WO2001019932A3 - Agents for producing self-cleaning thin surface coatings and methods suited therefor - Google Patents

Agents for producing self-cleaning thin surface coatings and methods suited therefor Download PDF

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Publication number
WO2001019932A3
WO2001019932A3 PCT/EP2000/008825 EP0008825W WO0119932A3 WO 2001019932 A3 WO2001019932 A3 WO 2001019932A3 EP 0008825 W EP0008825 W EP 0008825W WO 0119932 A3 WO0119932 A3 WO 0119932A3
Authority
WO
WIPO (PCT)
Prior art keywords
coating agent
solution
surface coatings
agents
powder
Prior art date
Application number
PCT/EP2000/008825
Other languages
German (de)
French (fr)
Other versions
WO2001019932A2 (en
Inventor
Georg Gros
Original Assignee
Georg Gros
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Georg Gros filed Critical Georg Gros
Priority to AU74183/00A priority Critical patent/AU7418300A/en
Publication of WO2001019932A2 publication Critical patent/WO2001019932A2/en
Publication of WO2001019932A3 publication Critical patent/WO2001019932A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B05D5/083Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B17/00Methods preventing fouling
    • B08B17/02Preventing deposition of fouling or of dust
    • B08B17/06Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B17/00Methods preventing fouling
    • B08B17/02Preventing deposition of fouling or of dust
    • B08B17/06Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
    • B08B17/065Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement the surface having a microscopic surface pattern to achieve the same effect as a lotus flower
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/69Particle size larger than 1000 nm
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18Homopolymers or copolymers or tetrafluoroethene

Abstract

The invention relates to a method for producing self-cleaning surface coatings, whereby an inventive coating agent dispersion or solution is applied with a thin coat to the surface and is dried thereon. Said coating agent dispersion or solution is comprised of: a) a film-forming plastic provided in the form of an aqueous dispersion or of a solution in an organic solvent; b) a hydrophobic polymer provided in the form of a powder with an average grain size ranging from 10-50 νm, which is insoluble in the above-mentioned solvent; c) a sufficient quantity of water and/or of an organic solvent for producing a coating agent that is capable of being spread or sprayed; d) whereby the applied layer is so thin that the grains of the hydrophobic polymeric powder are interspaced by a distance of 5 to 100 νm, and e) whereby the quantity of the film-forming plastic is measured so that it forms a layer after the solvent evaporates whose thickness is equal to 30-60 % of the average grain size of the hydrophobic powder.
PCT/EP2000/008825 1999-09-15 2000-09-09 Agents for producing self-cleaning thin surface coatings and methods suited therefor WO2001019932A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU74183/00A AU7418300A (en) 1999-09-15 2000-09-09 Agents for producing self-cleaning thin surface coatings and methods suited therefor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19944169A DE19944169B4 (en) 1999-09-15 1999-09-15 Composition for the production of self-cleaning thin surface coatings and methods suitable for this purpose
DE19944169.3 1999-09-15

Publications (2)

Publication Number Publication Date
WO2001019932A2 WO2001019932A2 (en) 2001-03-22
WO2001019932A3 true WO2001019932A3 (en) 2001-09-27

Family

ID=7922083

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2000/008825 WO2001019932A2 (en) 1999-09-15 2000-09-09 Agents for producing self-cleaning thin surface coatings and methods suited therefor

Country Status (3)

Country Link
AU (1) AU7418300A (en)
DE (1) DE19944169B4 (en)
WO (1) WO2001019932A2 (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10134477A1 (en) 2001-07-16 2003-02-06 Creavis Tech & Innovation Gmbh Self-cleaning surfaces through hydrophobic structures and processes for their production
DE10205783A1 (en) * 2002-02-13 2003-08-21 Creavis Tech & Innovation Gmbh Molded articles with self-cleaning properties and process for producing such molded articles
DE10210666A1 (en) * 2002-03-12 2003-10-02 Creavis Tech & Innovation Gmbh Shaping process for the production of moldings with at least one surface which has self-cleaning properties, and moldings produced using this process
DE10210674A1 (en) * 2002-03-12 2003-10-02 Creavis Tech & Innovation Gmbh Surface extrudates with self-cleaning properties and process for producing such extrudates
GB0209235D0 (en) * 2002-04-23 2002-06-05 Chemco Internat Non-scratch flooring top coat
DE10226022A1 (en) * 2002-06-12 2003-12-24 Creavis Tech & Innovation Gmbh Process for the production of surfaces with anti-coagulation properties
DE10315128A1 (en) * 2003-04-03 2004-10-14 Creavis Gesellschaft Für Technologie Und Innovation Mbh Process for suppressing mold formation using hydrophobic substances and an anti-mold agent for parts of buildings
DE102004062739A1 (en) 2004-12-27 2006-07-06 Degussa Ag Self-cleaning surfaces with protrusions formed by hydrophobic particles, with improved mechanical strength
DE102007044159A1 (en) 2007-09-11 2009-03-12 Leibniz-Institut Für Polymerforschung Dresden E.V. Metal materials with hybrid-stabilized oxide layer, process for the preparation and their use
CN103232797B (en) * 2013-04-11 2017-02-08 三棵树涂料股份有限公司 Colorizing water-based woodware top coat and preparation method thereof
CN103254784B (en) * 2013-05-30 2015-04-29 淮安市造漆厂有限公司 Formula based on modified hydrophobic SiO2 (silicon dioxide) self-cleaning paint and preparation method thereof
US9637658B2 (en) * 2013-06-24 2017-05-02 The Boeing Company Coatings, coating compositions, and methods of delaying ice formation
DE102013218380A1 (en) 2013-09-13 2015-03-19 Evonik Degussa Gmbh Self-generating textured surfaces with self-cleaning properties and a process for producing these surfaces
CN103614044B (en) * 2013-11-21 2015-12-09 浙江大学 For the preparation method of glass insulator antifouling work self-cleaning coating
CN104804592B (en) * 2015-05-08 2018-07-20 青岛华仁技术孵化器有限公司 Lotus leaf paint and preparation method thereof
US11168276B2 (en) 2015-08-28 2021-11-09 Battelle Memorial Institute Reinforced composites with repellent and slippery properties
US10221321B2 (en) * 2015-08-28 2019-03-05 Battelle Memorial Institute Paintable hydrophobic and lubricant-infused surface coatings and processes for making and using same
CN105602367A (en) * 2015-12-31 2016-05-25 文登蓝岛建筑工程有限公司 Hydrophobic coating and preparation method thereof
WO2017127500A1 (en) 2016-01-20 2017-07-27 Battelle Memorial Institute Stretchable hydrophobic materials and methods for making the same
CN108298853B (en) * 2018-01-11 2021-01-12 东南大学 Modification method of polyvinyl alcohol fiber for strain hardening cement-based composite material
CN109437735A (en) * 2018-11-22 2019-03-08 福建工程学院 A kind of super-hydrophobic cement and its application method
CN114921163B (en) * 2021-07-20 2023-03-31 上海澳昌实业有限公司 Nano-silver antibacterial mildew-resistant waterborne polyurethane coating and preparation method thereof
CN114892414A (en) * 2022-01-14 2022-08-12 浙江辰鸿纺织品科技股份有限公司 Coating roller shutter fabric with surface easy to clean
CN115058197A (en) * 2022-05-27 2022-09-16 海南宏鑫达防水工程有限公司 Multipurpose coating and using method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4309328A (en) * 1979-11-28 1982-01-05 Ppg Industries, Inc. Stable aqueous dispersions of particles of vinylidene fluoride polymer
US5171622A (en) * 1989-12-01 1992-12-15 Glyco-Metall-Werke Daelen & Hofmann Kg Composite laminate for sliding elements having a running or sliding layer to which a conforming filler-containing layer is applied
JPH0753912A (en) * 1993-08-06 1995-02-28 Asahi Pen:Kk Water-base coating composition
WO1996004123A1 (en) * 1994-07-29 1996-02-15 Wilhelm Barthlott Self-cleaning surfaces of objects and process for producing same
EP0896164A1 (en) * 1996-04-25 1999-02-10 Koyo Seiko Co., Ltd. Rolling sliding part
US6090869A (en) * 1998-10-30 2000-07-18 Turbine Controls, Inc. Self-lubricating coating composition of epoxy resins, polytetrafluoroethylene, MoS2 and mica

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4309328A (en) * 1979-11-28 1982-01-05 Ppg Industries, Inc. Stable aqueous dispersions of particles of vinylidene fluoride polymer
US5171622A (en) * 1989-12-01 1992-12-15 Glyco-Metall-Werke Daelen & Hofmann Kg Composite laminate for sliding elements having a running or sliding layer to which a conforming filler-containing layer is applied
JPH0753912A (en) * 1993-08-06 1995-02-28 Asahi Pen:Kk Water-base coating composition
WO1996004123A1 (en) * 1994-07-29 1996-02-15 Wilhelm Barthlott Self-cleaning surfaces of objects and process for producing same
EP0896164A1 (en) * 1996-04-25 1999-02-10 Koyo Seiko Co., Ltd. Rolling sliding part
US6090869A (en) * 1998-10-30 2000-07-18 Turbine Controls, Inc. Self-lubricating coating composition of epoxy resins, polytetrafluoroethylene, MoS2 and mica

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 1995, no. 05 30 June 1995 (1995-06-30) *

Also Published As

Publication number Publication date
DE19944169B4 (en) 2006-02-16
WO2001019932A2 (en) 2001-03-22
AU7418300A (en) 2001-04-17
DE19944169A1 (en) 2001-03-29

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