (de) * | 2007-03-02 | 2011-12-15 | Fabian Ferdinand Dipl Ing Dr | Vorrichtung zur aufbereitung von wasser |
DE102010024559A1 (de) | 2010-06-22 | 2011-12-22 | Süd-Chemie AG | Verfahren zur Herstellung hydrophober Oberflächen |
US8129195B2 (en) | 2007-07-03 | 2012-03-06 | Roche Diagnostics Operations, Inc. | Method for the production of an analytical element |
US8147607B2 (en) | 2009-10-26 | 2012-04-03 | Ashland Licensing And Intellectual Property Llc | Hydrophobic self-cleaning coating compositions |
US8258206B2 (en) | 2006-01-30 | 2012-09-04 | Ashland Licensing And Intellectual Property, Llc | Hydrophobic coating compositions for drag reduction |
US8338351B2 (en) | 2006-01-30 | 2012-12-25 | Ashland Licensing And Intellectual Property, Llc | Coating compositions for producing transparent super-hydrophobic surfaces |
WO2014097309A1 (en) | 2012-12-17 | 2014-06-26 | Asian Paints Ltd. | Stimuli responsive self cleaning coating |
US8828333B2 (en) | 2007-07-03 | 2014-09-09 | Roche Diagnotics Operations, Inc. | Method for the production of a microfluidic system on a polymer surface |
US9016221B2 (en) | 2004-02-17 | 2015-04-28 | University Of Florida Research Foundation, Inc. | Surface topographies for non-toxic bioadhesion control |
US9675994B2 (en) | 2011-06-01 | 2017-06-13 | The University Of North Carolina At Chapel Hill | Superhydrophobic coatings and methods for their preparation |
US9937655B2 (en) | 2011-06-15 | 2018-04-10 | University Of Florida Research Foundation, Inc. | Method of manufacturing catheter for antimicrobial control |
US10150245B2 (en) | 2008-11-11 | 2018-12-11 | University Of Florida Research Foundation, Inc. | Method of patterning a surface and articles comprising the same |
DE102017008415A1 (de) | 2017-08-19 | 2019-02-21 | Hescoat GmbH | Antihaftbeschichtung |
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---|---|---|---|---|
DE10160055A1 (de) * | 2001-12-06 | 2003-06-18 | Degussa | Diffus reflektierende Oberflächen zu deren Herstellung |
DE10160054A1 (de) * | 2001-12-06 | 2003-06-18 | Degussa | Lichtstreuende Werkstoffe die selbstreinigende Oberflächen aufweisen |
DE10356752A1 (de) | 2003-12-04 | 2005-06-30 | Roche Diagnostics Gmbh | Beschichtete Testelemente |
US8974590B2 (en) | 2003-12-18 | 2015-03-10 | The Armor All/Stp Products Company | Treatments and kits for creating renewable surface protective coatings |
US7828889B2 (en) | 2003-12-18 | 2010-11-09 | The Clorox Company | Treatments and kits for creating transparent renewable surface protective coatings |
DE102004025368A1 (de) | 2004-05-19 | 2005-12-08 | Basf Ag | Verfahren zur Herstellung von strukturierten Oberflächen |
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AT504995B1 (de) * | 2007-03-02 | 2011-12-15 | Fabian Ferdinand Dipl Ing Dr | Vorrichtung zur aufbereitung von wasser |
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Also Published As
Publication number | Publication date |
---|---|
JP2002540283A (ja) | 2002-11-26 |
PT1171529E (pt) | 2003-12-31 |
SK13402001A3 (sk) | 2002-05-09 |
US20070098957A1 (en) | 2007-05-03 |
HUP0200452A2 (en) | 2002-11-28 |
EP1171529B1 (de) | 2003-07-23 |
KR20020000792A (ko) | 2002-01-05 |
HRP20010699A2 (en) | 2002-12-31 |
NO20014618L (no) | 2001-09-25 |
EE200100494A (et) | 2002-12-16 |
RU2246514C2 (ru) | 2005-02-20 |
YU67701A (sh) | 2003-08-29 |
DK1171529T3 (da) | 2003-11-03 |
SK285771B6 (sk) | 2007-08-02 |
ES2203450T3 (es) | 2004-04-16 |
DE50003003D1 (de) | 2003-08-28 |
US20050136217A1 (en) | 2005-06-23 |
ATE245681T1 (de) | 2003-08-15 |
CN1344297A (zh) | 2002-04-10 |
AU765310B2 (en) | 2003-09-18 |
BG105920A (en) | 2002-05-31 |
CA2368204A1 (en) | 2000-10-05 |
CZ20013361A3 (cs) | 2002-02-13 |
PL191143B1 (pl) | 2006-03-31 |
EP1171529A1 (de) | 2002-01-16 |
ZA200107800B (en) | 2002-05-29 |
PL350945A1 (en) | 2003-02-24 |
AU4106300A (en) | 2000-10-16 |
CA2368204C (en) | 2008-09-09 |
NO20014618D0 (no) | 2001-09-24 |
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