WO2011034885A3 - Epoxy-functionalized perfluoropolyether polyurethanes - Google Patents

Epoxy-functionalized perfluoropolyether polyurethanes Download PDF

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Publication number
WO2011034885A3
WO2011034885A3 PCT/US2010/048876 US2010048876W WO2011034885A3 WO 2011034885 A3 WO2011034885 A3 WO 2011034885A3 US 2010048876 W US2010048876 W US 2010048876W WO 2011034885 A3 WO2011034885 A3 WO 2011034885A3
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WO
WIPO (PCT)
Prior art keywords
epoxy
functionalized perfluoropolyether
carbon atoms
lower alkyl
polyurethanes
Prior art date
Application number
PCT/US2010/048876
Other languages
French (fr)
Other versions
WO2011034885A2 (en
Inventor
Zai-Ming Qiu
John C. Hulteen
Original Assignee
3M Innovative Properties Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Company filed Critical 3M Innovative Properties Company
Priority to EP10817735.3A priority Critical patent/EP2478035A4/en
Priority to KR1020127009449A priority patent/KR101781660B1/en
Priority to CN2010800413610A priority patent/CN102498156B/en
Publication of WO2011034885A2 publication Critical patent/WO2011034885A2/en
Publication of WO2011034885A3 publication Critical patent/WO2011034885A3/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/2845—Monohydroxy epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/2885—Compounds containing at least one heteroatom other than oxygen or nitrogen containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C08G18/588—Epoxy resins having silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
    • C08G59/308—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3254—Epoxy compounds containing three or more epoxy groups containing atoms other than carbon, hydrogen, oxygen or nitrogen
    • C08G59/329—Epoxy compounds containing three or more epoxy groups containing atoms other than carbon, hydrogen, oxygen or nitrogen containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
    • C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
    • C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/321—Polymers modified by chemical after-treatment with inorganic compounds
    • C08G65/323—Polymers modified by chemical after-treatment with inorganic compounds containing halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/14—Polyamide-imides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/08—Polyurethanes from polyethers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/0046—Photosensitive materials with perfluoro compounds, e.g. for dry lithography
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable

Abstract

Disclosed are epoxy-functionalized perfluoropolyether polyurethane compounds having the following general structure (RfQX1C(O)NH)m-Ri-(NHC(O)X2Q(E)o)n wherein Rf is a monovalent perfluoropolyether moiety; Q is independently a connecting group of valence at least 2, which may contain heteroatoms; X1 is O, S, or NR, wherein R is H or a lower alkyl of 1 to 4 carbon atoms; Ri is a residue of a multi-isocyanate; X2 is O, S, or NR, wherein R is a lower alkyl of 1 to 4 carbon atoms; E is an organic group having at least one oxirane ring; m is at least 1; n is at least 1; o is 1, 2 or 3; and m + n is from 2 to 10.
PCT/US2010/048876 2009-09-16 2010-09-15 Epoxy-functionalized perfluoropolyether polyurethanes WO2011034885A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP10817735.3A EP2478035A4 (en) 2009-09-16 2010-09-15 Epoxy-functionalized perfluoropolyether polyurethanes
KR1020127009449A KR101781660B1 (en) 2009-09-16 2010-09-15 Epoxy-functionalized perfluoropolyether polyurethanes
CN2010800413610A CN102498156B (en) 2009-09-16 2010-09-15 Epoxy-functionalized perfluoropolyether polyurethanes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/561,113 US8420281B2 (en) 2009-09-16 2009-09-16 Epoxy-functionalized perfluoropolyether polyurethanes
US12/561,113 2009-09-16

Publications (2)

Publication Number Publication Date
WO2011034885A2 WO2011034885A2 (en) 2011-03-24
WO2011034885A3 true WO2011034885A3 (en) 2011-08-18

Family

ID=43730917

Family Applications (1)

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PCT/US2010/048876 WO2011034885A2 (en) 2009-09-16 2010-09-15 Epoxy-functionalized perfluoropolyether polyurethanes

Country Status (6)

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US (1) US8420281B2 (en)
EP (1) EP2478035A4 (en)
KR (1) KR101781660B1 (en)
CN (1) CN102498156B (en)
TW (1) TWI512057B (en)
WO (1) WO2011034885A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9096712B2 (en) 2009-07-21 2015-08-04 3M Innovative Properties Company Curable compositions, method of coating a phototool, and coated phototool

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009114580A2 (en) * 2008-03-11 2009-09-17 3M Innovative Properties Company Hardcoat composition
US8420281B2 (en) 2009-09-16 2013-04-16 3M Innovative Properties Company Epoxy-functionalized perfluoropolyether polyurethanes
WO2011034847A1 (en) 2009-09-16 2011-03-24 3M Innovative Properties Company Fluorinated coating and phototools made therewith
WO2011034845A1 (en) 2009-09-16 2011-03-24 3M Innovative Properties Company Fluorinated coating and phototools made therewith
US8715904B2 (en) 2012-04-27 2014-05-06 3M Innovative Properties Company Photocurable composition
EP2883109A1 (en) 2012-08-09 2015-06-17 3M Innovative Properties Company Photocurable compositions
US8883402B2 (en) * 2012-08-09 2014-11-11 3M Innovative Properties Company Photocurable compositions
CN103526324B (en) * 2013-10-14 2015-06-17 江苏恒力化纤股份有限公司 High-strength low-elongation creep-resistant polyester industrial yarn and preparation method
CN103526328B (en) * 2013-10-14 2015-10-07 江苏恒力化纤股份有限公司 Supplementary restraint system industrial yarn of a kind of creep resistant polyester and preparation method thereof
CN107075338B (en) * 2014-11-19 2020-11-27 横滨橡胶株式会社 Two-pack polyurethane adhesive composition
CN106432686B (en) * 2016-06-21 2018-12-14 衢州氟硅技术研究院 A kind of novel perfluoropolyether alkoxysilane compound and its synthetic method
US11155710B2 (en) * 2016-08-09 2021-10-26 Solvay Specialty Polymers Italy S.P.A. Composition comprising aromatic and fluorinated polymers and use thereof
CN109715701B (en) * 2016-09-23 2021-07-27 大金工业株式会社 Water-repellent substrate
US10544260B2 (en) 2017-08-30 2020-01-28 Ppg Industries Ohio, Inc. Fluoropolymers, methods of preparing fluoropolymers, and coating compositions containing fluoropolymers
CN112480355B (en) * 2020-12-04 2022-07-05 上海应用技术大学 Low-surface-energy resin emulsion and preparation method thereof
CN112608445B (en) * 2020-12-04 2022-07-12 上海应用技术大学 Ultraviolet light curing resin and preparation method thereof
CN115558419B (en) * 2022-10-28 2023-07-21 西安长峰机电研究所 Photo-curing composite epoxy fluorosilicone resin coating and preparation method and coating preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02232251A (en) * 1989-03-03 1990-09-14 Kansai Paint Co Ltd Resin composition, curable composition and paint composition
US20030207963A1 (en) * 2002-01-03 2003-11-06 Zang Hongmei Functionalized halogenated polymers for microencapsulation
US20070287093A1 (en) * 2006-06-13 2007-12-13 3M Innovative Properties Company Low refractive index composition comprising fluoropolyether urethane compound
US20080124555A1 (en) * 2006-11-29 2008-05-29 3M Innovative Properties Company Polymerizable composition comprising perfluoropolyether urethane having ethylene oxide repeat units
WO2009069974A2 (en) * 2007-11-29 2009-06-04 Lg Chem, Ltd. Coating composition and coating film having enhanced abrasion resistance and fingerprint traces removability
WO2009086515A2 (en) * 2007-12-27 2009-07-09 3M Innovative Properties Company Protective coating compositions

Family Cites Families (108)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3131161A (en) * 1960-02-25 1964-04-28 Wacker Chemie Gmbh Silicone rubber containing an epoxide compound
US3250808A (en) 1963-10-31 1966-05-10 Du Pont Fluorocarbon ethers derived from hexafluoropropylene epoxide
US4094911A (en) 1969-03-10 1978-06-13 Minnesota Mining And Manufacturing Company Poly(perfluoroalkylene oxide) derivatives
US3753755A (en) * 1971-04-26 1973-08-21 Minnesota Mining & Mfg Sheet material coated with heat hardenable tacky adhesive
US4025407A (en) * 1971-05-05 1977-05-24 Ppg Industries, Inc. Method for preparing high solids films employing a plurality of curing mechanisms
BE789188A (en) 1971-09-24 1973-01-15 Orion Yhtymae Oy METHOD FOR THE QUANTITATIVE AND QUALITATIVE DETERMINATION OF MOLECULES HAVING ANTIGENIC PROPERTIES
US4058401A (en) * 1974-05-02 1977-11-15 General Electric Company Photocurable compositions containing group via aromatic onium salts
GB1512982A (en) * 1974-05-02 1978-06-01 Gen Electric Salts
US4161478A (en) * 1974-05-02 1979-07-17 General Electric Company Photoinitiators
US4025348A (en) * 1974-05-10 1977-05-24 Hitachi Chemical Company, Ltd. Photosensitive resin compositions
US4049861A (en) * 1975-03-07 1977-09-20 Minnesota Mining And Manufacturing Company Abrasion resistant coatings
US4000115A (en) * 1975-04-18 1976-12-28 American Can Company Photopolymerization of epoxides
US4101513A (en) * 1977-02-02 1978-07-18 Minnesota Mining And Manufacturing Company Catalyst for condensation of hydrolyzable silanes and storage stable compositions thereof
US4100134A (en) * 1977-03-28 1978-07-11 Minnesota Mining And Manufacturing Company Storage-stable epoxy-terminated silane prepolymer
US4156046A (en) * 1977-03-28 1979-05-22 Minnesota Mining And Manufacturing Company Ultraviolet radiation protective, abrasion resistant, bloom resistant coatings
US4130690A (en) * 1977-09-12 1978-12-19 Minnesota Mining And Manufacturing Company Abrasion resistant coatings cured in the presence of PF5, SbF5, or HSbF6
US4293606A (en) * 1978-03-13 1981-10-06 Minnesota Mining And Manufacturing Company Low friction, abrasion resistant coating for transparent film
US4156035A (en) * 1978-05-09 1979-05-22 W. R. Grace & Co. Photocurable epoxy-acrylate compositions
JPS5545774A (en) * 1978-09-29 1980-03-31 Daikin Ind Ltd Epoxy resin composition
US4508916A (en) 1979-04-11 1985-04-02 Minnesota Mining And Manufacturing Company Curable substituted urethane acrylates
US4279717A (en) 1979-08-03 1981-07-21 General Electric Company Ultraviolet curable epoxy silicone coating compositions
DE2948420A1 (en) * 1979-12-01 1981-06-11 Agfa-Gevaert Ag, 5090 Leverkusen METHOD FOR PRODUCING PROTECTIVE LAYERS FOR PHOTOGRAPHIC MATERIALS
US4399192A (en) * 1980-01-07 1983-08-16 Panelographic Corporation Radiation cured abrasion resistant coatings of pentaerythritol acrylates and cellulose esters on polymeric substrates
US4337107A (en) * 1980-06-16 1982-06-29 Minnesota Mining And Manufacturing Company Abrasion-resistant transfer laminating sheet material
US4348462A (en) * 1980-07-11 1982-09-07 General Electric Company Abrasion resistant ultraviolet light curable hard coating compositions
CA1172790A (en) * 1980-11-24 1984-08-14 Gerald M. Leszyk Radiation curable composition including an acrylated urethane, and unsaturated carboxylic acid, a multifunctional acrylate and a siloxy-containing polycarbinol
US4818801A (en) * 1982-01-18 1989-04-04 Minnesota Mining And Manufacturing Company Ophthalmic device comprising a polymer of a telechelic perfluoropolyether
JPS5933315A (en) 1982-08-20 1984-02-23 Asahi Glass Co Ltd Production of antisoiling finish
US4426431A (en) * 1982-09-22 1984-01-17 Eastman Kodak Company Radiation-curable compositions for restorative and/or protective treatment of photographic elements
US4647413A (en) * 1983-12-27 1987-03-03 Minnesota Mining And Manufacturing Company Perfluoropolyether oligomers and polymers
US4623676A (en) * 1985-01-18 1986-11-18 Minnesota Mining And Manufacturing Company Protective coating for phototools
IT1187705B (en) 1985-07-24 1987-12-23 Montefluos Spa FLUORINATED POLYMERS AND RESINS FROM THEM
EP0247489B1 (en) * 1986-05-28 1993-08-25 Daikin Industries, Limited Fluorine containing water and oil repellent composition
IT1199770B (en) * 1986-12-16 1988-12-30 Ausimont Spa EPOXY RESINS OBTAINED BY CORETICULATION OF FLUORINATED EPOXY PREPOLYMERS AND NON-FLUORINATED EPOXY PREPOLYMERS
JPS63196621A (en) * 1987-02-10 1988-08-15 Matsushita Electric Works Ltd Production of epoxy resin composition
US5073404A (en) 1987-03-09 1991-12-17 Minnesota Mining And Manufacturing Company Silica coating composition for reflective sheeting
US4830910A (en) * 1987-11-18 1989-05-16 Minnesota Mining And Manufacturing Company Low adhesion compositions of perfluoropolyethers
JPH0532867A (en) * 1991-07-30 1993-02-09 Matsushita Electric Works Ltd Epoxy resin composition
FR2688790B1 (en) * 1992-03-23 1994-05-13 Rhone Poulenc Chimie COMPOSITIONS BASED ON POLYORGANOSILOXANES WITH CROSSLINKABLE FUNCTIONAL GROUPS AND THEIR USE FOR THE PRODUCTION OF ANTI-ADHESIVE COATINGS.
JP3246026B2 (en) * 1992-04-23 2002-01-15 ダイキン工業株式会社 Water and oil repellent fiber
US5274159A (en) 1993-02-18 1993-12-28 Minnesota Mining And Manufacturing Company Destructable fluorinated alkoxysilane surfactants and repellent coatings derived therefrom
US5514728A (en) * 1993-07-23 1996-05-07 Minnesota Mining And Manufacturing Company Catalysts and initiators for polymerization
US5554664A (en) * 1995-03-06 1996-09-10 Minnesota Mining And Manufacturing Company Energy-activatable salts with fluorocarbon anions
JPH0922111A (en) 1995-07-05 1997-01-21 Shin Etsu Chem Co Ltd Pellicle
WO1998040439A1 (en) 1997-03-14 1998-09-17 Minnesota Mining And Manufacturing Company Cure-on-demand, moisture-curable compositions having reactive silane functionality
DE19730245B4 (en) 1997-07-15 2007-08-30 W.L. Gore & Associates Gmbh Coating material, coated material and method of making the same
US5980992A (en) 1997-10-03 1999-11-09 3M Innovative Properties Company Fluorochemical treatments to provide low-energy surfaces
US6344526B1 (en) 1998-03-10 2002-02-05 Canon Kabushiki Kaisha Fluorine-containing epoxy resin composition, and surface modification process, ink jet recording head and ink jet recording apparatus using same
US6448346B1 (en) * 1998-03-10 2002-09-10 Canon Kabushiki Kaisha Fluorine-containing epoxy resin composition, and surface modification process, ink jet recording head and ink jet recording apparatus making use of the same
US6190743B1 (en) 1998-07-06 2001-02-20 Micro Lithography, Inc. Photomask protection system
US6780232B2 (en) * 1999-08-20 2004-08-24 The Walman Optical Company Coating composition yielding abrasion-resistant tiniable coating
US6187834B1 (en) 1999-09-08 2001-02-13 Dow Corning Corporation Radiation curable silicone compositions
US6678495B1 (en) 1999-10-11 2004-01-13 Xerox Corporation Epoxy silane cured fluoropolymers
KR100800010B1 (en) 1999-10-20 2008-01-31 가부시키가이샤 신에이샤 Photomask original form having layer for protecting film surface and method for preparing the same, and protective layer-forming liquid for photomask original form
DE10004132B4 (en) 2000-01-31 2007-02-01 Few Chemicals Gmbh Coating composition for the production of dirt-repellent layers and two-component system and their use
US6831770B2 (en) * 2000-03-03 2004-12-14 Sipix Imaging, Inc. Electrophoretic display and novel process for its manufacture
JP3757759B2 (en) * 2000-05-30 2006-03-22 ソニーケミカル株式会社 Connection structure
US6646088B2 (en) * 2000-08-16 2003-11-11 3M Innovative Properties Company Urethane-based stain-release coatings
ATE432298T1 (en) 2001-01-19 2009-06-15 3M Innovative Properties Co FLUOROVINYL LIGOMER COMPONENT WITH SILANE GROUPS, LIQUID COMPOSITIONS THEREOF AND COATING METHOD
ATE358143T1 (en) 2001-01-19 2007-04-15 3M Innovative Properties Co WATER SOLUBLE OR WATER DISPERSIBLE FLUOROCHEMICAL SILANES TO MAKE SUBSTRATES OIL AND WATER REPELLENT
US6803109B2 (en) * 2001-03-09 2004-10-12 3M Innovative Properties Company Water-and oil-repellency imparting urethane oligomers comprising perfluoroalkyl moieties
US6753380B2 (en) * 2001-03-09 2004-06-22 3M Innovative Properties Company Water-and oil-repellency imparting ester oligomers comprising perfluoroalkyl moieties
WO2003002628A1 (en) * 2001-06-27 2003-01-09 Daikin Industries, Ltd. Surface-treating agent composition and process for producing the same
JP2003096308A (en) * 2001-09-25 2003-04-03 Asahi Glass Co Ltd Water-repellent and oil-repellent composition and its formed product
CN101045852B (en) * 2001-10-30 2011-02-09 日立化成工业株式会社 Sealing material tablet, method of manufacturing the tablet and electronic component device
US6649272B2 (en) 2001-11-08 2003-11-18 3M Innovative Properties Company Coating composition comprising fluorochemical polyether silane polycondensate and use thereof
KR100487025B1 (en) * 2002-02-28 2005-05-11 주식회사 루밴틱스 Photo-curable resin composition for optical waveguide and optical waveguide prepared therefrom
US7094829B2 (en) * 2002-05-24 2006-08-22 3M Innovative Properties Company Fluorochemical composition comprising a fluorinated polymer and treatment of a fibrous substrate therewith
EP1587635A4 (en) 2002-12-17 2006-03-01 Insight Equity A P X Lp Rapid, thermally cured, back side mar resistant and antireflective coating for ophthalmic lenses
US20040147188A1 (en) 2003-01-28 2004-07-29 3M Innovative Properties Company Fluorochemical urethane composition for treatment of fibrous substrates
JP2004250517A (en) 2003-02-19 2004-09-09 Sentan Gijutsu Incubation Systems:Kk Coating composition and coated material
AU2003254564A1 (en) 2003-07-22 2005-02-25 Canon Kabushiki Kaisha Liquid-repellent coating composition and coating having high alkali resistance
ES2316877T3 (en) 2003-07-22 2009-04-16 Leibniz-Institut Fur Neue Materialien Gemeinnutzige Gmbh COMPOSITION OF COATING REPELLENT TO LIQUIDS RESISTANCE TO THE MAYORS AND COATING THAT CAN BE USED IN PATTERN FORMATION PROCEDURES.
JP4370846B2 (en) 2003-07-30 2009-11-25 ソニー株式会社 Antifouling hard coat, method for producing the same, and antifouling substrate
US20050037932A1 (en) * 2003-08-15 2005-02-17 Jianwei Liu Ultra-thin lubricant film for advanced tribological performance of magnetic storage media
US7189479B2 (en) 2003-08-21 2007-03-13 3M Innovative Properties Company Phototool coating
US7652115B2 (en) 2003-09-08 2010-01-26 3M Innovative Properties Company Fluorinated polyether isocyanate derived silane compositions
US7803894B2 (en) 2003-12-05 2010-09-28 3M Innovatie Properties Company Coating compositions with perfluoropolyetherisocyanate derived silane and alkoxysilanes
ITMI20040106A1 (en) 2004-01-27 2004-04-27 Solvay Solexis Spa POLIURETANI
US7811480B2 (en) 2004-03-04 2010-10-12 Transitions Optical, Inc. Photochromic optical article
US20050196616A1 (en) 2004-03-04 2005-09-08 Stewart Kevin J. Photochromic optical article
US20050196626A1 (en) 2004-03-04 2005-09-08 Knox Carol L. Photochromic optical article
JP2005255740A (en) 2004-03-09 2005-09-22 Sony Corp Hard-coating composition, surface-protective film, and optical disk
JP2006169328A (en) 2004-12-14 2006-06-29 Nippon Kayaku Co Ltd Photosensitive resin composition and film having its cured coating
US20060147177A1 (en) 2004-12-30 2006-07-06 Naiyong Jing Fluoropolymer coating compositions with olefinic silanes for anti-reflective polymer films
US7495118B2 (en) 2004-12-30 2009-02-24 3M Innovative Properties Company Compositions containing C4-swallow tail silanes
CA2593694A1 (en) 2004-12-30 2006-07-13 3M Innovative Properties Company Articles comprising a fluorochemical surface layer and related methods
US20060165919A1 (en) 2005-01-27 2006-07-27 Fuji Photo Film Co., Ltd. Coating composition, optical film, anti-reflection film, polarizing plate and image display device using the same
US7264669B1 (en) 2005-02-03 2007-09-04 Tribofilm Research, Inc. Scratch resistant gradient coating and coated articles
US20060216524A1 (en) 2005-03-23 2006-09-28 3M Innovative Properties Company Perfluoropolyether urethane additives having (meth)acryl groups and hard coats
FR2886309B1 (en) * 2005-05-31 2007-08-17 Airbus France Sas FLOOR FOR SOL-GEL COATING OF SURFACE AND SOL-GEL COATING PROCESS USING THE SAME
US20070014927A1 (en) 2005-07-15 2007-01-18 Buckanin Richard S Fluorochemical urethane composition for treatment of fibrous substrates
US8609742B2 (en) * 2006-03-02 2013-12-17 Daikin Industries, Ltd. High energy ray-curable composition
US8163354B2 (en) 2006-05-29 2012-04-24 Essilor International Compagnie Generale D'optique Process for obtaining a hard coated article having anti-fouling properties
US7728098B2 (en) 2006-07-27 2010-06-01 3M Innovative Properties Company Fluorochemical composition comprising fluorinated oligomeric silane
DE102007020404A1 (en) * 2006-09-18 2008-10-30 Nano-X Gmbh Process for the preparation of a coating material
US8530054B2 (en) 2006-09-27 2013-09-10 3M Innovative Properties Company Solar control multilayer film
WO2008073689A1 (en) 2006-12-15 2008-06-19 3M Innovative Properties Company Fluorochemical urethane compounds having pendent silyl groups used for surface treatment
US7825272B2 (en) 2006-12-20 2010-11-02 3M Innovative Properties Company Fluorochemical urethane compounds having pendent silyl groups
US7745653B2 (en) 2007-03-08 2010-06-29 3M Innovative Properties Company Fluorochemical compounds having pendent silyl groups
US7335786B1 (en) 2007-03-29 2008-02-26 3M Innovative Properties Company Michael-adduct fluorochemical silanes
US8015970B2 (en) * 2007-07-26 2011-09-13 3M Innovative Properties Company Respirator, welding helmet, or face shield that has low surface energy hard-coat lens
US7897678B2 (en) 2007-07-26 2011-03-01 3M Innovative Properties Company Fluorochemical urethane compounds having pendent silyl groups
WO2009029438A1 (en) * 2007-08-31 2009-03-05 3M Innovative Properties Company Hardcoats
US20110020657A1 (en) 2007-12-27 2011-01-27 Cheng-Chung Chang Protective coating compositions
FR2925908A1 (en) 2007-12-27 2009-07-03 Bmuestar Silicones France Sas CATIONICALLY POLYMERIZABLE / CROSS-LINKABLE COMPOSITION COMPRISING IODONIUM BORATE AND FREEZING ACCEPTABLE ODOR
WO2009114580A2 (en) * 2008-03-11 2009-09-17 3M Innovative Properties Company Hardcoat composition
US8420281B2 (en) 2009-09-16 2013-04-16 3M Innovative Properties Company Epoxy-functionalized perfluoropolyether polyurethanes

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02232251A (en) * 1989-03-03 1990-09-14 Kansai Paint Co Ltd Resin composition, curable composition and paint composition
US20030207963A1 (en) * 2002-01-03 2003-11-06 Zang Hongmei Functionalized halogenated polymers for microencapsulation
US20070287093A1 (en) * 2006-06-13 2007-12-13 3M Innovative Properties Company Low refractive index composition comprising fluoropolyether urethane compound
US20080124555A1 (en) * 2006-11-29 2008-05-29 3M Innovative Properties Company Polymerizable composition comprising perfluoropolyether urethane having ethylene oxide repeat units
WO2009069974A2 (en) * 2007-11-29 2009-06-04 Lg Chem, Ltd. Coating composition and coating film having enhanced abrasion resistance and fingerprint traces removability
WO2009086515A2 (en) * 2007-12-27 2009-07-09 3M Innovative Properties Company Protective coating compositions

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2478035A4 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9096712B2 (en) 2009-07-21 2015-08-04 3M Innovative Properties Company Curable compositions, method of coating a phototool, and coated phototool

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