WO2009076179A3 - Inorganic particles hydrophobized with fluoroalkyl silanes - Google Patents

Inorganic particles hydrophobized with fluoroalkyl silanes Download PDF

Info

Publication number
WO2009076179A3
WO2009076179A3 PCT/US2008/085612 US2008085612W WO2009076179A3 WO 2009076179 A3 WO2009076179 A3 WO 2009076179A3 US 2008085612 W US2008085612 W US 2008085612W WO 2009076179 A3 WO2009076179 A3 WO 2009076179A3
Authority
WO
WIPO (PCT)
Prior art keywords
inorganic particles
hydrophobized
fluoroalkyl silanes
particles hydrophobized
fluorosilanes
Prior art date
Application number
PCT/US2008/085612
Other languages
French (fr)
Other versions
WO2009076179A2 (en
Inventor
Gerald Oronde Brown
Axel Hans-Joachim Herzog
Original Assignee
E. I. Du Pont De Nemours And Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by E. I. Du Pont De Nemours And Company filed Critical E. I. Du Pont De Nemours And Company
Priority to CA2706702A priority Critical patent/CA2706702C/en
Priority to NZ585501A priority patent/NZ585501A/en
Priority to EP08859173.0A priority patent/EP2231786B1/en
Priority to AU2008335413A priority patent/AU2008335413B2/en
Priority to CN200880126116.2A priority patent/CN101932661B/en
Priority to JP2010537095A priority patent/JP2011506240A/en
Publication of WO2009076179A2 publication Critical patent/WO2009076179A2/en
Publication of WO2009076179A3 publication Critical patent/WO2009076179A3/en
Priority to HK11106471.2A priority patent/HK1152330A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12—Treatment with organosilicon compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/04—Compounds of zinc
    • C09C1/043—Zinc oxide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28—Compounds of silicon
    • C09C1/30—Silicic acid
    • C09C1/3081—Treatment with organo-silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3684—Treatment with organo-silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40—Compounds of aluminium
    • C09C1/407—Aluminium oxides or hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/86—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by NMR- or ESR-data
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated

Abstract

Inorganic particles hydrophobized with fluorosilanes have been used to impart hydrophobic as well as oleophobic properties. The hydrophobized inorganic particles of the present invention comprise residues from fluorosilanes wherein the silicon atom is first bonded to a divalent organic linking group which in turn is bonded to a perfluoroalkyl group. It has been discovered that incorporation of the aforementioned divalent organic linking group can improve the ability of resulting hydrophobized inorganic particles to impart hydrophobic as well as oleophobic properties.
PCT/US2008/085612 2007-12-05 2008-12-05 Inorganic particles hydrophobized with fluoroalkyl silanes WO2009076179A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CA2706702A CA2706702C (en) 2007-12-05 2008-12-05 Inorganic particles hydrophobized with fluoroalkyl silanes
NZ585501A NZ585501A (en) 2007-12-05 2008-12-05 Inorganic particles hydrophobized with fluoroalkyl silanes
EP08859173.0A EP2231786B1 (en) 2007-12-05 2008-12-05 Inorganic particles hydrophobized with fluoroalkyl silanes
AU2008335413A AU2008335413B2 (en) 2007-12-05 2008-12-05 Inorganic particles hydrophobized with fluoroalkyl silanes
CN200880126116.2A CN101932661B (en) 2007-12-05 2008-12-05 Inorganic particles hydrophobized with fluoroalkyl silanes
JP2010537095A JP2011506240A (en) 2007-12-05 2008-12-05 Hydrophobization of inorganic particles with fluoroalkylsilanes
HK11106471.2A HK1152330A1 (en) 2007-12-05 2011-06-22 Inorganic particles hydrophobized with fluoroalkyl silanes

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US566707P 2007-12-05 2007-12-05
US61/005,667 2007-12-05
US12/328,122 2008-12-04
US12/328,122 US8153834B2 (en) 2007-12-05 2008-12-04 Surface modified inorganic particles

Publications (2)

Publication Number Publication Date
WO2009076179A2 WO2009076179A2 (en) 2009-06-18
WO2009076179A3 true WO2009076179A3 (en) 2010-03-11

Family

ID=40631578

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/085612 WO2009076179A2 (en) 2007-12-05 2008-12-05 Inorganic particles hydrophobized with fluoroalkyl silanes

Country Status (9)

Country Link
US (1) US8153834B2 (en)
EP (1) EP2231786B1 (en)
JP (2) JP2011506240A (en)
KR (1) KR101544235B1 (en)
CN (1) CN101932661B (en)
CA (1) CA2706702C (en)
HK (1) HK1152330A1 (en)
NZ (1) NZ585501A (en)
WO (1) WO2009076179A2 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102216361B (en) * 2008-11-14 2014-01-29 纳幕尔杜邦公司 Fluoropolymer compositions and treated substrates
US8324314B2 (en) 2009-10-12 2012-12-04 E.I. Du Pont De Nemours And Company Fluoropolymer compositions and treated substrates
US8258341B2 (en) * 2009-07-10 2012-09-04 E.I. Du Pont De Nemours And Company Polyfluorosulfonamido amine and intermediate
US9777161B1 (en) 2010-08-16 2017-10-03 The United States Of America As Represented By The Secretary Of The Air Force Fluoroalkylsilanated mesoporous metal oxide particles and methods of preparation thereof
US8741432B1 (en) * 2010-08-16 2014-06-03 The United States Of America As Represented By The Secretary Of The Air Force Fluoroalkylsilanated mesoporous metal oxide particles and methods of preparation thereof
US8981140B1 (en) 2010-08-18 2015-03-17 The United States Of America As Represented By The Secretary Of The Air Force Peripherally aromatic silsesquioxanes featuring reactive functionality: synthesis and applications thereof
WO2012032868A1 (en) * 2010-09-09 2012-03-15 Hoya株式会社 Manufacturing method for surface-modified titanium particles, dispersion of titanium particles, and resin having titanium particles dispersed therein
CN102432742B (en) * 2011-09-09 2013-08-07 中科院广州化学有限公司 Super-amphiphobic polymer and super-amphiphobic surface prepared from super-amphiphobic polymer
US9249313B2 (en) 2011-09-21 2016-02-02 The United States Of America As Represented By The Secretary Of The Air Force Synthesis of functional fluorinated polyhedral oligomeric silsesquioxane (F-POSS)
KR101369381B1 (en) * 2011-11-04 2014-03-06 에스케이이노베이션 주식회사 Coating composition for low refractive layer comprising fluorine-containing compound, anti-reflection film using the same, polarizer and image displaying device comprising said anti-reflection film
CN102604467B (en) * 2012-01-13 2013-12-25 中科院广州化学有限公司 High-dispersion fluorine-containing nanosphere and epoxy resin super-amphiphobic surface
US9217064B2 (en) 2013-01-24 2015-12-22 The United States Of America, As Represented By The Secretary Of The Air Force Thermosetting resins with enhanced cure characteristics containing organofunctional silane moieties
US9394408B2 (en) 2013-08-29 2016-07-19 The United States Of America As Represented By The Secretary Of The Air Force Controlled polymerization of functional fluorinated polyhedral oligomeric silsesquioxane monomers
WO2016176388A1 (en) * 2015-04-30 2016-11-03 The Chemours Company Tt, Llc Crosslinkable fluorinated inorganic oxide particle for architectural coatings
CN106390764B (en) * 2015-07-28 2018-10-12 北京工业大学 A kind of super-hydrophobic oleophobic method of modifying of perforated membrane
WO2018160455A1 (en) 2017-03-03 2018-09-07 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Moisture-curable omniphobic coatings
CN109868652A (en) * 2019-03-07 2019-06-11 扬州金泉旅游用品有限公司 A method of preparing hydrophobic and antifouling fabric and cloth
KR102531723B1 (en) * 2020-11-06 2023-05-11 도레이첨단소재 주식회사 Release film and manufacturing method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0157218A1 (en) * 1984-03-09 1985-10-09 Daikin Industries, Limited Fluorine-containing silane compounds and method of preparing them
JPH03109482A (en) * 1989-09-22 1991-05-09 Mitsubishi Materials Corp Surface treating agent of jewel
US5739369A (en) * 1995-04-20 1998-04-14 Shin-Etsu Chemical Co., Ltd. Water-soluble surface treating agents
EP1055718A1 (en) * 1998-12-10 2000-11-29 Toray Industries, Inc. Optical article, method for preparing optical article and organic silicon compound
US20050038150A1 (en) * 2001-08-02 2005-02-17 Christian Meiners Fluoroalkyl-modified organosilanes and their use in coating compositions
US20060222815A1 (en) * 2003-05-15 2006-10-05 Degussa Ag Use of particles hydrophobized by fluorosilanes for the production of self-cleaning surfaces having lipophobic, oleophobic, lactophobic and hydrophobic properties

Family Cites Families (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3719698A (en) * 1967-11-27 1973-03-06 Stevens & Co Inc J P Polyfluorinated esters of acids containing silicon and amino groups
GB1267224A (en) * 1969-08-06 1972-03-15
US4171282A (en) * 1977-12-07 1979-10-16 Ciba-Geigy Corporation Fluorinated nonionic surfactants
JPH0393605A (en) * 1989-09-01 1991-04-18 Asahi Glass Co Ltd Improvement of flowability of metal oxide film powder
US5084653A (en) * 1990-07-18 1992-01-28 Nilssen Ole K Power-line-isolated dimmable electronic ballast
JP2673763B2 (en) * 1992-07-03 1997-11-05 信越化学工業株式会社 Surface-treated inorganic oxide particles
JPH08127733A (en) * 1994-11-01 1996-05-21 Shiseido Co Ltd Water-and oil-repellent solid and its production
JPH08157643A (en) * 1994-12-07 1996-06-18 Asahi Glass Co Ltd Water-repellent/oil-repellent porous silica particle and water-repellent/oil-repellent coating film
US5726247A (en) * 1996-06-14 1998-03-10 E. I. Du Pont De Nemours And Company Fluoropolymer nanocomposites
JPH09309745A (en) 1996-05-24 1997-12-02 Central Glass Co Ltd Water-repellent and oil-repellent article and its production
JPH10139930A (en) 1996-11-07 1998-05-26 Kansai Shin Gijutsu Kenkyusho:Kk Reactive particle
US6495624B1 (en) * 1997-02-03 2002-12-17 Cytonix Corporation Hydrophobic coating compositions, articles coated with said compositions, and processes for manufacturing same
JP3109482B2 (en) * 1998-06-29 2000-11-13 タイガー魔法瓶株式会社 Electric hot water storage container
JP4411668B2 (en) * 1998-08-13 2010-02-10 凸版印刷株式会社 Antifouling agent
JP2000191668A (en) * 1998-12-10 2000-07-11 Toray Ind Inc Fluorine-containing compound, antifouling composition and antifouling article
DE19938551A1 (en) 1999-08-18 2001-02-22 Penth Bernd Production of waterproof coatings, e.g. on metals, glass, ceramics or wood, involves coating with thin, nanoscale metal oxide layer from sol and then applying alkyl-trialkoxy-silane by condensation reaction
CH695946A5 (en) * 2000-04-04 2006-10-31 Schoeller Technologies Ag Finishing of textile fibers, tissues and fabrics.
JP4126521B2 (en) 2000-08-04 2008-07-30 信越化学工業株式会社 Method for producing fluoroorganopolysiloxane resin for film forming composition
DE10051182A1 (en) 2000-10-16 2002-05-02 Nano X Gmbh Nanoparticle useful for coating substrate surfaces to impart hydrophobicity and oleophobicity, has specific substituents consisting of perfluorinated carbon chains and/or hydrocarbon chains
DE10106213A1 (en) 2001-02-10 2002-08-22 Dmc2 Degussa Metals Catalysts Cerdec Ag Self-cleaning paint coatings and methods and means of making the same
DE10118352A1 (en) * 2001-04-12 2002-10-17 Creavis Tech & Innovation Gmbh Self-cleaning surfaces through hydrophobic structures and processes for their production
DE10118346A1 (en) * 2001-04-12 2002-10-17 Creavis Tech & Innovation Gmbh Self-cleaning, water-repellent textiles, used e.g. for tents, sports clothing and carpets, made by impregnating textile material with a suspension of hydrophobic particles and then removing the solvent
DE10118349A1 (en) * 2001-04-12 2002-10-17 Creavis Tech & Innovation Gmbh Self-cleaning surfaces through hydrophobic structures and processes for their production
DE10118351A1 (en) * 2001-04-12 2002-10-17 Creavis Tech & Innovation Gmbh Self-cleaning surfaces through hydrophobic structures and processes for their production
DE10134477A1 (en) * 2001-07-16 2003-02-06 Creavis Tech & Innovation Gmbh Self-cleaning surfaces through hydrophobic structures and processes for their production
DE10139574A1 (en) * 2001-08-10 2003-02-20 Creavis Tech & Innovation Gmbh Maintaining the lotus effect by preventing microbial growth on self-cleaning surfaces
DE10205007A1 (en) * 2002-02-07 2003-08-21 Creavis Tech & Innovation Gmbh Process for the production of protective layers with dirt and water repellent properties
CN1454921A (en) 2002-03-01 2003-11-12 刘铁林 Nano fluorocarbon double-hydropholic film preparation, and generating method thereof
DE10209297A1 (en) 2002-03-01 2003-09-18 Koenig & Bauer Ag Surface for machine parts of a printing press
DE10210667A1 (en) * 2002-03-12 2003-09-25 Creavis Tech & Innovation Gmbh Production of web products with self-cleaning surfaces by means of a calendering process, web products themselves and the use of these
DE10210671A1 (en) * 2002-03-12 2003-09-25 Creavis Tech & Innovation Gmbh Mold release agent which has hydrophobic, nanoscale particles and use of these mold release agents
DE10210666A1 (en) * 2002-03-12 2003-10-02 Creavis Tech & Innovation Gmbh Shaping process for the production of moldings with at least one surface which has self-cleaning properties, and moldings produced using this process
DE10210673A1 (en) * 2002-03-12 2003-09-25 Creavis Tech & Innovation Gmbh Injection molded body with self-cleaning properties and method for producing such injection molded body
US6790904B2 (en) * 2002-06-03 2004-09-14 Ppg Industries Ohio, Inc. Liquid coating of film-forming resin and particles chemically modified to lower surface tension
US7141618B2 (en) * 2002-06-03 2006-11-28 Ppg Industries Ohio, Inc. Coating compositions with modified particles and methods of using the same
DE10231757A1 (en) * 2002-07-13 2004-01-22 Creavis Gesellschaft Für Technologie Und Innovation Mbh Process for the preparation of a surfactant-free suspension on an aqueous basis of nanostructured, hydrophobic particles and their use
DE10242560A1 (en) * 2002-09-13 2004-03-25 Creavis Gesellschaft Für Technologie Und Innovation Mbh Process for preparation of self-cleaning surfaces on coated flat textile structures useful for cladding technical textiles and structures obtained from these and production of raincoats and safety clothing with signaling effect
US20060159849A1 (en) * 2002-09-19 2006-07-20 Daikin Industries Ltd. Material with pattern surface for use as template and process for producing the same
DE10250328A1 (en) * 2002-10-29 2004-05-13 Creavis Gesellschaft Für Technologie Und Innovation Mbh Production of suspensions of hydrophobic oxide particles
US7407899B2 (en) * 2003-01-10 2008-08-05 Milliken & Company Textile substrates having layered finish structure for improving liquid repellency and stain release
DE10308379A1 (en) * 2003-02-27 2004-09-09 Creavis Gesellschaft Für Technologie Und Innovation Mbh Dispersion of water in hydrophobic oxides for the production of hydrophobic nanostructured surfaces
CN1441147A (en) 2003-03-14 2003-09-10 国玉江 Production process of metal pipe and rod with hydrophobic, olephobic and three-preventing functions and the paint used
KR20050107814A (en) * 2003-03-19 2005-11-15 가부시키가이샤 가네보케쇼힝 Cosmetic preparation
CN1469021A (en) 2003-04-25 2004-01-21 河 冯 Application of hydrophobic and oleophobic nano interface material in toilet
EP1479738A1 (en) 2003-05-20 2004-11-24 DSM IP Assets B.V. Hydrophobic coatings comprising reactive nano-particles
AU2003298231A1 (en) 2003-05-28 2005-01-21 Nanogate Coating Systems Gmbh Hydrophobic and/or oleophobic coating for glass surfaces with adhesion sites for sealants
US20070166464A1 (en) 2003-09-02 2007-07-19 Kazim Acatay Process for preparing superhydrophobic surface compositions, surfaces obtained by said process and use of them
CN100463931C (en) 2003-11-03 2009-02-25 长春赛纳纳米服饰有限公司 Textile finishing agent modified from Nano material and preparation method
CN1614128A (en) 2003-11-05 2005-05-11 北京中科安康医疗用品有限公司 Insulative bactericidal and anti-virus fabrics and its production and medical garment for hospital stuff
CN1614129A (en) 2003-11-05 2005-05-11 北京中科安康医疗用品有限公司 Bactericidal and anti-virus fabrics and its production and garment for patients therefrom
WO2005068399A1 (en) 2004-01-15 2005-07-28 Newsouth Innovations Pty Limited Method of making a surface hydrophobic
US7435450B2 (en) 2004-01-30 2008-10-14 Hewlett-Packard Development Company, L.P. Surface modification of silica in an aqueous environment
KR100607716B1 (en) 2004-04-22 2006-08-01 한국화학연구원 Fluorine-containing anti-fingerprint agents and preparation method thereof
TW200615424A (en) 2004-07-20 2006-05-16 Schoeller Textil Ag Finishings for textile fibres and babrics to give hydrophobic oleophobic and self-cleaning surfaces
CN1727566A (en) 2004-07-29 2006-02-01 只金芳 Nano water and oil repellent, and application in face fabric of winter proofing suit and necktie
DE102004037752A1 (en) 2004-08-04 2006-03-16 Cognis Deutschland Gmbh & Co. Kg Equipped fibers and textile fabrics
DE102004046568A1 (en) 2004-09-24 2006-04-06 Construction Research & Technology Gmbh Fluoromodified reactive resin systems, process for their preparation and their use
US20080090004A1 (en) 2004-10-05 2008-04-17 Hua Zhang Hydrophobic and Lyophobic Coating
CN100500778C (en) * 2004-11-23 2009-06-17 鸿富锦精密工业（深圳）有限公司 Anti-fingeprinting surface coating
DE102004062742A1 (en) * 2004-12-27 2006-07-06 Degussa Ag Textile substrates with self-cleaning properties (lotus effect)
DE102004062739A1 (en) * 2004-12-27 2006-07-06 Degussa Ag Self-cleaning surfaces with protrusions formed by hydrophobic particles, with improved mechanical strength
DE102004062743A1 (en) * 2004-12-27 2006-07-06 Degussa Ag Process for increasing the water-tightness of textile fabrics, textile fabrics treated in this way and their use
DE102004062740A1 (en) * 2004-12-27 2006-07-13 Degussa Ag Process for increasing the water-tightness of textile fabrics, textile fabrics treated in this way and their use
US8058463B2 (en) * 2007-12-04 2011-11-15 E. I. Du Pont De Nemours And Compnay Fluorosilanes

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0157218A1 (en) * 1984-03-09 1985-10-09 Daikin Industries, Limited Fluorine-containing silane compounds and method of preparing them
JPH03109482A (en) * 1989-09-22 1991-05-09 Mitsubishi Materials Corp Surface treating agent of jewel
US5739369A (en) * 1995-04-20 1998-04-14 Shin-Etsu Chemical Co., Ltd. Water-soluble surface treating agents
EP1055718A1 (en) * 1998-12-10 2000-11-29 Toray Industries, Inc. Optical article, method for preparing optical article and organic silicon compound
US20050038150A1 (en) * 2001-08-02 2005-02-17 Christian Meiners Fluoroalkyl-modified organosilanes and their use in coating compositions
US20060222815A1 (en) * 2003-05-15 2006-10-05 Degussa Ag Use of particles hydrophobized by fluorosilanes for the production of self-cleaning surfaces having lipophobic, oleophobic, lactophobic and hydrophobic properties

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
YAROSH ET AL: "Synthesis of water- and oil-repellent organofluorosilicon compounds", MENDELEEV COMMUNICATIONS, INSTITUTE OF PHYSICS PUBLISHING, BRISTOL, GB, vol. 16, no. 3, 1 January 2006 (2006-01-01), pages 190 - 192, XP022533366, ISSN: 0959-9436 *

Also Published As

Publication number Publication date
HK1152330A1 (en) 2012-02-24
US20090176097A1 (en) 2009-07-09
JP2011506240A (en) 2011-03-03
JP2015131755A (en) 2015-07-23
CN101932661A (en) 2010-12-29
KR20100110806A (en) 2010-10-13
CA2706702A1 (en) 2009-06-18
EP2231786B1 (en) 2018-12-05
NZ585501A (en) 2011-10-28
EP2231786A2 (en) 2010-09-29
JP5956617B2 (en) 2016-07-27
AU2008335413A1 (en) 2009-06-18
CN101932661B (en) 2014-05-14
WO2009076179A2 (en) 2009-06-18
KR101544235B1 (en) 2015-08-12
US8153834B2 (en) 2012-04-10
CA2706702C (en) 2018-01-16

Similar Documents

Publication Publication Date Title
WO2009076179A3 (en) Inorganic particles hydrophobized with fluoroalkyl silanes
BRPI1009907A8 (en) "dispersion containing surface modified silica particles with quaternary aminofunctional organosilicon compounds."
WO2009018463A3 (en) Fluoropolymer fine fiber
WO2012028964A3 (en) Reduced graphene oxide-based-composites for the purification of water
WO2007139615A9 (en) Use of hydrolysis resistant organomodified silylated surfactants
ZA201003876B (en) Antibodies to gdf8 as uses thereof
IL206036A0 (en) ANTIBODIES TO THE PcrV ANTIGEN OF PSEUDOMONAS AERUGINOSA AND USES THEREOF
EP2155620A4 (en) Preparation of super water repellent surface
JP2014500163A5 (en)
JP2010260863A5 (en)
WO2010059913A3 (en) Preparation of rasagiline and salts thereof
BRPI1012950A2 (en) "oil vapor separator"
WO2010054714A3 (en) Adsorptive molded parts and the use thereof
HK1150610A1 (en) Fluoroalkyl silanes
WO2009045993A3 (en) Compositions comprising cationic fluorinated ether, silanes, and related methods
WO2007102130A3 (en) Mems resonator having at least one resonator mode shape
WO2012085855A3 (en) Solid anhydrous cosmetic composition
WO2009003981A3 (en) Hybrid nanoparticles
EP1991412A4 (en) The use of organophosphorus compounds as creping aids
WO2011006875A3 (en) Mineral fibres and their use
MA38101B1 (en) Flotation of silicates from ores
BRPI0919991A2 (en) "fluid filter"
EP2209758A4 (en) Generation of endo- and/or exo-norbornenecarboxaldehyde as an intermediate to functionalized norbornenes
JP2012211299A5 (en)
WO2012028701A3 (en) Hydrophobic, functionalized particles

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880126116.2

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08859173

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 585501

Country of ref document: NZ

Ref document number: 2008335413

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 2706702

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 2008859173

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2010537095

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2008335413

Country of ref document: AU

Date of ref document: 20081205

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 4319/DELNP/2010

Country of ref document: IN

ENP Entry into the national phase

Ref document number: 20107014618

Country of ref document: KR

Kind code of ref document: A