WO2012024005A3 - Coating systems capable of forming ambiently cured highly durable hydrophobic coatings on substrates - Google Patents

Coating systems capable of forming ambiently cured highly durable hydrophobic coatings on substrates Download PDF

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Publication number
WO2012024005A3
WO2012024005A3 PCT/US2011/036929 US2011036929W WO2012024005A3 WO 2012024005 A3 WO2012024005 A3 WO 2012024005A3 US 2011036929 W US2011036929 W US 2011036929W WO 2012024005 A3 WO2012024005 A3 WO 2012024005A3
Authority
WO
WIPO (PCT)
Prior art keywords
ieast
substrates
forming
group
coating systems
Prior art date
Application number
PCT/US2011/036929
Other languages
French (fr)
Other versions
WO2012024005A2 (en
Inventor
Bryan Koene
Original Assignee
Luna Innovations Incorporated
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Luna Innovations Incorporated filed Critical Luna Innovations Incorporated
Priority to EP11818497.7A priority Critical patent/EP2591060B1/en
Priority to US13/809,247 priority patent/US20130109261A1/en
Publication of WO2012024005A2 publication Critical patent/WO2012024005A2/en
Publication of WO2012024005A3 publication Critical patent/WO2012024005A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/046Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/14Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/22Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/24Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31609Particulate metal or metal compound-containing
    • Y10T428/31612As silicone, silane or siloxane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31663As siloxane, silicone or silane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer

Abstract

A coating system is provided having (A) at least on fluorochemical silane compound having a perfluorinated segment and at least one silane group per molecule; (B) at least one non-fluorinated compound having an element M selected from the group consisting of Si, Ti, Zr, B, Al, Ge, V, Pb, Sn and Zn, and having at last two hydrolysable groups per molecule; (C) at least one cross-linking silicon compound having at Ieast one hydrolysable group, and at Ieast one reactive functional group capable of engaging in a crosslinking reaction; (D) ceramic particles; (E) at Ieast one acid catalyst; and (F) at least one ambient cure catalyst capable of ambient temperature polymerization of the at Ieast one reactive functional group of component (C).
PCT/US2011/036929 2010-07-09 2011-05-18 Coating systems capable of forming ambiently cured highly durable hydrophobic coatings on substrates WO2012024005A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP11818497.7A EP2591060B1 (en) 2010-07-09 2011-05-18 Coating systems capable of forming ambiently cured highly durable hydrophobic coatings on substrates
US13/809,247 US20130109261A1 (en) 2010-07-09 2011-05-18 Coating systems capable of forming ambiently cured highly durable hydrophobic coatings on substrates

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US36319010P 2010-07-09 2010-07-09
US61/363,190 2010-07-09

Publications (2)

Publication Number Publication Date
WO2012024005A2 WO2012024005A2 (en) 2012-02-23
WO2012024005A3 true WO2012024005A3 (en) 2012-04-12

Family

ID=45605598

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/036929 WO2012024005A2 (en) 2010-07-09 2011-05-18 Coating systems capable of forming ambiently cured highly durable hydrophobic coatings on substrates

Country Status (3)

Country Link
US (1) US20130109261A1 (en)
EP (1) EP2591060B1 (en)
WO (1) WO2012024005A2 (en)

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US8741158B2 (en) 2010-10-08 2014-06-03 Ut-Battelle, Llc Superhydrophobic transparent glass (STG) thin film articles
US11292919B2 (en) 2010-10-08 2022-04-05 Ut-Battelle, Llc Anti-fingerprint coatings
US9771656B2 (en) 2012-08-28 2017-09-26 Ut-Battelle, Llc Superhydrophobic films and methods for making superhydrophobic films
US9909027B2 (en) 2012-11-13 2018-03-06 Daikin Industries, Ltd. Surface treatment composition
KR20160061348A (en) * 2013-09-16 2016-05-31 허니웰 인터내셔날 인코포레이티드 Poly fluorine-containing siloxane coatings
US10113067B2 (en) 2013-10-04 2018-10-30 Luna Innovations Incorporated Transparent hydrophobic coating materials with improved durability and methods of making same
WO2015070218A2 (en) 2013-11-11 2015-05-14 Shaw Mark D Waterfroof apertured surfaces or materials using nanoparticle hydrophobic treatments
US20150239773A1 (en) 2014-02-21 2015-08-27 Ut-Battelle, Llc Transparent omniphobic thin film articles
CN108026438B (en) * 2015-07-13 2021-02-26 沙特阿拉伯石油公司 Stabilized nanoparticle compositions comprising ions
US10273399B2 (en) 2015-07-13 2019-04-30 Saudi Arabian Oil Company Polysaccharide coated nanoparticle compositions comprising ions
US10568240B2 (en) 2016-06-30 2020-02-18 Ford Global Technologies, Llc Coolant flow distribution using coating materials
US10326336B2 (en) 2016-06-30 2019-06-18 Ford Global Technologies, Llc Coolant flow distribution using coating materials
US10760672B2 (en) 2017-03-29 2020-09-01 Ford Global Technologies, Llc Coolant system pressure drop reduction
US10560002B2 (en) 2017-03-29 2020-02-11 Ford Global Technologies, Llc Coolant flow distribution using coating materials
US10622868B2 (en) 2017-03-29 2020-04-14 Ford Global Technologies, Llc Coolant flow distribution using coating materials
WO2019088117A1 (en) * 2017-10-31 2019-05-09 ダイキン工業株式会社 Curable composition
JP7266438B2 (en) * 2019-03-27 2023-04-28 三菱マテリアル電子化成株式会社 Liquid composition for forming an antifouling film
CA3141316A1 (en) 2019-05-29 2020-12-03 Saudi Arabian Oil Company Flow synthesis of polymer nanoparticles
US11566165B2 (en) 2019-05-30 2023-01-31 Saudi Arabian Oil Company Polymers and nanoparticles for flooding
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CN111533880B (en) * 2020-06-05 2022-10-21 陕西科技大学 Preparation method of nano-silica modified waterborne polyurethane
US11773715B2 (en) 2020-09-03 2023-10-03 Saudi Arabian Oil Company Injecting multiple tracer tag fluids into a wellbore
US11660595B2 (en) 2021-01-04 2023-05-30 Saudi Arabian Oil Company Microfluidic chip with multiple porosity regions for reservoir modeling
US11534759B2 (en) 2021-01-22 2022-12-27 Saudi Arabian Oil Company Microfluidic chip with mixed porosities for reservoir modeling
US11879328B2 (en) 2021-08-05 2024-01-23 Saudi Arabian Oil Company Semi-permanent downhole sensor tool
US11796517B2 (en) 2021-11-09 2023-10-24 Saudi Arabian Oil Company Multifunctional magnetic tags for mud logging
US11725139B2 (en) 2021-12-13 2023-08-15 Saudi Arabian Oil Company Manipulating hydrophilicity of conventional dye molecules for water tracer applications
US11860077B2 (en) 2021-12-14 2024-01-02 Saudi Arabian Oil Company Fluid flow sensor using driver and reference electromechanical resonators
US11867049B1 (en) 2022-07-19 2024-01-09 Saudi Arabian Oil Company Downhole logging tool
WO2024028618A1 (en) 2022-08-01 2024-02-08 Papadopoulos Nikolaos-Xafakis Sotirios G.P. Anti-soiling nano-coating systems with enhanced antimicrobial activity
EP4317098A1 (en) 2022-08-01 2024-02-07 Papadopoulos Nikolaos-Xafakis Sotirios G.P. Durable protective easy-to-clean nano-coating systems
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Also Published As

Publication number Publication date
US20130109261A1 (en) 2013-05-02
WO2012024005A2 (en) 2012-02-23
EP2591060A4 (en) 2015-07-22
EP2591060B1 (en) 2016-12-21
EP2591060A2 (en) 2013-05-15

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