WO2008077118B1 - An ultra-high solid content polyurethane dispersion and a continuous process for producing ultra-high solid content polyurethane dispersions - Google Patents

An ultra-high solid content polyurethane dispersion and a continuous process for producing ultra-high solid content polyurethane dispersions

Info

Publication number
WO2008077118B1
WO2008077118B1 PCT/US2007/088194 US2007088194W WO2008077118B1 WO 2008077118 B1 WO2008077118 B1 WO 2008077118B1 US 2007088194 W US2007088194 W US 2007088194W WO 2008077118 B1 WO2008077118 B1 WO 2008077118B1
Authority
WO
WIPO (PCT)
Prior art keywords
solid content
stream
ultra
high solid
polyurethane dispersion
Prior art date
Application number
PCT/US2007/088194
Other languages
French (fr)
Other versions
WO2008077118A3 (en
WO2008077118A2 (en
Inventor
Bedri Erdem
Debkumar Bhattacharjee
Original Assignee
Dow Global Technologies Inc
Bedri Erdem
Debkumar Bhattacharjee
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc, Bedri Erdem, Debkumar Bhattacharjee filed Critical Dow Global Technologies Inc
Priority to AT07865887T priority Critical patent/ATE517933T1/en
Priority to MX2009006624A priority patent/MX2009006624A/en
Priority to US12/519,831 priority patent/US8821983B2/en
Priority to EP07865887A priority patent/EP2094756B1/en
Priority to CA002672604A priority patent/CA2672604A1/en
Priority to CN2007800513918A priority patent/CN101605831B/en
Priority to BRPI0719419A priority patent/BRPI0719419B8/en
Priority to JP2009543194A priority patent/JP2010513701A/en
Publication of WO2008077118A2 publication Critical patent/WO2008077118A2/en
Publication of WO2008077118A3 publication Critical patent/WO2008077118A3/en
Publication of WO2008077118B1 publication Critical patent/WO2008077118B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/302—Water
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4269—Lactones
    • C08G18/4277—Caprolactone and/or substituted caprolactone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4808—Mixtures of two or more polyetherdiols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2190/00—Compositions for sealing or packing joints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2270/00—Compositions for creating interpenetrating networks

Abstract

The instant invention is an ultra-high solid content polyurethane dispersion, and a continuous process for producing ultra-high solid content polyurethane dispersions. The ultra-high solid content polyurethane dispersion includes the reaction product of: (1) a first component, wherein the first component is a first polyurethane prepolymer or a first polyurethane prepolymer emulsion; (2) a second component, wherein the second component is a second polyurethane prepolymer, a second polyurethane prepolymer emulsion, a low solid content polyurethane dispersion, a seed latex, or combinations thereof; (3) and a chain extender. The ultra-high solid content polyurethane dispersion has a solid content of at least 60 percent by weight of the solid, based on the total weight of the ultra-high solid content polyurethane dispersion, and a viscosity in the range of less than 5000 cps at 20 rpm at 21° C using spindle #4 with Brookfield viscometer. The method for producing a high-solid content polyurethane dispersion includes the following steps: (1) providing a first stream, wherein said first stream comprising a first polyurethane prepolymer or a first polyurethane prepolymer emulsion; (2) providing a second stream, wherein said second stream being a media phase selected from the group consisting of a second polyurethane prepolymer, a second polyurethane prepolymer emulsion, a polyurethane prepolymer dispersion, a seed latex emulsion, or combinations thereof; (3) continuously merging said first stream with said second stream in the presence of a chain extender; and (4) thereby forming a polyurethane dispersion having a solid content of at least 60 percent by weight of the solid, based on the total weight of the ultra-high solid content polyurethane dispersion, and a viscosity in the range of less than 5000 cps at 20 rpm at 21° C using spindle #4 with Brookfield viscometer.

Claims

AMENDED CLAIMS received by the International Bureau on 20 October 2008 (20.10.2008)WE CLAIM:
1. A continuous process for producing an ultra-high solid content polyurethane dispersion comprising the steps of: providing a first stream, wherein said first stream comprises a first polyurethane prepolymer or a first polyurethane prepolymer emulsion; providing a second stream, wherein said second stream is a media phase selected from the group consisting of a second polyurethane prepolymer, a second polyurethane prepolymer emulsion, a low solid content polyurethane dispersion, a seed latex, and combinations thereof ; continuously merging said first stream with said second stream in the presence of a chain extender; thereby forming said ultra-high solid content polyurethane dispersion, wherein said ultra-high solid content polyurethane dispersion having at least a solid content of at least 60 percent by weight of said solid, based on the total weight of said ultra-high solid content polyurethane dispersion, and a viscosity of less than 5000 cps at 20 rpm at 21° C using spindle #4 with Brookfield viscometer.
2. The continuous process for producing an ultra-high solid content polyurethane dispersion according to Claim 1, wherein said first stream comprises first polymer resins and said second stream comprises second polymer resins, and wherein said first polymer resin and said second polymer resin have a volume average particle size ratio in the range of 1 :5 to 1 :2.
3. The continuous process for producing an ultra-high solid content polyurethane dispersion according to Claim 2, wherein said first polymer resin and said second polymer resin have a volume average particle size ratio in the range of about 1 :3.
4. The continuous process for producing an ultra-high solid content polyurethane dispersion according to Claim 1, wherein said first stream comprises first polymer resins and said second stream comprises second polymer resins, and wherein
42 said ultra-high solid content polyurethane dispersion comprises 20 to 40 percent by weight of said first polymer resins having a particle size in the range of 0.04 micron to 5.0 micron, and 60 to 80 percent by weight of said second polymer resins having a particle size in the range of 0.05 micron to 5.0 micron, based on the total weight of said first polymer resin and said second polymer resin.
5. The continuous process for producing an ultra-high solid content polyurethane dispersion according to Claim 1, wherein said seed latex is selected from the group consisting of a dispersion, emulsion, and latex of olefins, epoxies, silicon, styrene, acrylate, butadiene, isoprene, vinyl acetate, copolymers thereof, and blends thereof.
6. The continuous process for producing an ultra-high solid content polyurethane dispersion according to Claim 1, wherein said seed latex is an oil phase emulsified in water.
7. A continuous process for producing an ultra-high solid content polyurethane dispersion comprising the steps of: providing a first stream, wherein said first stream is a first polyurethane prepolymer stream; providing a second stream, wherein said second stream is a media phase; continuously merging said first and said second stream together in the presence of a surfactant at a temperature in the range of 100C to 7O0C, wherein the ratio of said second stream to first stream being in the range of 0.1 to 0.6, and wherein said surfactant being present in a concentration range of 0.1 to 3.0 percent, based on the total weight of said first stream, said second stream, and said surfactant; thereby forming said ultra-high solid content polyurethane dispersion, wherein said ultra-high solid content polyurethane dispersion having at least a solid content of at least 60 percent by weight of said solid, based on the total weight of said ultra-high solid content polyurethane dispersion, and a viscosity of less than 5000 cps at 20 rpm at 21° C using spindle #4 with Brookfield viscometer.
43
8. An ultra high solid content polyurethane dispersion prepared according to the continuous process of either Claim 1 or Claim 7.
9. The ultra-high solid content polyurethane dispersion according to Claim 8, wherein said ultra high solid content polyurethane dispersion further comprises an inorganic filler.
10. The continuous process for producing an ultra-high solid content polyurethane dispersion according to either Claim 1 or Claim 7, wherein said first or second polyurethane prepolymer is a reaction product of at least one polyisocyanate and at least one polyol.
11. The continuous process for producing an ultra-high solid content polyurethane dispersion according to Claim 10, wherein said polyisocyanate is aromatic or aliphatic.
12. The continuous process for producing an ultra-high solid content polyurethane dispersion according to Claim 11, wherein said polyol is selected from the group consisting of polyether, polyester, polycarbonate, natural seed oil polyol, and combinations thereof.
13. The continuous process for producing an ultra-high solid content polyurethane dispersion according to Claim 12, wherein said first or second polyurethane prepolymer is ionic or non-ionic.
14. The continuous process for producing an ultra-high solid content polyurethane dispersion according to Claim 8, wherein said first or second polyurethane prepolymer is isocyanate terminated or hydroxyl terminated.
44
15. The continuous process for producing an ultra-high solid content polyurethane dispersion according to Claim 8, wherein said first or second polyurethane prepolymer is isocyanate terminated or hydroxy! terminated.
16. A method for producing an article comprising the steps of: providing a first stream, wherein said first stream comprises a first polyurethane prepolymer or a first polyurethane prepolymer emulsion; providing a second stream, wherein second stream is a media phase selected from the group consisting of a second polyurethane prepolymer, a second polyurethane prepolymer emulsion, a polyurethane dispersion, a seed latex emulsion, or combinations thereof; continuously merging the first stream with the second stream optionally in the presence of a chain extender; (4) thereby forming a polyurethane dispersion having a solid content of at least 60 percent by weight of the solid, based on the total weight of the ultra-high solid content polyurethane dispersion, and a viscosity of less than 5000 cps at 20 rpm at 21° C using spindle #4 with Brookfield viscometer; applying the dispersion to a substrate drying the dispersion; and thereby forming the article.
17. A method for producing an article comprising the steps of: providing a first stream, wherein said first stream comprises a first polyurethane prepolymer or a first polyurethane prepolymer emulsion; providing a second stream, wherein second stream is a media phase selected from the group consisting of a second polyurethane prepolymer, a second polyurethane prepolymer emulsion, a polyurethane dispersion, a seed latex emulsion, or combinations thereof; continuously merging the first stream with the second stream optionally in the presence of a chain extender; (4) thereby forming a polyurethane dispersion having a solid content of at least 60 percent by weight of the solid, based on the total weight of the ultra-high solid content polyurethane dispersion, and a viscosity of less than 5000 cps at 20 rpm at 21° C using spindle #4 with Brookfield viscometer; frothing the dispersion; thereby forming a foam; drying the foam; and thereby forming the article.
18. An article produced according to the method of either Claim 16 or Claim 17.
46
PCT/US2007/088194 2006-12-19 2007-12-19 An ultra-high solid content polyurethane dispersion and a continuous process for producing ultra-high solid content polyurethane dispersions WO2008077118A2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
AT07865887T ATE517933T1 (en) 2006-12-19 2007-12-19 ULTRA HIGH SOLIDS POLYURETHANE DISPERSION AND CONTINUOUS PROCESS FOR PRODUCING ULTRA HIGH SOLIDS POLYURETHANE DISPERSIONS
MX2009006624A MX2009006624A (en) 2006-12-19 2007-12-19 An ultra-high solid content polyurethane dispersion and a continuous process for producing ultra-high solid content polyurethane dispersions.
US12/519,831 US8821983B2 (en) 2006-12-19 2007-12-19 Ultra-high solid content polyurethane dispersion and a continuous process for producing ultra-high solid content polyurethane dispersions
EP07865887A EP2094756B1 (en) 2006-12-19 2007-12-19 An ultra-high solid content polyurethane dispersion and a continuous process for producing ultra-high solid content polyurethane dispersions
CA002672604A CA2672604A1 (en) 2006-12-19 2007-12-19 An ultra-high solid content polyurethane dispersion and a continuous process for producing ultra-high solid content polyurethane dispersions
CN2007800513918A CN101605831B (en) 2006-12-19 2007-12-19 Ultra-high solid content polyurethane dispersion and continuous process for producing ultra-high solid content polyurethane dispersions
BRPI0719419A BRPI0719419B8 (en) 2006-12-19 2007-12-19 continuous process for producing an ultra-high solids aqueous polyurethane dispersion and method for producing an article
JP2009543194A JP2010513701A (en) 2006-12-19 2007-12-19 Polyurethane dispersion with ultra-high solid content and continuous process for producing polyurethane dispersion with ultra-high solid content

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87565606P 2006-12-19 2006-12-19
US60/875,656 2006-12-19

Publications (3)

Publication Number Publication Date
WO2008077118A2 WO2008077118A2 (en) 2008-06-26
WO2008077118A3 WO2008077118A3 (en) 2008-10-16
WO2008077118B1 true WO2008077118B1 (en) 2008-11-27

Family

ID=39325855

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US2007/088197 WO2008077120A1 (en) 2006-12-19 2007-12-19 Composition comprising polyurethane dispersion having high solids content
PCT/US2007/088194 WO2008077118A2 (en) 2006-12-19 2007-12-19 An ultra-high solid content polyurethane dispersion and a continuous process for producing ultra-high solid content polyurethane dispersions

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/US2007/088197 WO2008077120A1 (en) 2006-12-19 2007-12-19 Composition comprising polyurethane dispersion having high solids content

Country Status (15)

Country Link
US (2) US8821983B2 (en)
EP (2) EP2094756B1 (en)
JP (2) JP2010513702A (en)
KR (2) KR101467594B1 (en)
CN (2) CN101432327A (en)
AT (2) ATE499394T1 (en)
BR (2) BRPI0719419B8 (en)
CA (2) CA2643426A1 (en)
DE (1) DE602007012665D1 (en)
DK (1) DK1991597T3 (en)
MX (2) MX2008013124A (en)
RU (2) RU2009127752A (en)
TW (2) TW200838891A (en)
WO (2) WO2008077120A1 (en)
ZA (1) ZA200807314B (en)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008077120A1 (en) * 2006-12-19 2008-06-26 Dow Global Technologies Inc. Composition comprising polyurethane dispersion having high solids content
US9234068B2 (en) * 2007-10-02 2016-01-12 The Hong Kong University of Science and Technologhy Method for preparing aqueous polyacrylate modified polyurethane dispersions
JP5348520B2 (en) * 2008-05-29 2013-11-20 日本ポリウレタン工業株式会社 Method and system for producing polyurethane water dispersion
BRPI0909892A2 (en) * 2008-06-03 2015-10-06 Dow Global Technologies Inc sealant composition
WO2009148902A1 (en) * 2008-06-03 2009-12-10 Dow Global Technologies Inc. A composite dispersion, method of producing the same, and articles made therefrom
EP2283097B1 (en) * 2008-06-03 2019-10-30 Dow Global Technologies LLC Pressure sensitive adhesive compositions and method of making the same
EP2303942A1 (en) * 2008-06-03 2011-04-06 Dow Global Technologies Inc. Heat activated adhesive compositions and method of making the same
CN102333803B (en) * 2009-03-27 2013-11-27 三井化学株式会社 Polyurethane dispersion and process for producing same
WO2010114648A1 (en) * 2009-03-30 2010-10-07 Dow Global Technologies Inc. Hybrid dispersions and methods for producing the same
TWI404596B (en) * 2009-09-22 2013-08-11 San Fang Chemical Industry Co Method for manufacturing polishing pad and polishing pad
CN101787100B (en) * 2010-02-10 2011-08-17 黄山加佳科技有限公司 Synthesis technology of water-emulsion fluorescent pigment
CN102211319B (en) * 2010-04-08 2014-06-11 三芳化学工业股份有限公司 Polishing pad manufacturing method and polishing pad
CN101824299B (en) * 2010-04-30 2012-10-03 山西省应用化学研究所 Method for preparing single-component high-solid content water-based polyurethane adhesive
WO2012020026A1 (en) * 2010-08-12 2012-02-16 Bayer Materialscience Ag Process for the production of polyurethane-urea dispersions
ITMI20110632A1 (en) * 2011-04-14 2012-10-15 Sapsa Bedding Srl PROCEDURE FOR THE MANUFACTURE OF A COMPOSITE FOAM
JP6031103B2 (en) 2011-07-22 2016-11-24 ダウ グローバル テクノロジーズ エルエルシー Fabrication method of cemented and skinned ceramic honeycomb structure
CN102504527A (en) * 2011-11-15 2012-06-20 华东理工大学 Ultraviolet curing cationic aqueous polyurethane dispersion liquid with ion-containing soft segment, and preparation method thereof
CN103254864B (en) * 2012-02-16 2014-12-03 苏州井上高分子新材料有限公司 Aqueous adhesive used for aircraft seats and preparation method thereof
US9732026B2 (en) 2012-12-14 2017-08-15 Resinate Technologies, Inc. Reaction products containing hydroxyalkylterephthalates and methods of making and using same
CA2906460C (en) * 2013-03-15 2020-12-01 Stepan Company Polyester polyols imparting improved flammability properties
CN103484051A (en) * 2013-09-29 2014-01-01 苏州华周胶带有限公司 Hot-sealing adhesive tape adhesive
CN103992737B (en) * 2014-05-24 2016-05-11 南京武家嘴船舶制造有限公司 Ship hull coating material of a kind of water-proof climate resisting and preparation method thereof
KR102154144B1 (en) 2014-08-01 2020-09-09 대우조선해양 주식회사 Cooling system using sea water, and cooling method thereof
BR112017011603A2 (en) 2014-12-01 2018-03-06 Dow Global Technologies Llc shrink films and methods for making the same
TWI650159B (en) * 2017-11-27 2019-02-11 三芳化學工業股份有限公司 Sphere structure and manufacturing method thereof
NL2020093B1 (en) 2017-12-15 2019-06-25 Stahl Int B V Process for producing aqueous polyurethane dispersions in a continuous manner; apparatus suitable for performing such a process; and products obtained by said process
WO2019216700A1 (en) * 2018-05-11 2019-11-14 주식회사 삼양사 Solid dispersion, preparation method therefor, chain-extended polyurethane using same, and epoxy resin composition comprising same
NL2023089B1 (en) 2019-05-08 2019-10-04 Stahl Int B V Process for producing aqueous polyurethane dispersions in a continuous manner; apparatus suitable for performing such a process; and products obtained by said process
CN111334235B (en) * 2020-03-16 2021-09-28 重庆中科力泰高分子材料股份有限公司 Polyurethane water-based adhesive with double prepolymer structures and preparation method thereof
CN111518257B (en) * 2020-05-29 2021-11-23 骏能化工（龙南）有限公司 Water-based polyurethane shoe adhesive and preparation method thereof
CN111909392A (en) * 2020-07-24 2020-11-10 合肥科天水性科技有限责任公司 Ultrahigh-solid-content aqueous polyurethane resin and preparation method thereof
KR102301468B1 (en) * 2020-12-15 2021-09-15 주식회사 씨엔에스파트너 Aqueous polyurethane dispersion for coating glove, coating solution manufacturing method comprising the same and coating glove coated with the same
CN114656602B (en) * 2022-02-16 2023-12-19 万华化学集团股份有限公司 Prepolymer for polymer polyol and preparation method thereof
CN117534956A (en) * 2024-01-09 2024-02-09 乐陵思盛聚合物材料有限公司 High-solid-content aqueous polyurethane emulsion easy to self-foam and preparation method thereof

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1595685A1 (en) * 1966-09-30 1969-08-21 Bayer Ag Process for the production of modified, aqueous dispersions of polymers and copolymers
US3985688A (en) * 1972-05-18 1976-10-12 Minnesota Mining And Manufacturing Company Poly (urethane-urea) foam sealants for underground application and fluid precursors
JPS51123298A (en) * 1975-04-21 1976-10-27 Dainippon Ink & Chem Inc A method for manufacturing a foamed polyurethane
US4119602A (en) * 1977-04-07 1978-10-10 W. R. Grace & Co. Aqueous urethane codispersions
US4130523A (en) 1977-07-18 1978-12-19 Union Carbide Corporation High solids latexes
US4315703A (en) * 1979-06-25 1982-02-16 Minnesota Mining And Manufacturing Company Sealing method using latex-reinforced polyurethane sewer sealing composition
US4476276A (en) * 1979-06-25 1984-10-09 Minnesota Mining And Manufacturing Company Latex-reinforced polyurethane sewer sealing composition
DE3147008A1 (en) * 1981-11-27 1983-06-01 Röhm GmbH, 6100 Darmstadt METHOD FOR PRODUCING AQUEOUS, HIGH-CONCENTRATED BIMODAL PLASTIC DISPERSIONS
DE3239900A1 (en) * 1982-10-28 1984-05-03 Bayer Ag, 5090 Leverkusen LEVELING POLYURETHANE HIGH SOLID REACTIVE COATING SYSTEMS AND THEIR USE FOR REACTIVE COATING
US4609690A (en) * 1983-09-29 1986-09-02 Ashland Oil, Inc. Aqueous hydroxyl-acrylic latex and water dispersible multi-isocyanate adhesive composition
US4605725A (en) * 1984-11-14 1986-08-12 Basf Corporation Polyurethane sealant compositions and their use as thermal-break sealants
US4644030A (en) * 1985-02-01 1987-02-17 Witco Corporation Aqueous polyurethane - polyolefin compositions
US4783502A (en) * 1987-12-03 1988-11-08 Ppg Industries, Inc. Stable nonaqueous polyurethane microparticle dispersion
JP2969460B2 (en) * 1988-07-08 1999-11-02 大日本インキ化学工業株式会社 Method for producing aqueous polyurethane dispersion
US5155201A (en) * 1989-07-13 1992-10-13 Akzo N.V. Polyurethane polyols and high solids coatings therefrom
DE4127513A1 (en) * 1991-08-20 1993-02-25 Bayer Ag BINDER MIXTURES AND ITS USE
DE4213967A1 (en) * 1992-04-29 1993-11-04 Basf Ag AQUEOUS POLYMER DISPERSION
DE4213965A1 (en) * 1992-04-29 1993-11-04 Basf Ag AQUEOUS POLYMER DISPERSION
DE4213968A1 (en) * 1992-04-29 1993-11-04 Basf Ag AQUEOUS POLYMER DISPERSION
DE4213964A1 (en) * 1992-04-29 1993-11-04 Basf Ag AQUEOUS POLYMER DISPERSIONS
DE4213969A1 (en) * 1992-04-29 1993-11-04 Basf Ag AQUEOUS POLYMER DISPERSION
JP3779333B2 (en) * 1992-05-28 2006-05-24 大日本インキ化学工業株式会社 Method for producing aqueous dispersion of high solid content polyurethane resin
US5721302A (en) * 1994-06-06 1998-02-24 Wood; Benny R. Water dispersible adhesive
US5759695A (en) * 1997-06-05 1998-06-02 Huntsman Petrochemical Corporation Polyurea elastomer systems with improved adhesion to substrates
DE19812751C2 (en) * 1998-03-24 2001-11-22 Skw Bauchemie Gmbh Solvent-free polyurethane dispersion
JP2000198828A (en) * 1999-01-07 2000-07-18 Sekisui Chem Co Ltd Manufacture of aqueous composition
US6087440A (en) * 1999-02-16 2000-07-11 The Dow Chemical Company Continuous process for preparing a polyurethane latex
DE19933826A1 (en) * 1999-07-20 2001-02-01 Basf Ag Aqueous dispersion of a mixture of a polyurethane with a radiation-curable (meth) acrylate prepolymer
DE19949971A1 (en) * 1999-10-16 2001-04-19 Skw Bauchemie Gmbh Solvent-free polyurethane-polymer hybrid dispersion, used especially in floor coatings for sports areas, obtained by radically polymerizing unsaturated monomers in neutralized polyurethane base dispersion
US6329060B1 (en) * 1999-11-10 2001-12-11 Ppg Industries Ohio, Inc. Solvent-free film-forming compositions for clearcoats, coated substrates and method related thereto
ES2187427T3 (en) * 2000-06-23 2003-06-16 Nat Starch Chem Invest INA DISPERSION OF POLYMER THAT INCLUDES PARTICLES OF POLYURETHANE AND OF A COPOLYMER OR TERPOLIMERO PRODUCED THROUGH POLYMERIZATION BY EMULSION OF OLYFINICALLY INSATURED MONOMERS.
DE10038941C2 (en) * 2000-08-09 2002-08-14 Skw Bauwerkstoffe Deutschland Polyurethane (polymer hybrid) dispersion with reduced hydrophilicity, process for its preparation and its use
CA2427836C (en) * 2000-11-02 2009-12-29 Dow Global Technologies Inc. Process for preparing aqueous dispersions of hybrid polyurethane particles
EP1354009B1 (en) * 2001-01-17 2009-03-04 Dow Global Technologies Inc. Bimodal aqueous polymer dispersions
US6855765B2 (en) * 2001-12-12 2005-02-15 National University Of Singapore Heat and hot water resistant polyurethane sealant
DE10223614A1 (en) * 2002-05-27 2003-12-11 Basf Ag Radiation-curable aqueous dispersions
US20040116594A1 (en) * 2002-12-11 2004-06-17 Debkumar Bhattacharjee Polyurethane prepolymer, stable aqueous dispersions with high solids containing the same and method of using and preparing the aqueous dispersions
US7582698B2 (en) * 2003-07-02 2009-09-01 Lubrizol Advanced Materials, Inc. Water dispersions of non-uniform polyurethane particles
DE10331484A1 (en) * 2003-07-11 2005-03-03 Construction Research & Technology Gmbh Polyurethane-polymer hybrid dispersion with improved surface properties, process for their preparation and their use
EP1646669A1 (en) * 2003-07-14 2006-04-19 Cytec Surface Specialties, S.A. Waterborne self-crosslinkable polyurethane dispersions and polyurethane: acrylic hybrid dispersions
DE102004060139A1 (en) * 2004-12-13 2006-06-29 Bayer Materialscience Ag Solid-rich polyurethane-polyurea dispersions
WO2008077120A1 (en) * 2006-12-19 2008-06-26 Dow Global Technologies Inc. Composition comprising polyurethane dispersion having high solids content
BRPI0909892A2 (en) * 2008-06-03 2015-10-06 Dow Global Technologies Inc sealant composition
EP2303942A1 (en) * 2008-06-03 2011-04-06 Dow Global Technologies Inc. Heat activated adhesive compositions and method of making the same
EP2283097B1 (en) * 2008-06-03 2019-10-30 Dow Global Technologies LLC Pressure sensitive adhesive compositions and method of making the same

Also Published As

Publication number Publication date
BRPI0709290A2 (en) 2011-07-05
ATE499394T1 (en) 2011-03-15
CN101605831B (en) 2012-12-26
TW200838891A (en) 2008-10-01
KR20090098984A (en) 2009-09-18
KR101467594B1 (en) 2014-12-01
US8821983B2 (en) 2014-09-02
CA2672604A1 (en) 2008-06-26
BRPI0719419B8 (en) 2018-11-13
JP2010513702A (en) 2010-04-30
MX2008013124A (en) 2008-10-21
DK1991597T3 (en) 2011-06-14
EP2094756B1 (en) 2011-07-27
WO2008077118A3 (en) 2008-10-16
ZA200807314B (en) 2010-01-27
DE602007012665D1 (en) 2011-04-07
KR20090100224A (en) 2009-09-23
CN101432327A (en) 2009-05-13
RU2008138868A (en) 2010-04-10
JP2010513701A (en) 2010-04-30
TW200927831A (en) 2009-07-01
RU2009127752A (en) 2011-01-27
EP1991597B1 (en) 2011-02-23
US20100015341A1 (en) 2010-01-21
MX2009006624A (en) 2009-09-29
WO2008077118A2 (en) 2008-06-26
EP2094756A2 (en) 2009-09-02
CN101605831A (en) 2009-12-16
US20090012230A1 (en) 2009-01-08
BRPI0719419A2 (en) 2014-02-11
WO2008077120A1 (en) 2008-06-26
BRPI0719419B1 (en) 2018-10-16
EP1991597A1 (en) 2008-11-19
CA2643426A1 (en) 2008-06-26
ATE517933T1 (en) 2011-08-15

Similar Documents

Publication Publication Date Title
WO2008077118B1 (en) An ultra-high solid content polyurethane dispersion and a continuous process for producing ultra-high solid content polyurethane dispersions
JP2010513701A5 (en)
EP0689561B1 (en) A polyurethane foam containing a particulate organic solid and a process for the preparation thereof
WO2013173836A4 (en) An encapsulated particle
NO179287B (en) Process for the production of polyurethane foam without the use of inert propellants
EP3765541B1 (en) Flexible polyurethane foam having prolonged recovery time
HK1065807A1 (en) Aqueous 2k pur systems
CA2455513A1 (en) Agents for reducing the force-to-crush (ftc) of high support flexible foams
US5084486A (en) Reactive feed stream to replace inert blowing agent feed stream in a polyurethane foam process
US6590028B1 (en) Aqueous two-component polyurethane systems with increased impact resistance, high stability and good optical properties, method for producing same and their use
US10370479B2 (en) Process for making a polymer polyol
JP2002533489A5 (en)
JP6761308B2 (en) Curable composition for flexible polyurethane foam containing polymer fine particles having a core-shell structure
AU753481B2 (en) Process for the preparation of flexible polyurethane foams
CN108409940A (en) A kind of preparation method for the modification MDI being used to prepare high rebound foam
EP4038126A1 (en) Spray polyurethane elastomers and methods for producing the same
JP2004051707A (en) Aqueous emulsion and its manufacturing method

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200780051391.8

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2672604

Country of ref document: CA

ENP Entry into the national phase

Ref document number: 2009543194

Country of ref document: JP

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 12519831

Country of ref document: US

Ref document number: 3494/CHENP/2009

Country of ref document: IN

Ref document number: 2007865887

Country of ref document: EP

Ref document number: MX/A/2009/006624

Country of ref document: MX

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 1020097014941

Country of ref document: KR

ENP Entry into the national phase

Ref document number: 2009127752

Country of ref document: RU

Kind code of ref document: A

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07865887

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: PI0719419

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20090618